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Surface Enhanced IR Absorption and Raman Detection of Tryptophan Amino Acids Over Silver Nanoislands Deposited on Graphene

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The Physics of Semiconductor Devices (IWPSD 2017)

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Abstract

Surface enhanced IR absorption (SEIRA) and Surface enhanced Raman scattering (SERS) of amino acids in protein (L-Tryptophan) drop coated on deposited silver nanoislands over monolayer of graphene on silicon were obtained using FTIR in reflectance mode and micro-Raman respectively. In this work, two dimensional Ag nanoislands were prepared on LPCVD-grown monolayer graphene on Si. Here we describe the enhanced interaction between light and silver nanoislands deposited on graphene as a tool for trace detection of molecular entities, especially in the area of bio-molecule detection and characterisation. This enhanced interaction is due to localised surface plasmons generated in silver nano islands that we fabricate by simple means of metal deposition on top of graphene. We have achieved femto molar detection limit of L-Tryptophan on monolayer graphene.

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References

  1. L.M. Malard, M.A. Pimenta, G. Dresselhaus, M.S. Dresselhaus, Raman spectroscopy in graphene. Phys. Rep. 473, 51–87 (2009)

    Article  ADS  Google Scholar 

  2. A.K. Geim, K.S. Novoselov, The rise of graphene. Nat. Mater. 6, 183–191 (2007)

    Article  ADS  Google Scholar 

  3. E.C. Le Ru, E. Blackie, M. Meyer, Surface enhanced raman scattering enhancement factors: a comprehensive study. J. Phys. Chem. C 111, 113794–113803 (2007)

    Google Scholar 

  4. M. Fleischm, P.J. Hendra, A.J. McQuilla, Raman Spectra of pyridine absorbed at a silver electrode. Chem. Phys. Lett. 26(2), 163–166 (1974)

    Article  ADS  Google Scholar 

  5. A.X. Wang, Review of recent progress of plasmonic materials and nano-structure for surface-enhanced Raman scattering materials. Materials 8, 3024–3305 (2015)

    Article  ADS  Google Scholar 

  6. J. Theiss, P. Pavaskar, P.M. Echternach, R.E. Muller, S.B. Cronin, Plasmonic nanoparticle arrays with nanometer separation for high-performance SERS substrates. Nano Lett. 10(8), 2749–2754 (2010)

    Article  ADS  Google Scholar 

  7. A. Urich, A. Pospischil, M.M. Furchi, D. Daitze, K. Unterrainer, T. Mueller, Silver nanoisland enhanced Raman interaction in graphene. Appl. Phys. Lett. 101, 153113 (2012)

    Article  ADS  Google Scholar 

  8. A.C. Ferrari, D.M. Bosko, Raman Spectroscopy as a versatile tool for studying properties of graphene. Nat. Nanotechnol. 8, 235 (2013)

    Article  ADS  Google Scholar 

  9. J. Lee, K.S. Novoselov, H.S. Shin, Interaction between metal and graphene: dependence on number of layer of graphene. ACS Nano 05, 608–612 (2011)

    Article  Google Scholar 

  10. M.K. Hossain, Y. Ozaki, Surface enhanced Raman Scattering; facts and inline trends. Curr. Sci. 97, 192–201 (2009)

    Google Scholar 

  11. H.R. Stuart, D.G. Hall, Island size effects in nano particle-enhanced photodetectors. Appl. Phys. Lett. 73, 3815 (1998)

    Article  ADS  Google Scholar 

  12. E.C. Ru, E. Blackie, M. Meyer, P.G. Etchegoin, Surface enhanced Raman Scattering enhancement factors: a comprehensive study. J. Phys. Chem. C 111(37), 13794–13803 (2007)

    Article  Google Scholar 

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Acknowledgements

The authors would like to thank the Director of the Solid State Physics Laboratory (SSPL) for giving permission to publish this work.

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Correspondence to Preeti Garg .

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Garg, P., Sahoo, P., Raman, R., Soni, R.K. (2019). Surface Enhanced IR Absorption and Raman Detection of Tryptophan Amino Acids Over Silver Nanoislands Deposited on Graphene. In: Sharma, R., Rawal, D. (eds) The Physics of Semiconductor Devices. IWPSD 2017. Springer Proceedings in Physics, vol 215. Springer, Cham. https://doi.org/10.1007/978-3-319-97604-4_21

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