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Sulfur(IV) Oxidation

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Book cover Heterogeneous and Liquid Phase Processes

Summary

The kinetics of the decomposition of aqueous peroxonitric acid, O2 NOOH, have been studied as a function of pH in the range pH = 0-9. In addition to literature studies on the stability of peroxonitric acid solutions two more reactions have been measured. They are assigned to the formation and the decay of a short-lived intermediate. The composition of the intermediate is discussed. A peroxo-species containing two nitrogens in different oxidation states (+III and +V) is favoured.

The kinetics of the oxidation of S(IV) by peroxonitric acid as well as by the intermediate have been studied as a function of pH in the range pH = 0-8.2 (T = 285 K, I = 1.0 M NaC104).

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Authors and Affiliations

  1. Institut för Anorganische Chemie, Technische Hochschule Darmstadt, Petersenstraße 18, D-64287, Darmstadt, Germany

    P. Amels, H. Elias, U. Götz, U. Steingens & K. J. Wannowius

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  1. P. Amels
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  2. H. Elias
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  3. U. Götz
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  4. U. Steingens
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  5. K. J. Wannowius
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Editors and Affiliations

  1. Max-Planck-Institut för Chemie, Abteilung Biogeochemie, Saarstraße 23, D-55122, Mainz, Germany

    Peter Warneck

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© 1996 Springer-Verlag Berlin Heidelberg

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Amels, P., Elias, H., Götz, U., Steingens, U., Wannowius, K.J. (1996). Sulfur(IV) Oxidation. In: Warneck, P. (eds) Heterogeneous and Liquid Phase Processes. Transport and Chemical Transformation of Pollutants in the Troposphere, vol 2. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-61445-3_3

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  • DOI: https://doi.org/10.1007/978-3-642-61445-3_3

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-64847-2

  • Online ISBN: 978-3-642-61445-3

  • eBook Packages: Springer Book Archive

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