Metal-substituted Bacteriochlorophylls: Novel Molecular Tools

  • Roie Yerushalmi
  • Idan Ashur
  • Avigdor Scherz
Part of the Advances in Photosynthesis and Respiration book series (AIPH, volume 25)


Chromophore molecules have fascinated scientists for decades. As early as 1903, chlorophylls were analyzed by chromatography, a newly introduced technique at that time (Tswett, 1906). Ever since, porphyrins and hydroporphyrins and their metal complexes, such as chlorophylls and bacteriochlorophylls, have been studied extensively in the context of their roles in photosynthesis, as biological model systems, and recently, as promising sensitizers for photodynamic therapy. When increasing ring saturation from the D 4h porphyrin macrocycle symmetry to the less symmetrical hydroporphyrins (together with an additional isocyclic ring), a wealth of possibilities for experimental observations of increasing complexity and detail became available. The synergistic link between theoretical and experimental approaches has advanced not only the understanding of various (bacterio)chlorophyll functions, but has also provided tools for exploring other complex electronic systems.


Chem Phys Photodynamic Therapy Axial Ligand Frontier Molecular Orbital Photosynthetic Reaction Center 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


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Copyright information

© Springer 2006

Authors and Affiliations

  • Roie Yerushalmi
    • 1
  • Idan Ashur
    • 1
  • Avigdor Scherz
    • 1
  1. 1.Department of Plant SciencesThe Weizmann Institute of ScienceRehovotIsrael

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