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From Phosphorus-Containing Macrocycles to Phosphorus-Containing Dendrimers

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Phosphorous Heterocycles I

Part of the book series: Topics in Heterocyclic Chemistry ((TOPICS,volume 20))

Abstract

Various methods of synthesis of phosphorus-containing macrocycles are described. They are obtained in good to quantitative yields, thanks to the presence of phosphorhydrazone (P–N–N=) linkages in their structure. Multi-macrocyclic species and cryptands possessing the same linkage are also described. Various types of reactions, including complexation properties of the macrocycles are also reviewed. In the last part, the use of the same linkage for the elaboration of phosphorus-containing dendrimers is described, with emphasis on dendrimers incorporating macrocycles in some part of their structure (terminal groups, core or interior).

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Notes

  1. 1.

    Dendrimers are a very special type of polymers, hyperbranched and multifunctional, having a perfectly defined structure, due to their step by step synthesis (never by polymerization)

  2. 2.

    This notation does not refer to the mechanism but to the number of partners that associate in the macrocycle

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Authors and Affiliations

  1. LCC (Laboratoire de Chimie de Coordination), Centre National de la Recherche Scientifique(CNRS), 205, route de Narbonne, 31077, Toulouse, France

    Anne-Marie Caminade

  2. Université de Toulouse, UPS, INPT; LCC, 31077, Toulouse, France

    Anne-Marie Caminade & Jean-Pierre Majoral

Authors
  1. Anne-Marie Caminade
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  2. Jean-Pierre Majoral
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Correspondence to Anne-Marie Caminade .

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Editors and Affiliations

  1. Dept. Chemistry, University of Rajasthan, Jaipur, 302004, India

    Raj K. Bansal

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Caminade, AM., Majoral, JP. (2009). From Phosphorus-Containing Macrocycles to Phosphorus-Containing Dendrimers. In: Bansal, R. (eds) Phosphorous Heterocycles I. Topics in Heterocyclic Chemistry, vol 20. Springer, Berlin, Heidelberg. https://doi.org/10.1007/7081_2008_18

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