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Sinterability of Y-Doped BaZrO3 with Micro- and Nano-CaO Additives and Its Interaction with Titanium Alloy

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Characterization of Minerals, Metals, and Materials 2019

Part of the book series: The Minerals, Metals & Materials Series ((MMMS))

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Abstract

The effects of micro - and nano-CaO additive on the sinterability of Y-doped BaZrO3 and its interface reaction with titanium alloys were investigated. The 10 mol% micro - and nano-CaO is doped into BaZr0.97Y0.03O3 (BZY), respectively. The sinterability of BZY with micro - and nano-CaO was investigated by density analyzer, SEM and XRD . The relative density of BZY pellets with micro - and nano-CaO addition improved from 88% to 97.5% and 98% at 1750 °C for 6 h, respectively. XRD and SEM (BSE) show no secondary phase in the two sintered ceramics, which indicates that a single phase of cubic perovskite-type structure of Ca-modified BZY can be obtained. After melted titanium alloys , the erosion layer is 70 μm with nano-CaO addition, while a 310 μm erosion layer with micro -CaO addition. This shows that nano-CaO can be used as an appropriate sintering aid and can prevent the Y-doped BaZrO3 refractory from erosion.

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Acknowledgements

The authors thank the National Natural Science Foundation of China (No.: 51574164, U1760109); Basic Major Research Program of Science and Technology Commission Foundation of Shanghai (No.: 14JC1491400). China Postdoctoral Science Foundation funded project (2018M632081).

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Authors and Affiliations

  1. State Key Laboratory of Advanced Special Steel, Shanghai Key Laboratory of Advanced Ferro Metallurgy, School of Materials Science and Engineering, Shanghai University, Shanghai, 200072, China

    Juyun Kang, Guangyao Chen, Baobao Lan, Xionggang Lu & Chonghe Li

  2. Materials Genome Institute of Shanghai University, Shanghai, 201900, China

    Guangyao Chen

  3. Shanghai University Library, Shanghai, China

    Shihua Wang

  4. Shanghai Special Casting Engineering Technology Research Center, Shanghai, 201605, China

    Xionggang Lu & Chonghe Li

Authors
  1. Juyun Kang
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  2. Guangyao Chen
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  3. Baobao Lan
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  4. Shihua Wang
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  5. Xionggang Lu
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  6. Chonghe Li
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Correspondence to Chonghe Li .

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Editors and Affiliations

  1. Michigan Technological University, Houghton, MI, USA

    Bowen Li

  2. CanmetMATERIALS, Hamilton, ON, Canada

    Jian Li

  3. Al-Isra University, Amman, Jordan

    Shadia Ikhmayies

  4. ArcelorMittal Global R&D, East Chicago, IN, USA

    Mingming Zhang

  5. Middle East Technical University, Ankara, Turkey

    Yunus Eren Kalay

  6. Los Alamos National Laboratory, Los Alamos, NM, USA

    John S. Carpenter

  7. Michigan Technological University, Houghton, MI, USA

    Jiann-Yang Hwang

  8. Military Institute of Engineering, Rio de Janeiro, Brazil

    Sergio Neves Monteiro

  9. Chongqing University, Chongqing, China

    Chenguang Bai

  10. UNSW Canberra, Campbell, ACT, Australia

    Juan P. Escobedo-Diaz

  11. Free University of Bozen-Bolzano, Bolzano, Italy

    Pasquale Russo Spena

  12. Naval Research Laboratory, Washington, DC, USA

    Ramasis Goswami

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Kang, J., Chen, G., Lan, B., Wang, S., Lu, X., Li, C. (2019). Sinterability of Y-Doped BaZrO3 with Micro- and Nano-CaO Additives and Its Interaction with Titanium Alloy. In: Li, B., et al. Characterization of Minerals, Metals, and Materials 2019. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-05749-7_7

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