Skip to main content

Inelastic Electron Tunneling Spectroscopy

  • Chapter
  • First Online:
  • 656 Accesses

Abstract

Inelastic electron tunneling spectroscopy (IETS) is a vibrational spectroscopy method.

This is a preview of subscription content, log in via an institution.

References

  1. Lambe, J., Jaklevic, R.C.: Molecular vibration spectra by inelastic electron tunneling. Phys. Rev. 165, 821–832 (1968)

    Article  CAS  Google Scholar 

  2. Ho, W.: Single-molecule chemistry. J. Chem. Phys. 117, 11033–11061 (2002)

    Article  CAS  Google Scholar 

  3. Komeda, T.: Chemical identification and manipulation of molecules by vibrational excitation via inelastic tunneling process with scanning tunneling microscopy. Prog. Surf. Sci. 78, 41–85 (2005)

    Article  CAS  Google Scholar 

  4. Morgenstern, K., Lorente, N., Rieder, K.-H.: Controlled manipulation of single atoms and small molecules using the scanning tunneling microscope. Phys. Status Solidi B 250, 1671–1751 (2013)

    Article  CAS  Google Scholar 

  5. Kim, Y., Song, H.: Investigation of molecular junctions with inelastic electron tunneling microscopy. Appl. Spectrosc. Rev. 51, 603–620 (2016)

    Article  Google Scholar 

  6. Hihath, J., Tao, N.: Electron-phonon interactions in atomic and molecular devices. Prog. Surf. Sci. 87, 189–208 (2012)

    Article  CAS  Google Scholar 

  7. Lorente, N., Persson, M., Lauhon, L.J., Ho, W.: Symmetry selection rules for vibrationally inelastic tunneling. Phys. Rev. Lett. 86, 2593–2596 (2001)

    Article  CAS  Google Scholar 

  8. Paulsson, M., Frederiksen, T., Ueba, H., Lorente, N., Brandbyge, M.: Unified description of inelastic propensity rules for electron transport through nanoscale junctions. Phys. Rev. Lett. 100, 226604/1–226604/4 (2008)

    Article  CAS  Google Scholar 

  9. Okabayashi, N., Paulsson, M., Ueba, H., Konda, Y., Komeda, T.: Inelastic tunneling spectroscopy of alkanethiol molecules: high-resolution spectroscopy and theoretical simulations. Phys. Rev. Lett. 104, 077801/1–077801/4 (2010)

    Article  CAS  Google Scholar 

  10. Alducin, M., Sánchez-Portal, D., Arnau, A., Lorente, N.: Mixed-valency signature in vibrational inelastic electron tunneling spectroscopy. Phys. Rev. Lett. 104, 136101/1–136101/4 (2010)

    Article  CAS  Google Scholar 

  11. Shiotari, A., Okuyama, H., Hatta, S., Aruga, T., Alducin, M., Frederiksen, T.: Role of valence states of adsorbates in inelastic electron tunneling spectroscopy: A study of nitric oxide on Cu (110) and Cu (001). Phys. Rev. B 94, 075442/1–075442/12 (2016)

    Article  CAS  Google Scholar 

  12. Stipe, B.C., Rezaei, M.A., Ho, W.: A variable-temperature scanning tunneling microscope capable of single-molecule vibrational spectroscopy. Rev. Sci. Instrum. 70, 137–143 (1999)

    Article  CAS  Google Scholar 

  13. Stipe, B.C., Rezaei, M.A., Ho, W.: Single-molecule vibrational spectroscopy and microscopy. Science 280, 1732–1735 (1998)

    Article  CAS  Google Scholar 

  14. Stipe, B.C., Rezaei, M.A.: Ho, W, Localization of inelastic tunneling and the determination of atomic-scale structure with chemical specificity. Phys. Rev. Lett. 82, 1724–1727 (1999)

    Article  CAS  Google Scholar 

  15. Kiguchi, M., Tal, O., Wohlthat, S., Pauly, F., Krieger, M., Djukic, D., van Ruitenbeek, J.M.: Highly conductive molecular junctions based on direct binding of benzene to platinum electrodes. Phys. Rev. Lett. 101, 046801/1–046801/4 (2008)

    Article  CAS  Google Scholar 

  16. Chiang, C.L., Xu, C., Han, Z., Ho, W.: Real-space imaging of molecular structure and chemical bonding by single-molecule inelastic tunneling probe. Science 344, 885–888 (2014)

    Article  CAS  Google Scholar 

  17. Li, S., Yu, A., Toledo, F., Han, Z., Wang, H., He, H.Y., Wu., R., Ho, W.: Rotational and vibrational excitations of a hydrogen molecule trapped within a nanocavity of tunable dimension. Phys. Rev. Lett. 111, 146102/1–146102/4 (2013)

    CAS  Google Scholar 

  18. Heinrich, A.J., Gupta, J.A., Lutz, C.P., Eigler, D.M.: Single-atom spin-flip spectroscopy. Science 306, 466–469 (2004)

    Article  CAS  Google Scholar 

  19. Tsukahara, N., Noto, K.I., Ohara, M., Shiraki, S., Takagi, N., Takata, Y., Kawai, M.: Adsorption-induced switching of magnetic anisotropy in a single iron (II) phthalocyanine molecule on an oxidized Cu (110) surface. Phys. Rev. Lett. 102, 167203/1–167203/4 (2009)

    Article  CAS  Google Scholar 

  20. Vitali, L., Schneider, M.A., Kern, K., Wirtz, L., Rubio, A.: Phonon and plasmon excitation in inelastic electron tunneling spectroscopy of graphite. Phys. Rev. B 69, 121414(R)/1–121414(R)/4 (2004)

    Article  Google Scholar 

  21. Gawronski, H., Mehlhorn, M., Morgenstern, K.: Imaging phonon excitation with atomic resolution. Science 319, 930–933 (2008)

    Article  CAS  Google Scholar 

  22. Minamitani, E., Arafune, R., Tsukahara, N., Ohda, Y., Watanabe, S., Kawai, M., Takagi, N.: Surface phonon excitation on clean metal surfaces in scanning tunneling microscopy. Phys. Rev. B 93, 085411/1–085411/7 (2016)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Akitoshi Shiotari .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2018 Springer Nature Singapore Pte Ltd.

About this chapter

Check for updates. Verify currency and authenticity via CrossMark

Cite this chapter

Shiotari, A. (2018). Inelastic Electron Tunneling Spectroscopy. In: The Surface Science Society of Japan (eds) Compendium of Surface and Interface Analysis. Springer, Singapore. https://doi.org/10.1007/978-981-10-6156-1_46

Download citation

Publish with us

Policies and ethics