Abstract
Alkaline activated binders (AAB), which are the results of reaction between source aluminosilicates and alkaline activator, are an environmentally friendly binder that exhibits high compressive strength (CS). This study explores the effects of different combinations of ultrafine treated palm oil fuel ash (u-TPOFA) and fly ash (FA) on the compressive strength and structural composition changes of the u-TPOFA-FA alkali-activated binary binder mortar (AABBM). The alkaline activated mortar (AAM) was synthesized using mixtures of u-TPOFA and FA in varying ratio of u-TPOFA:FA of (100:0), (90:10), (80:20), (70:30), (50:50), (25,75) and (0:100), respectively, and the alkaline activating solution consist of a combination of Na2SiO3 and NaOH. The combination and concentration of Na2SiO3 and NaOH were constant for all mixtures. Primarily, it was found that mixture with a combination of u-TPOFA:FA of 25:75 gain the highest compressive strength (CS) of 54.82 MPa at 28 days. Therefore, the replacement of SiO2 from u-TPOFA by Al2O3 provided by FA contributes towards significant CS enhancement due to the formation of more N-A-S-H gel binder. The result observed for the gel binder formation was emphasized with XRD and FTIR analyses.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
ASTM C109/C109M-12 (2012) Standard test method for compressive strength of hydraulic cement mortars (Using 2-in [50 mm] cube specimen. Annual book of ASTM standards
ASTM C 305 (2013) Standard practice for mechanical mixing of hydraulic cement pastes and mortars of plastic consistency. Annual book of ASTM standards
Criado M, Palomo A, Fernández-Jiménez A (2005) Alkali activation of fly ashes. Part 1: effect of curing conditions on the carbonation of the reaction products. Fuel 84(16):2048–2054
Davidovits J (1989) Geopolymers and geopolymeric materials. J Therm Anal Calorim 35(2):429–441
Davidovits J (2002) 30 years of successes and failures in geopolymer applications. Market trends and potential breakthroughs. In: Keynote conference on geopolymer conference
de Vargas AS, Dal Molin DC, Masuero ÂB, Vilela AC, Castro-Gomes J, de Gutierrez RM (2014) Strength development of alkali-activated fly ash produced with combined NaOH and Ca (OH) 2 activators. Cement Concr Compos 53:341–349
Duxson PLG, van Deventer JSJ (2006) In: Davidovits J (ed) Green chemistry. Geopolymer, green chemistry and sustainable development solutions. Proceedings of the world congress of geopolymer 2005, St. Quentin, France, pp 189–194
Elbasir OM, Johari M, Azmi M, Ahmad ZA (2015) Influence of initial silica modulus of Na2SiO3 on the compressive strength of alkali activated ultrafine palm oil fuel ash based mortar. Appl Mech Mater Trans Tech Publ
Elbasir OMM, Megat Johari MA, Ahmad ZA (2019) Effect of fineness of palm oil fuel ash on compressive strength and microstructure of alkaline activated mortar. Eur J Environ Civ Eng 23(2):136–152
García-Lodeiro I, Fernández-Jiménez A, Palomo A, Macphee DE (2010) Effect of calcium additions on N–A–S–H cementitious gels. J Am Ceram Soc 93(7):1934–1940
Islam A, Alengaram UJ, Jumaat MZ, Bashar II (2014) The development of compressive strength of ground granulated blast furnace slag-palm oil fuel ash-fly ash based geopolymer mortar. Mater Des 1980–2015(56):833–841
Komnitsas K, Zaharaki D, Perdikatsis V (2007) Geopolymerisation of low calcium ferronickel slags. J Mater Sci 42(9):3073–3082
Kumar S, Kristály F, Mucsi G (2015) Geopolymerisation behaviour of size fractioned fly ash. Adv Powder Technol 26(1):24–30
Mijarsh M, Johari MM, Ahmad ZA (2015) Effect of delay time and Na2SiO3 concentrations on compressive strength development of geopolymer mortar synthesized from TPOFA. Constr Build Mater 86:64–74
Mijarsh MJA, Megat Johari MA, Ahmad ZA (2014) Synthesis of geopolymer from large amounts of treated palm oil fuel ash: application of the Taguchi method in investigating the main parameters affecting compressive strength. Constr Build Mater 52:473–481
Mijarsh MJA, Megat Johari MA, Ahmad ZA (2015) Compressive strength of treated palm oil fuel ash based geopolymer mortar containing calcium hydroxide, aluminum hydroxide and silica fume as mineral additives. Cement Concr Compos 60:65–81
Nataraja M, Das L (2010) Concrete mix proportioning as per IS 10262: 2009-comparison with IS 10262: 1982 and ACI 211.1-91. Indian Concr J 64–70
Phair JW, Smith JD, Van Deventer JSJ (2003) Characteristics of aluminosilicate hydrogels related to commercial “Geopolymers”. Mater Lett 57(28):4356–4367
Phul AA, Memon MJ, Shah SNR, Sandhu AR (2019) GGBS and fly ash effects on compressive strength by partial replacement of cement concrete. Civ Eng J 5(4):913–921
Ranjbar N, Mehrali M, Alengaram UJ, Metselaar HSC, Jumaat MZ (2014) Compressive strength and microstructural analysis of fly ash/palm oil fuel ash based geopolymer mortar under elevated temperatures. Constr Build Mater 65:114–121
Ranjbar N, Mehrali M, Behnia A, Alengaram UJ, Jumaat MZ (2014) Compressive strength and microstructural analysis of fly ash/palm oil fuel ash based geopolymer mortar. Mater Des 59:532–539
Silva PD, Sagoe-Crenstil K, Sirivivatnanon V (2007) Kinetics of geopolymerization: role of Al2O3 and SiO2. Cem Concr Res 37(4):512–518
ul Haq E, Kunjalukkal Padmanabhan S, Licciulli A (2014) Synthesis and characteristics of fly ash and bottom ash based geopolymers–a comparative study. Ceram Int 40(2):2965–2971
Wallah S, Rangan BV (2006) Low-calcium fly ash-based geopolymer concrete: long-term properties. Curtin University of Technology, Perth, p 107
Xu H, Gong W, Syltebo L, Izzo K, Lutze W, Pegg IL (2014) Effect of blast furnace slag grades on fly ash based geopolymer waste forms. Fuel 133:332–340
Yusuf MO, Johari MAM, Ahmad ZA, Maslehuddin M (2014) Effects of addition of Al(OH)3 on the strength of alkaline activated ground blast furnace slag-ultrafine palm oil fuel ash (AAGU) based binder. Constr Build Mater 50:361–367
Yusuf MO, Megat Johari MA, Ahmad ZA, Maslehuddin M (2014) Evolution of alkaline activated ground blast furnace slag–ultrafine palm oil fuel ash based concrete. Mater Des 55:387–393
Zhang Z, Li L, Ma X, Wang H (2016) Compositional, microstructural and mechanical properties of ambient condition cured alkali-activated cement. Constr Build Mater 113:237–245
Acknowledgements
The authors gratefully acknowledge the Ministry of Higher Education, Malaysia and Universiti Sains Malaysia for providing financial support through the Fundamental Research Grant Scheme (203/PAWAM/6071365) and University Bridging Grant Scheme (304/PAWAM/6316313), respectively for the undertaking of the research work. Special thanks are due to United Palm Oil Industries for providing the palm oil fuel ash and Lafarge Malaysia Berhad, (Associated Pan Malaysia Cement Sdn. Bhd.) for providing the fly ash.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2020 Springer Nature Switzerland AG
About this paper
Cite this paper
Elbasir, O.M.M., Johari, M.A.M., Mijarsh, M.J.A., Ahmad, Z.A. (2020). Investigation on Strength Enhancement of U-TPOFA Based Binary Blended Alkali Activated Mortar Through Addition of Fly Ash. In: Mohamed Nazri, F. (eds) Proceedings of AICCE'19. AICCE 2019. Lecture Notes in Civil Engineering, vol 53. Springer, Cham. https://doi.org/10.1007/978-3-030-32816-0_85
Download citation
DOI: https://doi.org/10.1007/978-3-030-32816-0_85
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-32815-3
Online ISBN: 978-3-030-32816-0
eBook Packages: EngineeringEngineering (R0)