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Luminescence pp 1–68Cite as

Investigation of polymers in solution by polarized luminescence

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Part of the book series: Advances in Polymer Science ((POLYMER,volume 40))

Abstract

In recent years, the method of polarized luminescence (PL) has become one of the most valuable methods for the study of macromolecules. It provides detailed information on micro-Brownian motion in polymer chains which is related to various features of the structures and conformational properties of macromolecules.

This review considers the use of PL in the investigation of macromolecules with covalently bonded luminescent markers (LM). This approach is very fruitful in the study of problems of physics and chemistry associated with changes in intra- and inter-macromolecular interactions, structural and conformational transformations in macromolecules and complex polymer systems, relationships between the reactivity of macromolecules and their intramolecular mobility, etc.

The PL method is based on the study of polarization and other parameters of light emitted by luminescent groups (LM) covalently bonded to some parts of the macromolecules or polymer systems.

The PL method can be widely and systematically used for the study of polymers and polymer systems of various classes if it is based on specifically developed methods of covalent bonding of LM to the macromolecules of the polymers investigated. The structure and optical properties of luminescent groups, their amount and type of bonding to the polymer chain should meet certain requirements. Moreover, LM should not effect the investigated properties of macromolecules.

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Abbreviations

PL:

Polarized luminescence

LM:

luminescent marker

LG:

luminescent group

IMM:

intramolecular mobility

ADM:

9-anthryldiazomethane

PA:

polyacid

PAA:

polyacrylic acid

PAmA:

polyamic acid

PGA:

polyglutamic acid

PDME:

polydimethoxyethylene

PMAA:

polymethacrylic acid

PMA:

polymethylacrylate

PMA-n:

polyalkylmethacrylate-n

PMMA:

polymethylmethacrylate

PPBE:

polypropenylbenzyl ether

PS:

polystyrene

P(α-CH3S):

poly-α-methylstyrene

PVBE:

polyvinylbenzyl ether

PMMAA-n:

methyl ester of poly-N-methacryloyl-ω-aminocarboxylic acids

PCMAA-n:

cetyl ester of poly-N-methacryloyl-ω-aminocarboxylic acids

PChMAA-n:

cholesterol ester of poly-N-methacryloyl-ω-aminocarboxylic acids

PChMAA-n:

cholesterol ester of poly-N-methacryloyl-ω-aminocarboxylic acids

PVpD:

polyvinylpyrrolidone

VP:

vinylpyrrolidone

VNH2 :

vinylamine

CMC:

carboxymethyl cellulose

PMMA-C:

crosslinked polymethacrylic acid

PC:

polymer-polymer complex

REE:

rare earth element

DMF:

dimethylformamide

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  1. The Institute of High Molecular Compounds, Academy of Sciences of the USSR, 199004, Leningrad, USSR

    Elizaveta V. Anufrieva & Yuli Ya. Gotlib

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  1. Elizaveta V. Anufrieva
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Anufrieva, E.V., Gotlib, Y.Y. (1981). Investigation of polymers in solution by polarized luminescence. In: Luminescence. Advances in Polymer Science, vol 40. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-10550-6_1

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