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Synthesis and Characterization of Some New Metal Complexes of Condensation Reaction Products of 3-Amino-1,2,4-Triazole with Isatin, N-Acetylisatin and Bis (2,3-Dioxoindolin-1-yl)Mercury(II)

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Book cover Chemistry: The Key to our Sustainable Future

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Abstract

The condensation reaction of 3-amino-1,2,4-triazole (amitrol, 3-AT) with N-acetylisatin caused the opening of the indole ring and led to the formation of the new ligand (Z)-2-(1H-1,2,4-triazol-3-ylimino-2-(2-acetamido-phenyl)-N-(1H-1,2,4-triazol-3-yl) acetamide (1), while the reaction with isatin and bis(2,3-dioxoindolin-1-yl)mercury(II), (Hg(isatin)2) caused no ring opening and the Schiff base (Z)-3-(1H-1,2,4-triazol-3-ylimino) indolin-2-one (2), and the new mercury complex 2-(E)-3-(1H-1,2,4-triazol-3-ylimino)-2-oxoindolin-1-yl)((Z)-3-(1H-1,2,4-triazol-3-ylimino)-2-oxoindolin-1-l)mercury(II) (3) were formed. New complexes of Co(II), Ni(II), Cu(II), Pd(II) and Zn(II) ions with the two ligands (1) and (2) were prepared. The studied products were characterized by elemental analysis, NMR, IR, mass spectra and thermal analysis. In all the complexes the metal was coordinated to the nitrogen atoms of the triazole ring and to the azomethine group.

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Authors and Affiliations

  1. Department of Chemistry, College of Science, University of Baghdad, Jaderiya, Baghdad, Iraq

    Ahlam J. Abdulghani & Zainab Z. Ahmed

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  1. Ahlam J. Abdulghani
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  2. Zainab Z. Ahmed
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Correspondence to Ahlam J. Abdulghani .

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Editors and Affiliations

  1. University of Mauritius Dept of Chemistry, Faculty of Science, Reduit, Mauritius

    Minu Gupta Bhowon

  2. University of Mauritius Dept. of Chemistry, Faculty of Science, Reduit, Mauritius

    Sabina Jhaumeer-Laulloo

  3. University of Mauritius Dept. of Chemistry, Faculty of Science, Reduit, Mauritius

    Henri Li Kam Wah

  4. University of Mauritius Dept. of Chemistry, Faculty of Science, Reduit, Mauritius

    Ponnadurai Ramasami

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Abdulghani, A.J., Ahmed, Z.Z. (2014). Synthesis and Characterization of Some New Metal Complexes of Condensation Reaction Products of 3-Amino-1,2,4-Triazole with Isatin, N-Acetylisatin and Bis (2,3-Dioxoindolin-1-yl)Mercury(II). In: Gupta Bhowon, M., Jhaumeer-Laulloo, S., Li Kam Wah, H., Ramasami, P. (eds) Chemistry: The Key to our Sustainable Future. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-7389-9_20

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