Abstract
Laser sintering of polymers is widely used for the production of individual products and small-batch series. However, the qualification of laser-sintered polymeric components for new application fields, e.g. in the food and packaging industry, is still limited due to missing knowledge on physicochemical material properties. This work investigates the mass transfer of low molecular weight substances through laser-sintered polyamide 12 sheets in comparison to an extruded polyamide 12 film. Analysis of structural material properties reveals significant differences between both materials depending on the production processes. Despite their apparent porosity, laser-sintered sheets show lower permeation coefficients for water vapor and oxygen compared to extruded films. This might be related to the higher crystallinity of the laser-sintered vs. the extruded material, arising from the slow cooling rate of the polymer in the laser sintering process.
This research brings knowledge of the different permeation behavior of laser-sintered and extruded polyamide 12 in relation to the structural properties.
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Gebhardt, A., Hötter, J.-S.: Additive Manufacturing: 3D Printing for Prototyping and Manufacturing. Hanser, Munich (2016)
Goodridge, R., Tuck, C., Hague, R.: Laser sintering of polyamides and other polymers. Prog. Mater. Sci. 57, 229–267 (2012)
Schmid, M.: Laser Sintering with Plastics: Technology, Processes, and Materials. Hanser, Munich (2018)
Wörz, A., Wudy, K., Drummer, D., Wegner, A., Witt, G.: Comparison of long-term properties of laser sintered and injection molded polyamide 12 parts. J. Polym. Eng. 38, 573–582 (2018)
Van Hooreweder, B., Moens, D., Boonen, R., Kruth, J.-P., Sas, P.: On the difference in material structure and fatigue properties of nylon specimens produced by injection molding and selective laser sintering. Polym. Test. 32, 972–981 (2013)
Brandrup, J., Immergut, E.H., Grulke, E.A., Abe, A., Bloch, D.R.: Polymer Handbook, 4th edn. Wiley, New York (1999)
Bourell, D.L., Watt, T.J., Leigh, D.K., Fulcher, B.: Performance limitations in polymer laser sintering. Phys. Procedia 56, 147–156 (2014)
Langowski, H.C.: Permeation of Gases and Condensable Substances through Monolayer and Multilayer Structures. In: Piringer, O.G., Baner, A.L. (eds.) Plastic Packaging. Interactions with Food and Pharmaceuticals, pp. 297–347. Wiley-VCH, Weinheim (2008)
Barrer, R.M.: Diffusion in and Through Solids. University Press, Cambridge (1941)
Crank, J.: The Mathematics of Diffusion, 2nd edn. Clarendon Press, Oxford (1975)
Wegner, A.: Theory on the continuation of melting processes as basic requirement for a robust processing in laser sintering of thermoplastics (Diss.), Universitätsbibliothek Duisburg-Essen (2015)
Liebrich, A., Langowski, H.C., Schreiber, R., Pinzer, B.R.: Porosity distribution in laser-sintered polymeric thin sheets as revealed by X-ray micro tomography. Polym. Test. 76, 286–297 (2019)
Gogolewski, S., Czerntawska, K., Gastorek, M.: Effect of annealing on thermal properties and crystalline structure of polyamides. Nylon 12 (polylaurolactam). Colloid Polym. Sci. 258, 1130–1136 (1980)
Launhardt, M., Wörz, A., Loderer, A., Laumer, T., Drummer, D., Hausotte, T., Schmidt, M.: Detecting surface roughness on SLS parts with various measuring techniques. Polym. Test. 53, 217–226 (2016)
Liebrich, A., Langowski, H.C., Schreiber, R., Pinzer, B.R.: Permeation properties of laser-sintered polyamide 12 sheets in relation to their material structure, to be published in Additive Manufacturing
Müller, K., Scheuerer, Z., Florian, V., Skutschik, T., Sängerlaub, S.: Comparison of test methods for oxygen permeability: optical method versus carrier gas method. Polym. Test. 63, 126–132 (2017)
Rüsenberg, S., Schmidt, L., Schmid, H.: Mechanical and physical properties—A way to assess quality of laser sintered parts. In: Proceedings of the 22nd International Solid Freeform Fabrication Symposium, pp. 239–251 (2011)
Verbelen, L., Dadbakhsh, S., Van den Eynde, M., Kruth, J.-P., Goderis, B., Van Puyvelde, P.: Characterization of polyamide powders for determination of laser sintering processability. Eur. Polym. J. 75, 163–174 (2016)
Meyer, K.R., Hornung, K.H., Feldmann, R., Smigerski, H.J.: Method for polytropically precipitating polyamide powder coating compositions where the polyamides have at least 10 aliphatically bound carbon atoms per carbonamide group. US Patent 4,334,056, 1982
Scholten, H., Christoph, W.: Use of a nylon-12 for selective laser sintering. US Patent 6,245,281, 2001
Schmid, M., Amado, A., Wegener, K.: Materials perspective of polymers for additive manufacturing with selective laser sintering. J. Mater. Res. 29, 1824–1832 (2014)
Zarringhalam, H., Majewski, C., Hopkinson, N.: Degree of particle melt in Nylon-12 selective laser-sintered parts. Rapid Prototyp. J. 15, 126–132 (2009)
Domininghaus, H.: Kunststoffe: Eigenschaften und Anwendungen (Plastics: Properties and Applications), 7th edn. Springer, Berlin (2008)
McKeen, L.W.: Permeability Properties of Plastics and Elastomers. William Andrew Publishing, Oxford (2012)
Tasch, D., Mad, A., Stadlbauer, R., Schagerl, M.: Thickness dependency of mechanical properties of laser-sintered polyamide lightweight structures. Addit. Manuf. 23, 25–33 (2018)
Michaels, A., Parker Jr., R.: Sorption and flow of gases in polyethylene. J. Polym. Sci. 41, 53–71 (1959)
Acknowledgments
The authors would like to thank Monika Gessler from EOS Electro Optical Systems GmbH (Krailling, Germany) for her helpful advice and for providing the LS samples for this research.
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Liebrich, A., Langowski, HC., Schreiber, R., Pinzer, B. (2020). Permeation Properties of Laser-Sintered Polyamide 12 Sheets in Comparison to an Extruded Polyamide 12 Film. In: Hopmann, C., Dahlmann, R. (eds) Advances in Polymer Processing 2020. Springer Vieweg, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-60809-8_21
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DOI: https://doi.org/10.1007/978-3-662-60809-8_21
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