Abstract
Olive mill wastewater (OMW) includes high concentrations of polyphenolic organics. Phenolic compounds in OMW cannot be removed with conventional removal processes. In this study, the polyphenols were removed with nano-ZnO–SiO2 under sunlight. The effects of nano-composite levels, irradiation times, and pH on the phenol removals were investigated. The aim of this study is to photodegrade the total phenol and three polyphenols (gallic acid, para-coumaric acid, t-paracoumaric acid) in the OMW using nano-ZnO–SiO2. The behaviors of elevated nano-ZnO–SiO2 doses (0.5, 1, 3, 5 and 10 g/L), the photodegradation intervals (8, 16, 24 and 36 h) and elevated pHs (4, 7 and 10) during sunlight were researched on the removals of polyphenols in the OMW. The best phenol yield was 73% using 3 g/L nano-ZnO–SiO2 under 24 h sunlight at pH 4. The maximum yields for gallic acid, para-coumaric acid, and t-para-coumaric acid were 90%, 5%, and 5%, respectively.
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References
Stasinakis AS, Elia I, Petalas AV, Halvadakis CP (2008) Removal of total phenols from olive-mill wastewater using an agricultural by-product, olive pomace. J Hazard Mater 160:408–413
Jahangiri M, Rahimpour A, Nemati S, Alimohammady M (2014) Recovery of poly-phenols from olive mill wastewater by nanofiltration. Cell Chem Technol 50(9–10):961–966
Rosello-Soto E, Koubaa M, Moubarik AP, Lopes R, Saraiva A, Boussetta J, Grimi N, Barba JF (2015) Emerging opportunities for the effective valorization of wastes and by-products generated during olive oil production process: nonconventional methods for the recovery of high-added value compounds. Trends Food Sci Technol 45:296–310
Bertin L, Ferri F, Scoma A, Marchetti L, Fava F (2011) Recovery of high added value natural polyphenols from actual olive mill wastewater through solid phase extraction. Chem Eng J 171:1287–1293
Basta AH, Fierro V, El-Saied H, Celzard A (2009) 2-Steps KOH activation of rice straw: an efficient method for preparing high-performance activated carbons. Bioresour Technol 100:3941–3947
Pagnanelly F, Sara M, Luigi T (2008) New biosorbent materials for heavy metal removal: development guided by active site characterization. Water Res 42:2953–2962
Annab H, Fiol N, Villaescusa I, Essamri A (2019) A proposal for the sustainable treatment and valorisation of olive mill wastes. J Environ Chem Eng 7:102–803
Mostafaa H, Iqdiam BM, Abuagela M, Marshall MR, Pullammanappallil P, Goodrich-Schneiderb R (2018) Treatment of olive mill wastewater using high power ultrasound (HPU) and electro-fenton (EF) method. Chem Eng Process Process Intensif 131:131–136
Deeb AA, Fayyad MK, Alawi MA (2012) Separation of polyphenols from Jordanian olive oil mill wastewater. Hindawi Publishing Corporation Chromatography Research International Volume, Article ID 812127, 8 p
Mulinnacci N, Romani A, Galardi C, Pinelli P, Giaccherini C, Vincieri FF (2001) Polyphenolic content in olive oil wastewaters and related olive samples. J Agric Food Chem 49:3509–3514
Leouıfoudı I, Zyad A, Mouse HA, Amechrouq A, Mbarkı M, Oukerrou MA (2013) Identification and characterisation of phenolic compounds extracted from Moroccan olive mill wastewater. Food Sci Technol Camp 34(2):249–257
Sangeeta M, Renuka L, Karthik KV, Ravishankar R, Anantharaju KS (2017) Synthesis of ZnO, MgO and ZnO/MgO by solution combustion method: characterization and photocatalytic studies. Mater Today: Proc 4(11):11791–11798
Lee HB, Yoo YM, Han YH (2006) Characteristic optical properties and synthesis of gold–silica core–shell colloids. Scripta Mater 55:1127–1129
Zhai J, Tao X, Pu Y, Zeng X, Chen J (2010) Core/shell structured ZnO/SiO2 nanoparticles: preparation, characterization and photocatalytic property. Appl Surf Sci 257:393–397
Mohamed RM, Baeissa ES, Mkhalid IA, Al-Rayyani MA (2013) Optimization of preparation conditions of ZnO–SiO2 xerogel by sol–gel technique for photodegradation of methylene blue dye. Appl Nanosci 3:57–63
Ali MA, İsmail AA, Najmy R, Al-Hajry A (2014) Preparation and characterization of ZnO–SiO2 thin films as highly efficient photocatalyst. J Photochem Photobiol A 275:37–46
Areerob Y, Cho JY, Jang WK, Oh WC (2018) Enhanced sonocatalytic degradation of organic dyes from aqueous solutions by novel synthesis of mesoporous Fe3O4-graphene/ZnO@SiO2 nanocomposites. Ultrason Sonochem 41:267–278
Nezamzadeh-Ejhieh A, Bahrami M (2014) Investigation of the photocatalytic activity of supported ZnO–TiO2 on clinoptilolite nano-particles towards photodegradation of wastewater-contained phenol. Desalination Water Treat 55(4):1096–1104
Shah N, Claessyns F, Rimmer S, Arain MB, Rehan T, Wazwaz A, Ahmad MW, Ul-Islam M (2016) Effective role of magnetic core-shell nanocomposites in removing organic and inorganic wastes from water. Recent Pat Nanotechnol 10(3):202–212
Rabahi A, Assadi AA, Nasrallah N, Bouzaza A, Maachi R, Wolbert D (2018) Photocatalytic treatment of petroleum industry wastewater using recirculating annular reactor: comparison of experimental and modeling toluene removal. Environ Sci Pollut Res 1–12
Tuchmantel W, Kozikowski AP, Romanczyk LJ Jr (1999) Studies inpolyphenolchemistryandbioactivity. 1. Preparation of building blocks from (+) catechin. Procyanidin formation. Synthesis of the cancer cell growth inhibitor, 3-O-galloyl-(2R,3R)-epicatechin-4β,8-[3-O-galloyl-(2R,3R) epicatechin]. J Am Chem Soc 121:12073–12081
Flight I, Clifton P (2006) Cereal grains and legumes in the prevention of coronary heart disease and stroke: a review of the literature. Eur J Clin Nutr 60(10):1145–1159
Lu Z, Nie G, Belton PS, Tang H, Zhao B (2006) Structure-activity relationship analysis of antioxidant ability and neuroprotective effect of gallic acid derivatives. Neurochem Int 48(4):263–274
Tuck KL, Hayball PJ, Stupans I (2002) Structural characterisation of the metabolites of hydroxytyrosol, the principal phenolic component in olive oil, in rats. J Agric Food Chem 50:2404–2409
Visioli F, Poli A, Galli C (2002) Antioxidant and other biological activities of phenols from olives and olive oil. Med Res Rev 22(1):65–75
Bendini A, Cerretani L, Carrasco-Pancorbo A, Gomez-Caravaca AM, Segura Carretero A, Fernandez-Gutierrez A (2007) Phenolic molecules in virgin olive oils: a survey of their sensory properties, health effects, antioxidant activity and analytical methods. An overview of the last decade. Molecules 12:1679–1719
Kiritsakis AK (1998) Flavor components of olive oil—a review. J Am Oil Chem Soc 75:673–681
Medina E, Brenes M, Romero C, García A, De Castro A (2007) Mainantimicrobials compounds in table olives. J Agric Food Chem 55:9817–9823
Servili M, Selvaggini R, Esposto S, Taticchi A, Montedoro G, Morozzi M (2004) Health and sensory properties of virgin olive oil hydrophylic phenols: agronomic and technological aspects of production that affect their occurrence in the oil. J Chromatogr A 1054:113–127
Tura D, Gigliotti C, Pedo S, Failla O, Bassi D, Serraiocco A (2007) Influence of cultivar and site of cultivation on levels of lipophilic and hydrophilic antioxidants in virgin olive oils (Olea europaea L.) and correlations with oxidative stability. Sci Hortic 112:108–119
Vinha A, Ferreres F, Silva B, Valentão P, Gonçalves A, Pereira J, Oliveira M, Sebra R, Andrade P (2005) Phenolic profiles of Portuguese olive fruits (Olea europaea L.): Influences of cultivar and geographical origin. Food Chem 89:561–568
Kalua CM, Allen MS, Bedgood DR, Bishop AG, Prenzler PD (2005) Discrimination of olive oils and fruits into cultivars and maturity stages based on phenolic and volatile compounds. J Agric Food Chem 53:8054–8062
Gomez-Alonso S, Salvador MD, Fregapane G (2002) Phenolic compounds profile of Cornicabra virgin olive oil. J Agric Food Chem 50:6812–6817
Tovar MJ, Motilva MJ, Romero MP (2001) Changes in the phenolic composition of virgin olive oil from young trees (Olea europaea L. cv. Arbequina) grown under linear irrigation strategies. J Agric Food Chem 49:5502–5508
Ranalli A, Contento S, Schiavone C, Simone N (2001) Malaxing temperature affects volatile and phenol composition as well as other analytical features of virgin olive oil. Eur J Lipid Sci Technol 103:228–238
Genick UK, Borgstahl GE, Ng K, Ren Z, Pradervand C, Burke PM, Srajer V, Teng TY, Schildkamp W, McRee DE, Moffat K, Getzoff ED (1997) Structure of a protein photocycle intermediate by millisecond time-resolved crystallography. Science 275(5305):1471–1475
Hoff WD, Düx P, Hård K, Devreese B, Nugteren-Roodzant IM, Crielaard W, Boelens R, Kaptein R, Van Beeumen J, Hellingwerf KJ (1994) Thiol ester-linked p-coumaric acid as a new photoactive prosthetic group in a protein with rhodopsin-like photochemistry. Biochemistry 33(47):13959–13962
Premvardhan LL, Buda F, Van Der Horst MA, Lührs DC, Hellingwerf KJ, Van Grondelle R (2004) Impact of photon absorption on the electronic properties of p-coumaric acid derivatives of the photoactive yellow protein chromophore. J Phys Chem B 108(16):5138–5148
Hellingwerf KJ (2000) Key issues in the photochemistry and signalling-state formation of photosensor proteins. J Photochem Photobiol B Biol 54(2–3):94–102
Yamaguchi S, Kamikubo H, Kurihara K, Kuroki R, Niimura N, Shimizu N, Yamazaki Y, Kataoka M (2009) Low-barrier hydrogen bond in photoactive yellow protein. Proc Natl Acad Sci USA 106(2):440–444
Capasso R, Evidente A, Schivo L, Orru G, Marcialis MA, Cristinzio G (1995) Antibacterial polyphenols from olive oil mill waste waters. J Appl Bacteriol 79(4):393–398
Garcia-Castello E, Cassano A, Criscuoli A, Conidi C, Drioli E (2010) Recovery and concentration of polyphenols from olive mill wastewaters by integrated membrane system. Watr Res 44(13):3883–3892
Casa R, D’Annibale A, Pierucetti F (2003) Reduction of the phenolic components in olive-mill wastewater by enzymatic treatment and its impact on durum wheat (Titricum durum Desf.) germinability. Chemosphere 50:959–966
Kashıf N, Ouyang F (2009) Parameters effect on heterogeneous photocatalyse degradation of phenol in aqueous dispersion of TiO2. J Environ Sci 21:527–533
Qamar M, Muneer M, Bahneman D (2006) Heterogeneous photocatalysed degradation of two selected pesticide derivatives, triclopyr and daminozid in aqueous suspensions of titanium dioxide. J Environ Manag 80:99–106
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Ulusoy, Ç., Sponza, D.T. (2020). Removal of Polyphenolic Compounds from Olive Mill Wastewater with Sunlight Irradiation Using Nano-Zno–Sio2 Composite. In: Dincer, I., Colpan, C., Ezan, M. (eds) Environmentally-Benign Energy Solutions. Green Energy and Technology. Springer, Cham. https://doi.org/10.1007/978-3-030-20637-6_19
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DOI: https://doi.org/10.1007/978-3-030-20637-6_19
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