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Book cover Epoxidations and Hydroperoxidations of α,β-Unsaturated Ketones

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Abstract

All solvents were purified by distillation before use following standard procedures. Absolute solvents were obtained by distillation over appropriate drying agent (vide infra) and then kept under an atmosphere of argon: diethyl ether, tetrahydrofuran, toluene, and n-hexane (sodium, benzophenone as indicator), chloroform, dichloromethane, triethylamine (calcium hydride), ethanol (magnesium). Absolute 1,4-dioxane, TBME, di(n-butyl)ether, DME, NMP, acetonitrile, and DMSO were purchased from Sigma-Aldrich and used as received. Other commercial reagents were obtained from various sources and used without further purification.

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Notes

  1. 1.

    Relative configuration was assigned on the basis of NOE correlations in collaboration with the NMR department of the Max-Planck-Institut für Kohlenforschung.

References

  1. Ouyang X-Y, Jiang H-F, Huang J-M (2006) Chin J Chem 24:1480

    Article  CAS  Google Scholar 

  2. Wynberg H, Marsman B (1980) J Org Chem 45:158

    Article  CAS  Google Scholar 

  3. Carlone A, Bartoli G, Bosco M, Pesciaioli F, Ricci P, Sambri L, Melchiorre P (2007) Eur J Org Chem 33:5492

    Article  Google Scholar 

  4. Wang X, Reisinger CM, List B (2008) J Am Chem Soc 130:6070

    Article  CAS  Google Scholar 

  5. Rickards RW, Rodwell JL, Schmalzl KJ (1977) J Chem Soc Chem Commun 849

    Google Scholar 

  6. Lv J, Zhang J, Lin Z, Wang Y (2009) Chem Eur J 15:972

    Article  CAS  Google Scholar 

  7. Wipf P, Smitrovich JH, Moon CW (1992) J Org Chem 57:3178

    Article  CAS  Google Scholar 

  8. Reisinger CM, Wang X, List B (2008) Angew Chem Int Ed 47:8112

    Article  CAS  Google Scholar 

  9. Usuda H, Kuramochi A, Kanai M, Shibasaki M (2004) Org Lett 6:4387

    Article  CAS  Google Scholar 

  10. Sato T, Kikuchi T, Tsujita H, Kaetsu A, Sootome N, Nishida K-i, Tachibana K, Murayama E (1991) Tetrahedron 47:3281–3304

    Article  CAS  Google Scholar 

  11. Scheller ME, Frei B (1992) Helv Chim Acta 75:69

    Article  CAS  Google Scholar 

  12. Miyashita M, Suzuki T, Yoshikoshi A (1987) Tetrahedron Lett 28:4293

    Article  CAS  Google Scholar 

  13. Dussault PH, Liu X (1999) Org Lett 1:1391

    Article  CAS  Google Scholar 

  14. Woods GF, Tucker IW (1948) J Am Chem Soc 70:2174

    Article  CAS  Google Scholar 

  15. Woods GF, Griswold PH, Armbrecht BH, Blumenthal DI, Plapinger R (1949) J Am Chem Soc 71:2028

    Article  CAS  Google Scholar 

  16. Coote SC, O’Brien P, Whitwood AC (2008) Org Biomol Chem 6:4299

    Article  CAS  Google Scholar 

  17. Uyanik M, Fukatsu R, Ishihara K (2009) Org Lett 11:3470

    Article  CAS  Google Scholar 

  18. Larock RC, Hightower TR, Kraus GA, Hahn P, Zheng D (1995) Tetrahedron Lett 36:2423

    Article  CAS  Google Scholar 

  19. Yu J-Q, Corey EJ (2002) Org Lett 4:2727

    Article  CAS  Google Scholar 

  20. Cahiez G, Avedissian H (1998) Synthesis 1199

    Google Scholar 

  21. Zhou J, Wakchaure V, Kraft P, List B (2008) Angew Chem Int Ed 47:7656

    Article  CAS  Google Scholar 

  22. Oare DA, Henderson MA, Sanner MA, Heathcock CH (1990) J Org Chem 55:132

    Article  CAS  Google Scholar 

  23. Brunner H, Bügler J, Nuber B (1995) Tetrahedron Asymmetry 6:1699

    Article  CAS  Google Scholar 

  24. Vakulya B, Varga S, Csámpai A, Soós T (1967) Org Lett 2005:7

    Google Scholar 

  25. Brunner H, Bügler J (1997) Bull Soc Chim Belg 106:77

    CAS  Google Scholar 

  26. Franz MH, Röper S, Wartchow R, Hoffmann HMR (2004) J Org Chem 69:2983

    Article  CAS  Google Scholar 

  27. Berkessel A, Guixá M, Schmidt F, Neudörfl JM, Lex J (2007) Chem Eur J 13:4483

    Article  CAS  Google Scholar 

  28. Chen W, Du W, Duan Y-Z, Wu Y, Yang S-Y, Chen Y-C (2007) Angew Chem Int Ed 46:7667

    Article  CAS  Google Scholar 

  29. Kessar SV, Singh P, Singh KN, Singh SK (1999) Chem Commun 19:1927

    Article  Google Scholar 

  30. Lygo B, Crosby J, Lowdon T, Wainwright PG (1999) Tetrahedron 55:2795

    Article  CAS  Google Scholar 

  31. Stotter PL, Friedman MD (1985) J Org Chem 50:29

    Article  CAS  Google Scholar 

  32. Andrés JM, Manzano R, Pedrosa R (2008) Chem Eur J 14:5116

    Article  Google Scholar 

  33. Martin NJA, Ozores L, List B (2007) J Am Chem Soc 129:8976

    Article  CAS  Google Scholar 

  34. Kim KH, Lee S, Lee D-W, Ko D-H, Ha D-C (2005) Tetrahedron Lett 46:5991

    Article  CAS  Google Scholar 

  35. Storer RI, Carrera DE, Ni Y, MacMillan DWC (2005) J Am Chem Soc 128:84

    Article  Google Scholar 

  36. Maruoka K, Itoh T, Araki Y, Shirasaka T, Yamamoto H (1988) Bull Chem Soc Jpn 61:2975

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Max-Planck-Institut für Kohlenforschung, Mülheim an der Ruhr, Germany

    Corinna Reisinger

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  1. Corinna Reisinger
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Correspondence to Corinna Reisinger .

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Reisinger, C. (2012). Experimental Part. In: Epoxidations and Hydroperoxidations of α,β-Unsaturated Ketones. Springer Theses. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-28118-1_7

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