Abstract
This review summarizes recent advances to date in the area of block copolymer micelles and also tries to highlight some new directions in that field. Generalities about the preparation, characterization, and dynamics of block copolymer micelles are first outlined. Selected examples of micelle formation in aqueous and organic media are shown for block copolymers with various architectures. The different types of micellar morphologies are discussed. New directions in block copolymer micellization are finally presented.
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Abbreviations
- AFM:
-
atomic force microscopy
- AUC:
-
analytical ultracentrifugation
- b :
-
grafting distance
- BIC:
-
block ionomer complex
- CMC:
-
critical micelle concentration
- CMD:
-
critical micelle density
- CMT:
-
critical micelle temperature
- CWC:
-
critical water concentration
- DMF:
-
N,N-dimethylformamide
- DLS:
-
dynamic light scattering
- D h :
-
hydrodynamic diameter
- FCS:
-
fluorescence correlation spectroscopy
- IPEC:
-
interpolyelectrolyte complex
- LCST:
-
lower critical solubility temperature
- MALS:
-
multiangle light scattering
- MW:
-
molecular weight
- N :
-
degree of polymerization
- N A :
-
degree of polymerization of core-forming block
- N B :
-
degree of polymerization of corona-forming block
- NMR:
-
nuclear magnetic resonance
- PAA:
-
poly(acrylic acid)
- PaspA:
-
Poly(aspartic acid)
- PB:
-
polybutadiene
- PBAEMA:
-
poly(tert-butylaminoethyl methacrylate)
- PBLG:
-
poly(γ-benzyl-L-glutamate)
- PBO:
-
poly(butylene oxide)
- PDEAEMA:
-
poly(N,N-diethylaminoethyl methacrylate)
- PDMAEMA:
-
poly(N,N-dimethylaminoethyl methacrylate)
- PDMAI:
-
poly(N,N-dimethylaminoisoprene)
- PDPAEMA:
-
poly(N,N-diisopropylaminoethyl methacrylate)
- PCEMA:
-
poly(cinnamoylethyl methacrylate)
- PCL:
-
poly(ε-caprolactone)
- PDMS:
-
poly(dimethylsiloxane)
- PEB:
-
poly(ethylene-co-butylene)
- PEI:
-
poly(ethylene imine)
- PEG:
-
poly(ethylene glycol)
- PEHA:
-
poly(2-ethylhexyl acrylate)
- PEHMA:
-
poly(2-ethylhexyl methacrylate)
- PEO:
-
poly(ethylene oxide)
- PEOVE:
-
poly(2-ethoxyethyl vinyl ether)
- PFS:
-
poly(ferrocenylsilane)
- PGANa:
-
poly(sodium L-glutamate)
- PHIC:
-
poly(hexyl isocyanate)
- PI:
-
poly(isoprene)
- PIB:
-
poly(isobutylene)
- PIC:
-
poly(isocyanodipeptide)
- PLL:
-
poly(L-lysine)
- PMAA:
-
poly(methacrylic acid)
- PMANa:
-
poly(sodium methacrylate)
- PMACs:
-
poly(cesium methacrylate)
- PMEMA:
-
poly(2-(N-morpholinoethyl) methacrylate)
- PMMA:
-
poly(methylmethacrylate)
- PMOVE:
-
poly(2-methoxyethyl vinyl ether)
- PMOXA:
-
poly(methyl oxazoline)
- PMPS:
-
poly(methylphenylsilane)
- PMTGEVE:
-
poly(methyl tri(ethyleneglycol) vinyl ether)
- PMVE:
-
poly(methyl vinyl ether)
- PNIPAAM:
-
poly(N-isopropyl acrylamide)
- PPO:
-
poly(propylene oxide)
- PPQ:
-
poly(phenylquinoline)
- PS:
-
polystyrene
- PSCNa:
-
poly(sodium 4-styrene carboxylate)
- PSMA:
-
poly(stearylmethacrylate)
- PSOH:
-
poly(styrene-co-[p-(2,2,2- trifluoro-1-hydroxy-1-trifluoromethyl)ethylmethylstyrene])
- PSS:
-
poly(styrene sulfonate)
- PTAN:
-
poly(1,1,2,2-tetrahydroperfluorooctyl acrylate)
- PtBA:
-
poly(tert-butylacrylate)
- PtBMA:
-
poly(tert-butyl methacrylate)
- PtBS:
-
poly(tert-butylstyrene)
- PVA:
-
poly(vinyl alcohol)
- PVAC:
-
poly(vinylacetate)
- P2VP:
-
poly(2-vinylpyridine)
- P2VPQ:
-
poly(2-vinylpyridine) quaternized
- P4VP:
-
poly(4-vinylpyridine)
- R c :
-
micellar core radius
- R g :
-
radius of gyration
- R h :
-
hydrodynamic radius
- R m :
-
total micellar radius
- SANS:
-
small-angle neutron scattering
- SAXS:
-
small-angle X-ray scattering
- SEC:
-
size-exclusion chromatography
- SEM:
-
scanning electron microscopy
- scCO2 :
-
supercritical CO2
- SLS:
-
static light scattering
- TEM:
-
transmission electron microscopy
- T g :
-
glass transition temperature
- THF:
-
tetrahydrofuran
- UCST:
-
upper critical solubility temperature
- Z :
-
aggregation number
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Gohy, JF. Block Copolymer Micelles. In: Abetz, V. (eds) Block Copolymers II. Advances in Polymer Science, vol 190. Springer, Berlin, Heidelberg. https://doi.org/10.1007/12_048
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