Skip to main content

Non-interacting Many-Particle Systems

  • Chapter
Advanced Undergraduate Quantum Mechanics
  • 2093 Accesses

Abstract

Quantum mechanical properties of a single particle are an important starting point for studying quantum mechanics, but in real experimental and practical situations, you will rarely deal with just a single particle. Most frequently you encounter systems consisting of many (from two to infinity) interacting particles. The main difficulty in dealing with many-particle systems comes from a significantly increased dimensionality of space, where all possible states of such systems reside. In Sect. 9.4 you saw that the states of the system of two spins belong to a four-dimensional spinor space. It is not too difficult to see that the states of a system consisting of N spins would need a 2N-dimensional space to fit them all. Indeed, adding each new spin 1/2 particle with two new spin states, you double the number of basis vectors in the respective tensor product, and even the system of as few as ten particles inhabits a space requiring 1024 basis vectors. More generally, imagine that you have a particle which can be in one of M mutually exclusive states, represented obviously by M mutually orthogonal vectors (I will call them single-particle states), which can be used as a basis in this single-particle M-dimensional space. You can generate a tensor product of single-particle spaces by stacking together M basis vectors from each single-particle space. Naively you might think that the dimension of the resulting space will be MN, but it is not always so. The reality is more interesting, and to get the dimensionality of many-particle states correctly, you need to dig deeper into the concept of identity of quantum particles.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 54.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 69.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 99.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Notes

  1. 1.

    Energy levels in a semiconductor are organized in bands separated by large gaps. The band, all energy levels of which are filled with electrons, is called a valence band, and the closest to its empty band is a conduction band. When an electron gets excited from the valence band, the conduction band acquires an electron, and a valence band losses an electron, which leaves in its stead a positively charged hole. Here you have an electron-hole pair behaving as real positively and negatively charged spin 1/2 particles.

  2. 2.

    “Occupied” in this context means that a given orbital participates in the formation of a given many-particle state.

  3. 3.

    I have to remind you that while the hydrogen energy levels are degenerate with respect to l, for other atoms this is not true because of the interaction with other electrons.

  4. 4.

    If instead of periodic boundary conditions you would use the particle-in-the-box boundary conditions requiring that the wave function vanishes at the boundary of the region Lx × Ly × Lz, you would have ended up with pi = πni/Li, where ni now can only take positive values because wave functions \(\sin \left (\pi n_{1}x/L_{x}\right )\sin \left (\pi n_{2}y/L_{y}\right )\sin \left (\pi n_{3}z/L_{z}\right )\) with positive and negative values of ni represent the same function, while function \(\exp i\left (\frac {2\pi }{L_{x}}n_{1}x+\frac {2\pi }{L_{y}}n_{2}y+\frac {2\pi }{L_{z}}n_{3}z\right )\) with positive and negative indexes represents two linearly independent states. As a result, Eq. 11.50 when used in this case would have an extra factor 1/8 reflecting the fact that only 1/8 of a sphere correspond to points with all positive coordinates.

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

Copyright information

© 2018 Springer International Publishing AG, part of Springer Nature

About this chapter

Cite this chapter

Deych, L.I. (2018). Non-interacting Many-Particle Systems. In: Advanced Undergraduate Quantum Mechanics. Springer, Cham. https://doi.org/10.1007/978-3-319-71550-6_11

Download citation

Publish with us

Policies and ethics