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Anticorrosion and Adsorption Mechanism of Rhizophora mangle L. Leaf-Extract on Steel-Reinforcement in 3.5% NaCl-Immersed Concrete

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Proceedings of the 3rd Pan American Materials Congress

Part of the book series: The Minerals, Metals & Materials Series ((MMMS))

Abstract

This paper studies anticorrosion and adsorption mechanism of Rhizophora mangle L. leaf-extract on steel-reinforcement in concrete immersed in 3.5% NaCl test-environment. Open circuit potential, macrocell current and corrosion rate measurements were obtained from steel-reinforced concrete samples, into which different concentrations of the leaf-extract was admixed during casting, and which were immersed in the saline/marine simulating-environment. Corrosion noise resistance was modelled as the ratio of standard deviation of the corrosion potential to the standard deviation of the corrosion current. Analyses of these test-results showed that the corrosion rate from linear polarization resistance exhibited very good correlation with the noise resistance model for the leaf-extract concentrations studied. Further analyses identified Rhizophora mangle L. leaf-extract concentration with excellent corrosion inhibition efficiency performance on steel-reinforcement. Also data of anticorrosion performance followed the Langmuir adsorption isotherm model, which indicated physisorption as the prevalent corrosion-protection mechanism by the Rhizophora mangle L. leaf-extract on steel-rebar in concrete immersed in the 3.5% NaCl, simulating saline/marine environment.

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Author information

Authors and Affiliations

  1. Mechanical Engineering Department, Covenant University, Ota, 112001, Nigeria

    Joshua Olusegun Okeniyi, Olugbenga Adeshola Omotosho & Cleophas Akintoye Loto

  2. Chemical, Metallurgical and Materials Engineering Department, Tshwane University of Technology, Pretoria, 0001, South Africa

    Cleophas Akintoye Loto & Abimbola Patricia Idowu Popoola

Authors
  1. Joshua Olusegun Okeniyi
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  2. Olugbenga Adeshola Omotosho
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  3. Cleophas Akintoye Loto
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  4. Abimbola Patricia Idowu Popoola
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Corresponding author

Correspondence to Joshua Olusegun Okeniyi .

Editor information

Editors and Affiliations

  1. Dept. of Nanoengineering, MC 0448, University of California-San Diego Dept. of Nanoengineering, MC 0448, LA JOLLA, California, USA

    Marc André Meyers

  2. ESFM-IPN , Mexico City, Mexico

    Hector Alfredo Calderon Benavides

  3. UTN-National University of Technology , Buenos Aires, Argentina

    Sonia P Brühl

  4. Universidad de Antioquia , Medellín, Colombia

    Henry A Colorado

  5. Pratt & Whitney Canada , Longueuil, Canada

    Elvi Dalgaard

  6. Military Institute of Engineering , Rio de Janerio, Brazil

    Carlos Nelson Elias

  7. Universidade Federal de Minas Gerais , Belo Horizonte, Brazil

    Roberto B Figueiredo

  8. Ternium Mexico , Nuevo León, Mexico

    Omar Garcia-Rincon

  9. Division of Materials Sci & Engg, Hanyang University Division of Materials Sci & Engg, Seoul, Korea (Republic of)

    Megumi Kawasaki

  10. Dept. Engineering & the Environment, University of Southampton Dept. Engineering & the Environment, Southampton, United Kingdom

    Terence G. Langdon

  11. University of Concepción , Concepción, Chile

    R.V. Mangalaraja

  12. Universidad Nacional de Ingeniería , Lima, Peru

    Mery Cecilia Gomez Marroquin

  13. Federal University of Rio de Janeiro , Rio de Janeiro, Brazil

    Adriana da Cunha Rocha

  14. Dept Chemical Engg & Sci, University of California, Irvine Dept Chemical Engg & Sci, Irvine, California, USA

    Julie M Schoenung

  15. Universidade Federal Fluminense , Niterói, Brazil

    Andre Costa e Silva

  16. Mechanical Engineering, University of Waterloo Mechanical Engineering, WATERLOO, Ontario, Canada

    Mary Wells

  17. ETH Zurich , Zürich, Switzerland

    Wen Yang

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Okeniyi, J.O., Omotosho, O.A., Loto, C.A., Popoola, A.P.I. (2017). Anticorrosion and Adsorption Mechanism of Rhizophora mangle L. Leaf-Extract on Steel-Reinforcement in 3.5% NaCl-Immersed Concrete. In: Meyers, M., et al. Proceedings of the 3rd Pan American Materials Congress. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-52132-9_17

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