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Americium and Curium Chemistry and Technology pp 53–79Cite as

Studies of Americium and Curium Solution Chemistry in the USSR

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Part of the book series: Topics in -Element Chemistry ((TFEC,volume 1))

Abstract

The historical review of the fundamental achievements on Americium and Curium properties study in the USSR is presented in the paper. The main attention is payed to the properties of these elements in the highest oxidation states. Methods of obtaining, kinetics of redox processes, mechanism of transformation and stability of Am(IV), Am(V), Am(VI), Cm(IV) and Cm(VI) are discussed. The values of redox potentials for a number of reactions are presented. Americium behaviour in the highest oxidation states during extraction, sorption and precipitation, as well as the new methods of this element determination are discussed in conclusion.

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Authors and Affiliations

  1. V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, USSR Academy of Sciences, 19 Kosygin street, 11797, Moscow, USSR

    B. F. Myasoedov & N. Yu. Kremliakova

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  1. B. F. Myasoedov
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  2. N. Yu. Kremliakova
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  1. Lawrence Berkeley Laboratory, Berkeley, California, USA

    Norman M. Edelstein

  2. Rock well International, Golden, Colorado, USA

    James D. Navratil

  3. Rockwell Hanford, Richland, Washington, USA

    Wallace W. Schulz

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Myasoedov, B.F., Kremliakova, N.Y. (1985). Studies of Americium and Curium Solution Chemistry in the USSR. In: Edelstein, N.M., Navratil, J.D., Schulz, W.W. (eds) Americium and Curium Chemistry and Technology. Topics in f-Element Chemistry, vol 1. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-5444-1_6

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