Skip to main content

Zinc Based Spinel Oxides for Energy Conversion and Storage Applications

  • Chapter
  • First Online:
Nanotechnology: Applications in Energy, Drug and Food
  • 1256 Accesses

Abstract

Recently, ZnV2O4 gained a great attention of the researchers in the field of energy storage applications. The main reason is that both zinc and vanadium are economical, earth abundant and have a variety of electrochemistry to offer. The different oxidation states of vanadium deliver a vast range of redox reactions which are favorable for energy (electrochemical) storage applications. In this chapter facile and template free methods are presented for the synthesis of novel hierarchical nanospheres (NHNs), glomerulus nano/microspheres and spinel oxide nanosheets of ZnV2O4 to be used in different energy storage applications including Lithium ion batteries (LIBs), hydrogen storage and supercapacitors. Also, ZnV2O4 is studied for the thermoelectric properties to be used in thermoelectric devices. These studies overlay the way to consider ZnV2O4 as a potential candidate for energy storage applications in future. This comprehensive review will boost the relevant research with a view to work on further performance enhancement of ZnV2O4 materials.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 149.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 199.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  • Bitla Y et al (2015) Origin of metallic behavior in NiCo2O4 ferrimagnet. Sci Rep 5:15201

    Article  CAS  Google Scholar 

  • Butt FK et al (2014a) Synthesis of novel ZnV2O4 hierarchical nanospheres and their applications as electrochemical supercapacitor and hydrogen storage material. ACS Appl Mater Interfaces 6(16):13635–13641

    Article  CAS  Google Scholar 

  • Butt FK et al (2014b) Synthesis of novel ZnV2O4 spinel oxide nanosheets and their hydrogen storage properties. CrystEngComm 16(5):894–899

    Article  CAS  Google Scholar 

  • Butt FK et al (2014c) Synthesis, evolution and hydrogen storage properties of ZnV2O4 glomerulus nano/microspheres: a prospective material for energy storage. Int J Hydrogen Energy 39(15):7842–7851

    Article  CAS  Google Scholar 

  • Chilev C, Lamari FD (2016) Hydrogen storage at low temperature and high pressure for application in automobile manufacturing. Int J Hydrog Energy 41(3):1744–1758

    Article  CAS  Google Scholar 

  • Duan F et al (2011) Template-free synthesis of ZnV2O4 hollow spheres and their application for organic dye removal. Appl Surf Sci 258(1):189–195

    Article  CAS  Google Scholar 

  • Elsheikh MH et al (2014) A review on thermoelectric renewable energy: principle parameters that affect their performance. Renew Sust Energ Rev 30:337–355

    Article  Google Scholar 

  • Etacheri V et al (2011) Challenges in the development of advanced Li-ion batteries: a review. Energy Environ Sci 4(9):3243–3262

    Article  CAS  Google Scholar 

  • Fotouhi A et al (2016) A review on electric vehicle battery modelling: from Lithium-ion toward Lithium–Sulphur. Renew Sust Energ Rev 56:1008–1021

    Article  CAS  Google Scholar 

  • Goldstein A et al (2013) Parasitic light absorption processes in transparent polycrystalline MgAl2O4 and YAG. J Am Ceram Soc 96(11):3523–3529

    Article  CAS  Google Scholar 

  • Hill RJ, Craig JR, Gibbs G (1979) Systematics of the spinel structure type. Phys Chem Miner 4(4):317–339

    Article  CAS  Google Scholar 

  • Jeppson P et al (2006) Cobalt ferrite nanoparticles: achieving the superparamagnetic limit by chemical reduction. J Appl Phys 100(11):114324

    Article  Google Scholar 

  • Lu L et al (2013) A review on the key issues for lithium-ion battery management in electric vehicles. J Power Sources 226:272–288

    Article  CAS  Google Scholar 

  • Marco JF et al (2001) Cation distribution and magnetic structure of the ferrimagnetic spinel NiCo2O4. J Mater Chem 11(12):3087–3093

    Article  CAS  Google Scholar 

  • Pei Y, Wang H, Snyder GJ (2012) Band engineering of thermoelectric materials. Adv Mater 24(46):6125–6135

    Article  CAS  Google Scholar 

  • Phanichphant S (2012) Cellulose-precursor synthesis of nanocrystalline Co 0.5 Cu 0.5 Fe 2 O 4 spinel ferrites. Mater Res Bull 47(2):473–477

    Article  Google Scholar 

  • Rechuis M et al (2003) Crystallographic and magnetic structure of ZnV2O4. Eur Phys J B 35:311–316

    Article  Google Scholar 

  • Shanmugavani A, Selvan RK (2016) Improved electrochemical performances of CuCo2O4/CuO nanocomposites for asymmetric supercapacitors. Electrochim Acta 188:852–862

    Article  CAS  Google Scholar 

  • Sickafus KE, Wills JM, Grimes NW (1999) Structure of spinel. J Am Ceram Soc 82(12):3279–3292

    Article  CAS  Google Scholar 

  • Simon P, Brousse T, Favier F (2017) Electrochemical double-layer capacitors (EDLC). In: Simon P, Brousse T, Favier F (eds) Supercapacitors based on carbon or pseudocapacitive materials. ISTE Ltd; Wiley, London; Hoboken, NJ, pp 1–25

    Chapter  Google Scholar 

  • Singh S, Maurya R, Pandey SK (2016) Investigation of thermoelectric properties of ZnV2O4 compound at high temperatures. J Phys D Appl Phys 49(42):425601

    Article  Google Scholar 

  • Sonoyama N et al (2006) Electrochemical luminescence of rare earth metal ion doped MgIn2O4 electrodes. J Electrochem Soc 153(3):H45–H50

    Article  CAS  Google Scholar 

  • Stetson NT, McWhorter S, Ahn CC (2015) 1 - Introduction to hydrogen storage. In: Gupta Ram B, Basile A, Veziroğluin TN (eds) Compendium of hydrogen energy, vol 2. Woodhead Publishing, Cambridge, pp 3–25

    Google Scholar 

  • Sutherland FL et al (2009) Gem-corundum megacrysts from east Australian basalt fields: trace elements, oxygen isotopes and origins∗. Aust J Earth Sci 56(7):1003–1022

    Article  CAS  Google Scholar 

  • Vomir M et al (2016) Dynamical torque in CoxFe3–xO4 nanocube thin films characterized by femtosecond magneto-optics: a π-shift control of the magnetization precession. Nano Lett 16(8):5291–5297

    Article  CAS  Google Scholar 

  • Wei C et al (2016) Valence change ability and geometrical occupation of substitution cations determine the pseudocapacitance of spinel ferrite XFe2O4 (X= Mn, Co, Ni, Fe). Chem Mater 28(12):4129–4133

    Article  CAS  Google Scholar 

  • Whittingham MS (2004) Lithium batteries and cathode materials. Chem Rev 104(10):4271–4302

    Article  CAS  Google Scholar 

  • Whittingham MS (2014) Ultimate limits to intercalation reactions for lithium batteries. Chem Rev 114(23):11414–11443

    Article  CAS  Google Scholar 

  • Xiao L et al (2009) Clewlike ZnV2O4 hollow spheres: nonaqueous sol–gel synthesis, formation mechanism, and lithium storage properties. Chem Eur J 15(37):9442–9450

    Article  CAS  Google Scholar 

  • Zeng L et al (2012) ZnV2O4–CMK nanocomposite as an anode material for rechargeable lithium-ion batteries. J Mater Chem 22(28):14284–14288

    Article  CAS  Google Scholar 

  • Zhang C et al (2016) Hierarchically porous Co3O4/C nanowire arrays derived from a metal–organic framework for high performance supercapacitors and the oxygen evolution reaction. J Mater Chem A 4(42):16516–16523

    Article  CAS  Google Scholar 

  • Zhang L et al (2018) A review of supercapacitor modeling, estimation, and applications: a control/management perspective. Renew Sust Energ Rev 81:1868–1878

    Article  Google Scholar 

  • Zhang X, Zhao L-D (2015) Thermoelectric materials: energy conversion between heat and electricity. J Mater 1(2):92–105

    Google Scholar 

  • Zhao Q et al (2017) Spinels: controlled preparation, oxygen reduction/evolution reaction application, and beyond. Chem Rev 117(15):10121–10211

    Article  CAS  Google Scholar 

  • Zheng C et al (2014) Synthesis of hierarchical ZnV2O4 microspheres and its electrochemical properties. CrystEngComm 16(44):10309–10313

    Article  CAS  Google Scholar 

  • Zhu X et al (2015) Nanophase ZnV2O4 as stable and high capacity Li insertion electrode for Li-ion battery. Curr Appl Phys 15(4):435–440

    Article  Google Scholar 

Download references

Acknowledgements

Financial support from Alexander von Humboldt Foundation and Federal Ministry for Education and Research (BMBF) is gratefully acknowledged.

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2019 Springer Nature Switzerland AG

About this chapter

Check for updates. Verify currency and authenticity via CrossMark

Cite this chapter

Butt, F.K., Rehman, S.U. (2019). Zinc Based Spinel Oxides for Energy Conversion and Storage Applications. In: Siddiquee, S., Melvin, G., Rahman, M. (eds) Nanotechnology: Applications in Energy, Drug and Food. Springer, Cham. https://doi.org/10.1007/978-3-319-99602-8_2

Download citation

Publish with us

Policies and ethics