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Photochemistry and Photophysics of Coordination Compounds: Ruthenium

  • Sebastiano Campagna
  • Fausto Puntoriero
  • Francesco Nastasi
  • Giacomo Bergamini
  • Vincenzo Balzani
Chapter
Part of the Topics in Current Chemistry book series (TOPCURRCHEM, volume 280)

Abstract

Ruthenium compounds, particularly Ru(II) polypyridine complexes, are the class of transition metal complexes which has been most deeply investigated from a photochemical viewpoint. The reason for such great interest stems from a unique combination of chemical stability, redox properties, excited-state reactivity, luminescence emission, and excited-state lifetime. Ruthenium polypyridine complexes are indeed good visible light absorbers, feature relatively intense and long-lived luminescence, and can undergo reversible redox processes in both the ground and excited states. This chapter presents some general concepts on the photochemical properties of Ru(II) polypyridine complexes and gives an overview of various research topics involving ruthenium photochemistry which have emerged in the last 15 years. In particular, aspects connected to supramolecular photochemistry and photophysics are discussed, such as multicomponent systems for light harvesting and photoinduced charge separation, systems for photoinduced multielectron/hole storage, and photocatalytic processes based on supramolecular Ru(II) polypyridine species. Interaction with biological systems and dye-sensitized photoelectrochemical cells are also briefly discussed.

Ruthenium Luminescence Electron transfer Energy transfer Solar energy conversion Light-powered molecular machines Dye-sensitized solar cells 

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Copyright information

© Springer-Verlag Berlin Heidelberg 2007

Authors and Affiliations

  • Sebastiano Campagna
    • 1
  • Fausto Puntoriero
    • 1
  • Francesco Nastasi
    • 1
  • Giacomo Bergamini
    • 2
  • Vincenzo Balzani
    • 2
  1. 1.Dipartimento di Chimica Inorganica, Chimica Analitica e Chimica FisicaUniversità di MessinaMessinaItaly
  2. 2.Dipartimento di Chimica “G. Ciamician”Università di BolognaBolognaItaly

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