Skip to main content
SpringerLink
Log in

Coordination Modes and Hydride Exchange Dynamics in Transition Metal Tetrahydroborate Complexes

  • Chapter
  • First Online:
Contemporary Metal Boron Chemistry I

Part of the book series: Structure and Bonding ((STRUCTURE,volume 130))

Abstract

This contribution reviews the structural and dynamical properties of mononuclear transition metal complexes with tetrahydroborate ligands. Three different coordination modes involving one (η1), two (η2) or three (η3) bridging hydrogen atoms are possible for the BH4 – ligand. A structural classification of the X-ray characterised complexes is presented. The metal-boron distances and the vibrational frequencies of the coordinated borohydrides, which are the key experimental data usually used to determine the hapticity of tetrahydroborate binding, have been surveyed and trends along the Periodic Table established. Electronic factors governing the coordination mode have been rationalized by means of simple orbital arguments supported by quantitative calculations. In solution, most of the transition metal tetrahydroborate complexes show fluxional behaviour, displaying a single resonance for the four B–H hydrogens in the 1H NMR spectrum at ambient temperature. This fast intramolecular exchange between bridging and terminal hydrogens has been analysed. Experimental and computational data for these processes have been collected and the exchange mechanisms are discussed. In summary, several examples illustrating the perspectives on the field are presented.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Marks TJ, Kolb JR (1977) Chem Rev 77:263

    CAS  Google Scholar 

  2. Ephritikhine M (1997) Chem Rev 97:2193

    CAS  Google Scholar 

  3. Makhaev VD (2000) Uspekhi Khimii 69:795

    Google Scholar 

  4. Xu Z, Lin Z (1996) Coord Chem Rev 156:139

    CAS  Google Scholar 

  5. Basuli F, Bailey BC, Watson LA, Tomaszewski J, Huffman JC, Mindiola DJ (2005) Organometallics 24:1886

    CAS  Google Scholar 

  6. Atwood JL, Hunter WE, Carmona-Guzman E, Wilkinson G (1980) J Chem Soc, Dalton Trans 3:467

    Google Scholar 

  7. Barron AR, Salt JE, Wilkinson G, Motevalli M, Hursthouse MB (1986) Polyhedron 5:1833

    CAS  Google Scholar 

  8. Frost PW, Howard JAK, Spencer JL (1984) J Chem Soc, Chem Commun, p 1362

    Google Scholar 

  9. Musaev DG, Morokuma K (1995) Organometallics, p 3327

    Google Scholar 

  10. Jandl S, Dufour P, Richard P, Nekvasil V, Zhigunov DI, Barilo SN, Shiryaev SV, Aldridge S, Downs AJ, Hofmann M, Pulham CR, Schleyer PV (1998) J Mol Struct 444:29

    Google Scholar 

  11. Jarid A, Lledós A, Jean Y, Volatron F (1995) Chem Eur J 1:436

    CAS  Google Scholar 

  12. Oishi Y, Albright TA, Fujimoto H (1995) Polyhedron 14:2603

    CAS  Google Scholar 

  13. Kandiah M, McGrady GS, Decken A, Sirsch P (2005) Inorg Chem 44:8650

    CAS  Google Scholar 

  14. Esteruelas MA, Jean Y, Lledos A, Oro LA, Ruiz N, Volatron F (1994) Inorg Chem 33:3609

    CAS  Google Scholar 

  15. Demachy I, Esteruelas MA, Jean Y, Lledos A, Maseras F, Oro LA, Valero C, Volatron F (1996) J Am Chem Soc 118:8388

    CAS  Google Scholar 

  16. Ariafard A, Amini MM (2005) J Organomet Chem 690:84

    CAS  Google Scholar 

  17. Ariafard A, Amini MM, Azadmehr A (2005) J Organomet Chem 690:1147

    CAS  Google Scholar 

  18. Makhaev VD, Borisov AP, Lobkovskii EB, Semenenko KN (1980) Izv Akad Nauk SSSR, Ser Khim, p 2614 (Russ Chem Bull)

    Google Scholar 

  19. Lobkovskii EB, Antipin MY, Borisov AP, Makhaev VD, Semenenko KN, Struchkov YT (1981) Koord Khim, p 307 (Russ J Coord Chem)

    Google Scholar 

  20. Takusagawa F, Fumagalli A, Koetzle TF, Shore SG, Schmitkons T, Fratini AV, Morse KW, Wei CY, Bau R (1981) J Am Chem Soc 103:5165

    CAS  Google Scholar 

  21. Bommer JC, Morse KW (1980) Inorg Chem 19:587

    CAS  Google Scholar 

  22. Dapporto P, Midollini S, Orlandini A, Sacconi L (1976) Inorg Chem 15:2768

    CAS  Google Scholar 

  23. Ghilardi CA, Midollini S, Orlandini A (1982) Inorg Chem 21:4096

    CAS  Google Scholar 

  24. Baker MV, Field LD (1984) J Chem Soc, Chem Commun, p 996

    Google Scholar 

  25. Bau R, Yuan HSH, Baker MV, Field LD (1986) Inorg Chim Acta 114:L27

    CAS  Google Scholar 

  26. Baker MV, Field LD (1990) Appl Organomet Chem 4:543

    CAS  Google Scholar 

  27. Ohkuma T, Koizumi M, Muñiz K, Hilt G, Kabuto C, Noyori R (2002) J Am Chem Soc 124:6508

    CAS  Google Scholar 

  28. Guo R, Morris RH, Song D (2005) J Am Chem Soc 127:516

    CAS  Google Scholar 

  29. Yoshida T, Adachi T, Ueda T, Akao H, Tanaka T, Goto F (1995) Inorg Chim Acta 231:95

    CAS  Google Scholar 

  30. Liang F, Schmalle HW, Fox T, Berke H (2003) Organometallics 22:3382

    CAS  Google Scholar 

  31. Liang F, Jacobsen H, Schmalle HW, Fox T, Berke H (2000) Organometallics 19:1950

    CAS  Google Scholar 

  32. Höck J, Jacobsen H, Schmalle HW, Artus GRJ, Fox T, Amor JI, Bäth F, Berke H (2001) Organometallics 20:1533

    Google Scholar 

  33. Lippard SJ, Melmed KM (1967) Inorg Chem 6:2223

    CAS  Google Scholar 

  34. Green BE, Kennard CHL, Hawkins CJ, Smith G, James BD, White AH (1980) Acta Crystallogr B 36:2407

    Google Scholar 

  35. Green BE, Kennard CHL, Smith G, Elcombe MM, Moore FH, James BD, White AH (1984) Inorg Chim Acta 83:177

    CAS  Google Scholar 

  36. Lobkovskii EB, Makhaev VD, Borisov AP (1984) Zh Strukt Khim (Russ J Struct Chem) 25:496

    Google Scholar 

  37. Makhaev VD, Borisov AP, Lobkovskii EB, Polyakova VB, Semenenko KN (1985) Izv Akad Nauk SSSR, Ser Khim (Russ Chem Bull) 34:1731

    Google Scholar 

  38. Moncol J, Gembicky M, Coppens P (2005) Acta Crystallogr E 61:m242

    Google Scholar 

  39. Li CY, Zhang YG, Zhou Y, Zhang LF (2000) Chinese J Struct Chem 19:91

    Google Scholar 

  40. Dick DG, Duchateau R, Edema JJH, Gambarotta S (1993) Inorg Chem 32:1959

    CAS  Google Scholar 

  41. Prust J, Hohmeister H, Stasch A, Roesky HW, Magull J, Alexopoulos E, Usón I, Schmidt H-G, Noltemeyer M (2002) Eur J lnorg Chem, p 2156

    Google Scholar 

  42. Berno P, Moore M, Minhas R, Gambarotta S (1996) Can J Chem 74:1930

    CAS  Google Scholar 

  43. Makhaev VD, Borisov AP, Antsyshkina AS, Sadikov GG, Poraikoshits MA, Kedrova NS, Maltseva NN, Istomin SY (1993) Koord Khim (Russ J Coord Chem) 19:858

    CAS  Google Scholar 

  44. Reger DL, Mason SS, Rheingold AL (1993) J Am Chem Soc 115:10406

    CAS  Google Scholar 

  45. Koutsantonis GA, Lee FC, Raston CL (1994) J Chem Soc, Chem Commun, p 1975

    Google Scholar 

  46. Gerlach CP, Arnold J (1997) J Chem Soc, Dalton Trans, p 4795

    Google Scholar 

  47. Corey EJ, Cooper NJ, Canning WM, Lipscomb WN, Koetzle TF (1982) Inorg Chem 21:192

    CAS  Google Scholar 

  48. Saito T, Nakajima M, Kobayashi A, Sasaki Y (1978) J Chem Soc, Dalton Trans, p 482

    Google Scholar 

  49. Green MLH, Munakata H, Tato S (1971) J Chem Soc(A), Inorg Phys Theor, p 469

    Google Scholar 

  50. Nakajima M, Moriyama H, Kobayashi A, Saito T, Sasaki Y (1975) J Chem Soc, Chem Commun, p 80

    Google Scholar 

  51. Nakajima M, Saito T, Kobayashi A, Sasaki Y (1977) J Chem Soc, Dalton Trans, p 385

    Google Scholar 

  52. Scoles L, Gambarotta S (1995) Inorg Chim Acta 235:375

    CAS  Google Scholar 

  53. Nückel S, Burger P (2001) Organometallics 20:4345

    Google Scholar 

  54. Darensbourg MY, Bau R, Marks MW, Burch RR, Deaton JC, Slater S (1982) J Am Chem Soc 104:6961

    CAS  Google Scholar 

  55. Kirtley SW, Andrews MA, Bau R, Grynkewich GW, Marks TJ, Tipton DL, Whittlesey BR (1977) J Am Chem Soc 99:7154

    CAS  Google Scholar 

  56. Thomas SA (1989) J Cryst Spectrosc 19:1017

    CAS  Google Scholar 

  57. Ghilardi CA, Innocenti P, Midollini S, Orlandini A (1982) J Organomet Chem 231:C78

    CAS  Google Scholar 

  58. Ghilardi CA, Innocenti P, Midollini S, Orlandini A (1985) J Chem Soc, Dalton Trans, p 605

    Google Scholar 

  59. Statler JA, Wilkinson G, Thornton-Pett M, Hursthouse MB (1984) J Chem Soc, Dalton Trans, p 1731

    Google Scholar 

  60. van der Zeijden AAH, Shklover V, Berke H (1991) Inorg Chem 30:4393

    Google Scholar 

  61. Liu X-Y, Bouherour S, Jacobsen H, Schmalle HW, Berke H (2002) Inorg Chim Acta 330:250

    CAS  Google Scholar 

  62. Tamm M, Drebel B, Lügger T, Fröhlich R, Grimme S (2003) Eur J lnorg Chem, p 1088

    Google Scholar 

  63. Tamm M, Drebel B, Urban V, Lügger T (2003) Inorg Chem Commun 5:837

    Google Scholar 

  64. Hessen B, Teuben JH, Lemmen TH, Huffman JC, Caulton KG (1985) Organometallics 4:946

    CAS  Google Scholar 

  65. Hessen B, Lemmen TH, Luttikhedde HJG, Teuben JH, Petersen JL, Huffman JC, Jagner S, Caulton KG (1987) Organometallics 6:2354

    CAS  Google Scholar 

  66. You YJ, Wilson SR, Girolami GS (1994) Organometallics 13:4655

    CAS  Google Scholar 

  67. Fryzuk MD, Mylvaganam M, Zaworotko MJ, McGillivray LR (1993) J Am Chem Soc 115:10360

    CAS  Google Scholar 

  68. Marks TJ, Kennelly WJ (1975) J Am Chem Soc 97:1439

    CAS  Google Scholar 

  69. Liu F-C, Plecnik CE, Liu S, Liu J, Meyers EA, Shore SG (2001) J Organomet Chem 627:109

    CAS  Google Scholar 

  70. Kirillova NI, Gusev AI, Struchkov YT (1974) Zh Strukt Khim (Russ J Struct Chem) 15:718

    Google Scholar 

  71. Bailey NJ, Green MLH, Leech MA, Saunders JF, Tidswell HM (1997) J Organomet Chem 538:111

    CAS  Google Scholar 

  72. Conway SLJ, Doerrer LH, Green MLH, Leech MA (2000) Organometallics 19:630

    CAS  Google Scholar 

  73. Lantero DR, Ward DL, Smith MR III (1997) J Am Chem Soc 119:9699

    CAS  Google Scholar 

  74. Melmed KM, Coucouva D, Lippard SJ (1973) Inorg Chem 12:232

    CAS  Google Scholar 

  75. Mamaeva GI, Hargittai I, Spiridonov VP (1977) Inorg Chim Acta 25:L123

    CAS  Google Scholar 

  76. Hartwig JF, De Gala SR (1994) J Am Chem Soc 116:3661

    CAS  Google Scholar 

  77. Lappert MF, Singh A, Atwood JL, Hunter WE (1983) J Chem Soc, Chem Commun, p 206

    Google Scholar 

  78. Antinolo A, Carrillo-Hermosilla F, Fernandez-Baeza J, Garcia-Yuste S, Otero A, Rodriguez AM, Sanchez-Prada J, Villasenor E, Gelabert R, Moreno M, Lluch JM, Lledos A (2000) Organometallics 19:3654

    CAS  Google Scholar 

  79. Schumann H, Keitsch MR, Demtschuk J, Muhle S (1998) Z Anorg Allg Chem 624:1811

    CAS  Google Scholar 

  80. Choukroun R, Douziech B, Donnadieu B (1997) Organometallics 16:5517

    CAS  Google Scholar 

  81. Laske DA, Duchateau R, Teuben JH, Spek AL (1993) J Organomet Chem 462:149

    CAS  Google Scholar 

  82. Qian CT, Zou G, Nie W-L, Sun J, Lemenovskii DA, Borzov MV (2000) Polyhedron 19:1955

    CAS  Google Scholar 

  83. Fischer PJ, Young VG, Ellis JE (2000) Angew Chem Int Ed 39:189

    CAS  Google Scholar 

  84. Garcia A, Mercero JM, Ugalde JM (1997) J Phys Chem A 101:5953

    CAS  Google Scholar 

  85. Garcia A, Mercero JM, Fowler JE, Ugalde JM (1998) J Phys Chem A 102:2055

    CAS  Google Scholar 

  86. Herrmann WA, Denk M, Scherer W, Klingan FR (1993) J Organomet Chem 444:C21

    CAS  Google Scholar 

  87. Noth H, Schmidt M (1995) Organometallics 14:4601

    Google Scholar 

  88. Kazani A, Gambarotta S, Bensimon C (1997) Can J Chem 75:1494

    Google Scholar 

  89. Desrochers PJ, LeLievre S, Johnson RJ, Lamb BT, Phelps AL, Cordes AW, Gu W, Cramer SP (2003) Inorg Chem 42:7945

    CAS  Google Scholar 

  90. Ariafard A, Fazaeli R, Aghabozorg HR, Monajjemi M (2003) J Mol Struct (Theochem) 625:305

    CAS  Google Scholar 

  91. Jensen JA, Girolami GS (1989) Inorg Chem 28:2107

    CAS  Google Scholar 

  92. Jensen JA, Girolami GS (1988) J Am Chem Soc 110:4450

    CAS  Google Scholar 

  93. Dionne M, Hao S, Gambarotta S (1995) Can J Chem 73:1126

    CAS  Google Scholar 

  94. Marsh RE (2004) Acta Crystallogr B60:252

    CAS  Google Scholar 

  95. Makhaev VD, Borisov AP, Gnilomedova TP, Lobkovskii EB, Chekhlov AN (1987) Izv Akad Nauk SSSR, Ser Khim (Russ Chem Bull) 36:1518

    Google Scholar 

  96. Jensen JA, Wilson SR, Schultz AJ, Girolami GS (1987) J Am Chem Soc 109:8094

    CAS  Google Scholar 

  97. Johnson PL, Cohen SA, Marks TJ, Williams JM (1978) J Am Chem Soc 100:2709

    CAS  Google Scholar 

  98. Smith BE, James BD, Dilts JA (1976) J Inorg Nuc Chem 38:1973

    CAS  Google Scholar 

  99. Sztaray B, Rosta E, Bocskey Z, Szepes L (1999) J Organomet Chem 582:267

    CAS  Google Scholar 

  100. Schaper F, Brintzinger H-H (2000) Acta Crystallogr C56:e78

    CAS  Google Scholar 

  101. Saidov BI, Borisov AP, Makhaev VD, Boiko GN, Antsyshkina AS, Kedrova NS, Mal'tseva NN (1990) Zh Neorg Khim (Russ J Inorg Chem) 35:626

    CAS  Google Scholar 

  102. Antsyshkina AS, Poraikoshits MA, Saidov BI, Makhaev VD, Borisov AP, Maltseva NN, Kedrova NS (1991) Koord Khim (Russ J Coord Chem) 17:405

    Google Scholar 

  103. Lobkovskii EB, Chekhlov AN, Makhaev VD, Borisov AP (1989) Koord Khim (Russ J Coord Chem) 15:377

    CAS  Google Scholar 

  104. Makhaev VD, Borisov AP, Karpova TP, Lobkovskii EB, Tarasov BP, Chekhlov AN (1989) Izv Akad Nauk SSSR, Ser Khim (Russ Chem Bull) 38:377

    Google Scholar 

  105. Jensen JA, Girolami GS (1989) Inorg Chem 28:2114

    CAS  Google Scholar 

  106. Lledos A, Duran M, Jean Y, Volatron F (1991) Inorg Chem 30:4440

    CAS  Google Scholar 

  107. Borisov AP, Makhaev VD, Lobkovskii EB, Semenenko KN (1986) Zh Neorg Khim (Russ J Inorg Chem) 31:86

    CAS  Google Scholar 

  108. Lobkovskii EB, Makhaev VD, Borisov AP, Semenenko KN (1986) Zh Strukt Khim (Russ J Struct Chem) 27:161

    Google Scholar 

  109. Corazza F, Floriani C, Chiesivilla A, Guastini C (1991) Inorg Chem 30:145

    CAS  Google Scholar 

  110. Cloke FGN, Hitchcock PB, Love JB (1995) J Chem Soc, Dalton Trans, p 25

    Google Scholar 

  111. Lobkovskii EB, Kravchenko SE, Kravchenko OV (1982) Zh Strukt Khim (Russ J Struct Chem) 23:582

    Google Scholar 

  112. Kravchenko OV, Kravchenko SE, Polyakova VB, Semenenko KN (1980) Koord Khim (Russ J Coord Chem) 6:76

    CAS  Google Scholar 

  113. Xu Z, Lin Z (1996) Inorg Chem 35:3964

    CAS  Google Scholar 

  114. Belskii VK, Sobolev AN, Bulychev BM, Alikhanova TK, Kurbonbekov A, Mirsaidov U (1990) Koord Khim (Russ J Coord Chem) 16:1693

    CAS  Google Scholar 

  115. Wang H, Wang H, Li H-W, Xie Z (2004) Organometallics 23:875

    CAS  Google Scholar 

  116. Dain CJ, Downs AJ, Goode MJ, Evans DG, Nicholls KT, Rankin DWH, Robertson HE (1991) J Chem Soc, Dalton Trans, p 967

    Google Scholar 

  117. Borisenko KB, Downs AJ, Robertson HE, Rankin DWH, Tang CY (2004) J Chem Soc, Dalton Trans, p 967

    Google Scholar 

  118. Jarid A, Lledos A, Jean Y, Volatron F (1993) Inorg Chem 32:4695

    CAS  Google Scholar 

  119. Broach RW, Chuang IS, Marks TJ, Williams JM (1983) Inorg Chem 22:1081

    CAS  Google Scholar 

  120. Keiderling TA, Wozniak WT, Gay RS, Jurkowitz D, Bernstein ER, Lippard SJ, Spiro TG (1975) Inorg Chem 14:576

    CAS  Google Scholar 

  121. Davies N, Wallbridge MGH, Smith BE, James BD (1973) J Chem Soc, Dalton Trans 2:162

    Google Scholar 

  122. Smith BE, Shurwell HF, James BD (1977) J Chem Soc, Dalton Trans, p 710

    Google Scholar 

  123. Bird PH, Churchill MR (1967) J Chem Soc, Chem Commun, p 403

    Google Scholar 

  124. Green JC, de Simone M, Coreno M, Jones A, Pritchard HMI, McGrady GS (2005) Inorg Chem 44:7781

    CAS  Google Scholar 

  125. Jensen JO (2003) Spectrochim Acta A 59:379

    Google Scholar 

  126. Jensen JO (2003) Vib Spectrosc 31:227

    CAS  Google Scholar 

  127. Haaland A, Shorokhov DJ, Tutukin AV, Volden HV, Swang O, McGrady GS, Kaltsoyannis N, Downs AJ, Tang CY, Turner JFC (2002) Inorg Chem 41:6646

    CAS  Google Scholar 

  128. Volatron F, Duran M, Lledos A, Jean Y (1993) Inorg Chem 32:951

    CAS  Google Scholar 

  129. Joseph SCP, Cloke FGN, Cardin CJ, Hitchcock PB (1995) Organometallics 14:3566

    CAS  Google Scholar 

  130. Lobkovskii EB, Kravchenko SE, Semenenko KN (1977) Zh Strukt Khim (Russ J Struct Chem) 18:312

    Google Scholar 

  131. Goedde DM, Girolami GS (2006) Inorg Chem 45:1380

    CAS  Google Scholar 

  132. Segal BG, Lippard SJ (1978) Inorg Chem 17:844

    CAS  Google Scholar 

  133. Edelstein N (1981) Inorg Chem 20:297

    CAS  Google Scholar 

  134. Allen FH (2002) Acta Crystallogr B58:380

    CAS  Google Scholar 

  135. Jensen JA, Girolami GS (1986) Chem Comm 15:1160

    Google Scholar 

  136. Hori K, Saito G, Teramae H (1988) J Phys Chem 92:3796

    CAS  Google Scholar 

  137. Lledos A, Duran M, Jean Y, Volatron F (1992) Bull Soc Chim Fr 129:216

    CAS  Google Scholar 

  138. Nissen-Sobocinska B, Jezowska-Trzebiatowska B (1993) J Organomet Chem 452:277

    CAS  Google Scholar 

  139. Green MLH, Wong L-L (1989) J Chem Soc, Dalton Tans, p 2133

    Google Scholar 

  140. Ashworth NJ, Conway SLJ, Green JC, Green MLH (2000) J Organomet Chem 609:83

    CAS  Google Scholar 

  141. Jensen JA, Wilson SR, Girolami GS (1988) J Am Chem Soc 110:4977

    CAS  Google Scholar 

  142. Engelhardt LM, Pakawatchai C, White AH, Healy PC (1985) J Chem Soc, Dalton Trans, p 125

    Google Scholar 

  143. Green BE, Kennard CHL, Smith G, White AH (1981) Cryst Struct Commun 10:1245

    CAS  Google Scholar 

  144. Kutal C, Grutsch P, Atwood JL, Rogers RD (1978) Inorg Chem 17:3558

    CAS  Google Scholar 

  145. Antsyshkina AS, Poraikoshits MA, Makhaev VD, Borisov AP, Kedrova NS, Maltseva NN (1992) Koord Khim (Russ J Coord Chem) 18:474

    CAS  Google Scholar 

  146. Bell RA, Cohen SA, Doherty NM, Threlkel RS, Bercaw JE (1986) Organometallics 5:972

    CAS  Google Scholar 

  147. Green MLH, Hughes AK (1992) J Chem Soc, Dalton Trans, p 527

    Google Scholar 

  148. Wink DJ, Cooper NJ (1984) J Chem Soc, Dalton Tans, p 1257

    Google Scholar 

  149. Chuang I-S, Marks TJ, Kennelly WJ, Kolb JR (1977) J Am Chem Soc 99:7536

    Google Scholar 

  150. Marks TJ, Kolb JR (1975) J Am Chem Soc 97:3397

    CAS  Google Scholar 

  151. Mehn MP, Brown SD, Paine TK, Brennessel WW, Cramer CJ, Peters JC, Que L (2006) Dalton Trans 1347

    Google Scholar 

  152. Journaux Y, Lozan V, Klingele J, Kersting B (2006) Chem Commun 83

    Google Scholar 

  153. Hillier AC, Jacobsen H, Gusev D, Schmalle HW, Berke H (2001) Inorg Chem 40:6334

    CAS  Google Scholar 

  154. Guilera G, McGrady GS, Steed JW, Kaltsoyannis N (2004) New J Chem 28:444

    CAS  Google Scholar 

  155. Chamberlain B, Duckett SB, Lowe JP, Mawby RJ, Stott JC (2003) Dalton Trans 2603

    Google Scholar 

  156. Duckett SB, Lowe JP, Mawby RJ (2006) Dalton Trans 2661

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Departament de Química, Universitat Autònoma de Barcelona, 08193, Bellaterra, Catalonia, Spain

    Maria Besora & Agustí Lledós

Authors
  1. Maria Besora
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Agustí Lledós
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Agustí Lledós .

Editor information

Todd B. Marder Zhenyang Lin

Rights and permissions

Reprints and permissions

Copyright information

© 2007 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Besora, M., Lledós, A. (2007). Coordination Modes and Hydride Exchange Dynamics in Transition Metal Tetrahydroborate Complexes. In: Marder, T.B., Lin, Z. (eds) Contemporary Metal Boron Chemistry I. Structure and Bonding, vol 130. Springer, Berlin, Heidelberg. https://doi.org/10.1007/430_2007_076

Download citation

Publish with us

Policies and ethics

Search

Navigation