Abstract
Intensive polarographic study of Cd(II) with amino acids (L-Serine, DL-Alanine) and the ligand 4,4,4-trifluoro-1-(2-napthyl)butane-1,3-dione have been carried out keeping constant ionic strength (μ = 1), at 308 K, by using KNO3 in 60% Acetonitrile media. It was found that the reduction of all the systems taken, are diffusion controlled and reversible involving two electrons. For the simple system of Cd(II) with 4,4,4-trifluoro-1-(2-napthyl)butane-1,3-dione and Cd(II) with amino acids, the stability constants were determined first by DeFord and Hume and then evaluated by Schaap and McMaster method.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Underwood EJ (1991) Trace element in human and animal nutrition. Academic press, London
Weinstein B (1994) Chemistry and biochemistry of amino acids. Peptides and proteins, vol 3, no 16. Marcel Dekker, New York
Ottaway JH, Apps DK (1984) Biochemistry, 4th edn. W.B. Saunders Company, London
Nomenclature and symbolism for amino acids and peptides (1984) Pure Appl Chem 56(5): 595–624
David LN, Cox MM (2005) Principle of biochemistry, 4th edn. New York, pp 684–685
Buxbaum G, Pfoff G (2005) Industrial inorganic pigments, 3rd edn. Willey-VCH, pp 121–123
Smith CJE, Higgs MS, Baldwin KR (1999) Advances to protective coating and their application to ageing aircraft. Mechanical Sciences Sector, UK
Lohiya RK, Pratihar PL, Singh RV, Mukherjee (2001) Electrochemical studies at dme of Copper-2-Amino-Lepidine complexes in Aqueous 1, 4-Dioxan, Dimethyl Formamide, Acetonitrile and Formamide mixture. Orient J Chem 17(3):391–398
Verma MK, Chandel CPS (2003) Mixed ligand complexes of Cd with L-citrulline and some bicarboxylic acids: a electrochemical study. Orient J Chem 19:49–54
Singh SK, Chandel CPS (2003) Studies on mixed-ligand complexes of lead ion with some amino acids and phthalate at DME: a polarographic approach. Bull Electrochem 19(3):119–26
Jadwiga U, Henryk K, Barbora K (1992) Polarographic and potentiometric study of ternary complexes of Cadmium with Penicillamine and Histidine. J Coord Chem 25(2):149–154
Verma A, Chauhan PKS, Paliwal RK (2004) Polarographic study of stability constants of Cadmium(II) complexes with pyridine and some amino acids (Glycine and Alanine). Orient J Chem 20(2)
Verma A, Chauhan PKS, Paliwal RK (2004) Polarographic study of stability constants of Lead(II) complexes with B-Picoline and some amino acids (Lysine and Metheonine). Orient J Chem 20(2)
Verma M, Chandel C (2005) Stability constants of complexes of Cd(Ii) with some Bicarboxylic acids and Ascorbic acid (vitamin C): an electro analytical study. Orient J Chem 21(1):9
Kalpana S, Kaur T, Gupta KJ (2005) Study of complexes of cadmium(II) and lead(II) with mixed ligand (thioglycolate-oxalate). Indian Chem Soc 82:61
Jain AK, Khan F (1998) Polarographic study of mixed-ligand complexes of cadmium(II) with L-amino acid and vitamin B5. J Indian Chem Soc 75(1):31–32
Yadav RP (2003) Ph.D. thesis, University of Rajasthan, Jaipur, India
Khan F, Sahu PL (2000) Thermodynamics parameter of [Cd-L-Amino Acidate-Vitamine B~5] system: polarographic approach. Ultra Sci Physic Soc 12(1):106–108
Khatoon Z, Kabir-ud-Din (1990) Potentiometric studies on mixed-ligand complexes of copper(II) and zinc(II) with some amino acids (glycine, DL-α-alanine and DL-valine) as primary ligands and imidazole as a secondary ligand. J Indian Chem Soc 15(3):217–221
Arishy NM, Ammar RA, Al-Warthan A (2014) Determination of stability constants of mixed ligand complexes of Picolinic acid and other bioactive ligands with Zn(II) by potentiometric titration method. Asian J Chem 26(8):2395
Verma A, Paliwal RK (2005) Polarographic study of stability constants of Copper(II) complexes with [beta]-picoline, Malic and Tartaric acid. Asian J Chem17(1):355
Verma A, Paliwal RK (2005) Polaigraphically determination of stability constants of mixed ligand complexes of Cadmium(II) with Pyridine and some Amino Acids. Asian J Chem 17(3):1423
Chauhan PKS, Verma A, Paliwal RK (2005) Polarographic study of stability constants of Cadmium(II) complexes with β-picoline and some Hydroxy acids. Asian J Chem 17(1):349–354
Kumar A, Chauhan PKS, Paliwal RK (2004) Stability constant of Cadmium(II) complexes with ethylenediamine and carboxylic acids: a polyrographic study. Int J Chem Sci 2(3)
Sharma G, Chandel CPS (2002) Electrochemical studies on mixed ligand complexes of Cadmium Ion with some Dicarboxylic acids and Pyridoxine (vitamin B6). Asian J Chem 14(1):23–33
Prakash D, Shafayat M, Jamal A, Gupta AK, Prakash D (2005) Mixed ligand complexes of copper glicinate with N-oxide. Orient J Chem 21(3):555–558
Joshi JD, Brahm Bhatt MP, Sharma S, Vora JJ (2003) Potentiometric studies and mechanism of protonation in complex formation of some Cu(II) mixed ligand complexes. Asian J Chem 15:373–378
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2018 Springer Nature Singapore Pte Ltd.
About this paper
Cite this paper
Meena, S., Grover, R. (2018). Evaluation of Formation Constants of Mixed-Ligands Complexes of Cadmium(II) with Some Amino Acids (Alanine, Serine) and 4,4,4-Trifluoro-1-(2-Napthyl)Butane-1,3-Dione at DME in 60% Acetonitrile Medium. In: Parmar, V., Malhotra, P., Mathur, D. (eds) Green Chemistry in Environmental Sustainability and Chemical Education. Springer, Singapore. https://doi.org/10.1007/978-981-10-8390-7_18
Download citation
DOI: https://doi.org/10.1007/978-981-10-8390-7_18
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-10-8389-1
Online ISBN: 978-981-10-8390-7
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)