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Virtual Phonon Exchange Influence on Magnetic Properties of Jahn-Teller Crystals: Triple Electronic Degeneracy

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Vibronic Interactions and the Jahn-Teller Effect

Part of the book series: Progress in Theoretical Chemistry and Physics ((PTCP,volume 23))

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Abstract

Mutual influence of magnetic interactions and competing two types of virtual phonon exchange interactions is considered in the framework of the cooperative Jahn-Teller effect theory. It is shown that this competition in the presence of magnetic interactions can result in a new type of structural tetragonal –tetragonal transition. The corresponding virtual phonon exchange interactions drastically affect the magnetic crystal properties. Comparison with the experimental data is presented.

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Author information

Authors and Affiliations

  1. Department of Chemistry and Physics, Simmons College, 300 The Fenway, Boston, MA, 02115, USA

    Michael D. Kaplan

  2. Department of Physics, Boston University, 590 Commonwealth Ave., Boston, MA, 02215, USA

    George O. Zimmerman

Authors
  1. Michael D. Kaplan
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  2. George O. Zimmerman
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Corresponding author

Correspondence to Michael D. Kaplan .

Editor information

Editors and Affiliations

  1. Inst. of General & Inorganic Chemistry, Bulgarian Academy of Sciences, Sofia, 1113, Bulgaria

    Mihail Atanasov

  2. , Chemistry, University of Fribourg, Ch. du Musee 9, Fribourg, 1700, Switzerland

    Claude Daul

  3. Paul Scherrer Institut, Villigen PSI, 5232, Switzerland

    Philip L.W. Tregenna-Piggott

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Kaplan, M.D., Zimmerman, G.O. (2011). Virtual Phonon Exchange Influence on Magnetic Properties of Jahn-Teller Crystals: Triple Electronic Degeneracy. In: Atanasov, M., Daul, C., Tregenna-Piggott, P. (eds) Vibronic Interactions and the Jahn-Teller Effect. Progress in Theoretical Chemistry and Physics, vol 23. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-2384-9_24

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