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International Conference on Nanotechnology and Nanomaterials

NANO 2017: Nanochemistry, Biotechnology, Nanomaterials, and Their Applications pp 165–176Cite as

High-Temperature Electrochemical Synthesis of Nanostructured Coatings of Molybdenum (Tungsten)–Nickel (Cobalt) Alloys and Intermetallic Compounds

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Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 214))

Abstract

The electrochemical behavior of nickel and cobalt in a tungstate melt and the effect of the electrolysis conditions on the composition and structure of the deposits of the nickel (cobalt)–molybdenum (tungsten) alloys and intermetallic compounds in oxide tungstate melts are studied. As the molybdenum (tungsten) concentration in the melt increases or the nickel (cobalt) concentration decreases, the phase composition of the cathodic deposits changes from nickel through nickel (cobalt)–molybdenum (tungsten) alloys and intermetallics of different compositions to pure molybdenum (tungsten).

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Abbreviations

C :

Electroactive particle concentration

E :

Potential value

E p :

Peak potential

E p/2 :

Half-peak potential

F :

Faraday constant

H :

Microhardness

I :

Current

i :

Current value

i d :

Diffusion current

i p :

Peak current

M:

Metal atom

n :

Electron number

R:

Universal gas constant

T :

Thermodynamic temperature

v :

Polarization rate

V :

Voltage

References

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Acknowledgments

Authors of the present paper acknowledge support of all the Dumlupinar University and the University “Ukraine” staff in conducting scientific researches and writing this paper.

Competing Interests

Authors of the present paper have no competing interests.

Authors’ Contributions

Authors of the present paper have made equal contributions in conducting scientific researches and writing this paper.

Funding

Authors of the present paper have not used any external sources of funding in addition to regular financing for scientific investigations provided by the Dumlupinar University and by the University “Ukraine.”

Author information

Authors and Affiliations

  1. University “Ukraine”, Kyiv, Ukraine

    Viktor Malyshev, Nataliia Uskova, Dmytro Shakhnin, Tetiana Lukashenko, Viktor Antsibor & Zafer Ustundag

  2. Dumlupinar University, Kutahya, Turkey

    Viktor Malyshev, Nataliia Uskova, Dmytro Shakhnin, Tetiana Lukashenko, Viktor Antsibor & Zafer Ustundag

Authors
  1. Viktor Malyshev
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  2. Nataliia Uskova
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  3. Dmytro Shakhnin
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  4. Tetiana Lukashenko
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  5. Viktor Antsibor
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  6. Zafer Ustundag
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Editor information

Editors and Affiliations

  1. National Academy of Sciences of Ukraine, Institute of Physics, Kyiv, Ukraine

    Olena Fesenko

  2. National Academy of Sciences of Ukraine, Institute of Physics, Kyiv, Ukraine

    Leonid Yatsenko

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Malyshev, V., Uskova, N., Shakhnin, D., Lukashenko, T., Antsibor, V., Ustundag, Z. (2018). High-Temperature Electrochemical Synthesis of Nanostructured Coatings of Molybdenum (Tungsten)–Nickel (Cobalt) Alloys and Intermetallic Compounds. In: Fesenko, O., Yatsenko, L. (eds) Nanochemistry, Biotechnology, Nanomaterials, and Their Applications. NANO 2017. Springer Proceedings in Physics, vol 214. Springer, Cham. https://doi.org/10.1007/978-3-319-92567-7_10

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