Skip to main content
SpringerLink
Log in

Patternable Block Copolymers

  • Chapter
  • First Online:
Book cover Block Copolymers II

Part of the book series: Advances in Polymer Science ((POLYMER,volume 190))

Abstract

This article is a review of the chemical and physical nature of patternable block copolymers and their use as templates for functional nanostructures. The patternability of block copolymers, that is, the ability to make complex, arbitrarily shaped submicron structures in block copolymer films, results from both their ability to self-assemble into microdomains, the “bottom-up” approach, and the manipulation of these patterns by a variety of physical and chemical means including “top-down” lithographic techniques. Procedures for achieving long-range control of microdomain pattern orientation as well as the combination of top-down and bottom-up patterning to give multilevel control of block copolymer films are extensively discussed. The level of control over patterning block copolymers that these strategies afford has enabled recent developments in nanofabrication including template nanolithography, template nanoparticle patterning, nanoporous as well as nanoreplicated materials.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Abbreviations

1D:

One dimensional

2D:

Two dimensional

3D:

Three dimensional

BA:

Benzoic acid

CPS:

Close-packed spheres

C:

Cylinder

G:

Gyroid

L:

Lamellae

OTS:

Octadecyltrichlorosilane

PαMS:

Poly(α-methylstyrene)

P2VP:

Poly(2-vinylpyridine)

PAG:

Photoacid generator

PBMA:

Poly(butylmethacrylate)

PB:

Poly(butadiene)

PDMS:

Poly(dimethylsiloxane)

PEO:

Poly(ethylene oxide)

PETS:

Phenylethyltrichlorosilane

PE:

Polyethylene

PFS:

Poly(ferrocenyl dimethylsilane)

PHS:

Poly(4-hydroxystyrene)

PI:

Polyisoprene

PMMA:

Poly(methylmethacrylate)

PMS:

Poly(para-methylstyrene)

PS:

Polystyrene

SAM:

Self-assembled monolayer

SBS:

Poly(styrene-b-butadiene-b-styrene)

SEBS:

Poly(styrene-b-ethylene butylene-b-styrene)

S:

Sphere

-b-:

-Block-

-r-:

-Random-

f A :

Volume ratio

L 0 :

Natural period of block copolymers

t :

Film thickness

χ:

Flory--Huggins parameter

∇T :

Temperature gradient

References

  1. Whitesides GM, Mathias JP, Seto CT (1991) Science 254:1312

    CAS  Google Scholar 

  2. Tolles WM (1996) Nanotechnology 7:59

    Article  CAS  Google Scholar 

  3. Rohrer H (1996) Microelectron Eng 32:5

    Article  CAS  Google Scholar 

  4. Xia Y, Rogers JA, Paul KE, Whitesides GM (1999) Chem Rev 99:1823

    Article  CAS  Google Scholar 

  5. Mansky P, Harrison CK, Chaikin PM, Register RA, Yao N (1996) Appl Phys Lett 68:2586

    Article  CAS  Google Scholar 

  6. Melosh NA, Davidson P, Chmelka BF (2000) J Am Chem Soc 122:823

    Article  CAS  Google Scholar 

  7. Bates FS, Fredrickson GH (1990) Ann Rev Phys Chem 41:525

    Article  CAS  Google Scholar 

  8. Hamley IW (1998) The physics of block copolymers. Oxford Science, p 26

    Google Scholar 

  9. Leibler L (1980) Macromolecules 13:1602

    Article  CAS  Google Scholar 

  10. Lee M, Cho B-K, Zin W-C (2001) Chem Rev 101:3869

    CAS  Google Scholar 

  11. Klok H-A, Lecommandoux S (2001) Adv Mater 13:1217

    Article  CAS  Google Scholar 

  12. Ober CK, Gabor AH, Gallagher-Wetmore P, Allen RD (1997) Adv Mater 9:1039

    CAS  Google Scholar 

  13. Fredrickson GH, Bates FS (1996) Annu Rev Mater Sci 26:501

    Article  CAS  Google Scholar 

  14. Fasolka MJ, Mayes AM (2001) Annu Rev Mater Res 31:323

    Article  CAS  Google Scholar 

  15. Tuzar Z, Kratochvil P (1993) Micelles of block and graft copolymers in solutions. In: Surface and colloid science, vol 15. Plenum, New York, p 1

    Google Scholar 

  16. Matsen MW, Bates FS (1996) Macromolecules 29:1091

    CAS  Google Scholar 

  17. Bates FS, Fredrickson GH (1999) Block copolymers-designer soft materials. Physics Today 52:32

    CAS  Google Scholar 

  18. Khandpur AK, Föerster S, Bates FS, Hamley IW, Ryan AJ, Bras W, Almdal K, Mortensen K (1995) Macromolecules 28:8796

    Article  CAS  Google Scholar 

  19. Breiner U, Krappe U, Stadler R (1996) Macromol Rapid Commun 17:567

    Article  CAS  Google Scholar 

  20. Breiner U, Krappe U, Abetz V, Stadler R (1997) Macromol Chem Phys 198:1051

    Article  CAS  Google Scholar 

  21. Krappe U, Stadler R, Voight-Martin I (1995) Macromolecules 28:4558

    CAS  Google Scholar 

  22. Stadler R, Auschra C, Beckmann J, Krappe U, Voight-Martin I, Leibler L (1995) Macromolecules 28:3080

    Article  CAS  Google Scholar 

  23. Matsen MW (1998) J Chem Phys 108:785

    Article  CAS  Google Scholar 

  24. Abetz V (2003) Block copolymers, ternary triblocks. In: Kroschwitz JI (ed) Encyclopedia of polymer science and technology, vol 1, 3rd edn. Wiley, New York

    Google Scholar 

  25. Milner ST (1994) Macromolecules 27:2333

    Article  CAS  Google Scholar 

  26. Zielinski JM, Spontak RJ (1992) Macromolecules 25:653

    CAS  Google Scholar 

  27. Radzilowski LH, Wu JL, Stupp SI (1993) Macromolecules 26:879

    Article  CAS  Google Scholar 

  28. Chen JT, Thomas EL, Ober CK, Mao G-P (1996) Science 273:343

    CAS  Google Scholar 

  29. Cohen RE, Cheng P-L, Douzinas K, Kofinas P, Berney CV (1990) Macromolecules 23:324

    Article  CAS  Google Scholar 

  30. Hamley IW, Fairclough JPA, Bates FS, Ryan AJ (1997) Polymer 39:1429

    Google Scholar 

  31. Muthukumar M, Ober CK, Thomas EL (1997) Science 277:1225

    Article  CAS  Google Scholar 

  32. Widawski G, Rawiso M, Francois B (1994) Nature 369:387

    Article  CAS  Google Scholar 

  33. Jenekhe SA, Chen XL (1999) Science 283:372

    Article  CAS  Google Scholar 

  34. Hayakawa T, Horiuchi S (2003) Angew Chem Int Ed 42:2285

    Article  CAS  Google Scholar 

  35. de Boer B, Stalmach U, Nijland H, Hadziioannou G (2000) Adv Mater 12:1581

    Article  Google Scholar 

  36. Jenekhe SA, Chen XL (1998) Science 279:1903

    Article  CAS  Google Scholar 

  37. Stupp SI, LeBonheur V, Walker K, Li LS, Huggins KE, Keser M, Amstutz A (1997) Science 276:384

    Article  CAS  Google Scholar 

  38. Zubarev ER, Pralle MU, Sone ED, Stupp SI (2001) J Am Chem Soc 123:4105

    Article  CAS  Google Scholar 

  39. Marsitzky D, Brand T, Geerts Y, Klapper M, Müllen K (1998) Macromol Rapid Commun 19:385

    Article  CAS  Google Scholar 

  40. Gallot B (1996) Prog Polym Sci 21:1035

    Article  CAS  Google Scholar 

  41. Fasolka MJ, Banerjee P, Mayes AM, Pickett G, Balazs AC (2000) Macromolecules 33:5702

    Article  CAS  Google Scholar 

  42. Mansky P, Russell TP, Hawker CJ, Pitsikalis M, Mays J (1997) Macromolecules 30:6810

    Article  CAS  Google Scholar 

  43. Thurn-Albrecht T, Schotter J, Kästle GA, Emley N, Shibauchi T, Krusin-Elbaum L, Guarini K, Black CT, Tuominen MT, Russell TP (2000) Science 290:2126

    Article  CAS  Google Scholar 

  44. Park M, Harrison C, Chaikin PM, Register RA, Adamson DH (1997) Science 276:1401

    Article  CAS  Google Scholar 

  45. Radzilowski LH, Carvalho BL, Thomas EL (1996) J Polym Sci, Part B: Polym Phys 34:3081

    CAS  Google Scholar 

  46. Huinink HP, Brokken-Zijp JCM, van Dijk MA, Sevink GJA (2000) J Chem Phys 112:2452

    Article  CAS  Google Scholar 

  47. Chu B, Zhou Z (1996) Physical chemistry of polyoxyalkylene block copolymer surfactant. In: Nonionic surfactants, polyoxyalkylene block copolymers, vol 60. Marcel Dekker, New York

    Google Scholar 

  48. Liu T, Burger C, Chu B (2003) Prog Polym Sci 28:5

    Article  Google Scholar 

  49. Spatz JP, Sheiko S, Möller M (1996) Adv Mater 8:513

    Article  CAS  Google Scholar 

  50. Selb J, Gallot Y (1985) Ionic block copolymers. In: Developments in block copolymers, vol 2. Elsevier, London, p 27

    Google Scholar 

  51. van Dijk MA, van den Berg R (1995) Macromolecules 28:6773

    Google Scholar 

  52. Kim H-C, Russell TP (2001) J Polym Sci Part B, Polym Phys 39:663

    CAS  Google Scholar 

  53. Vigild ME, Almdal K, Mortensen K, Hamley IW, Fairclough JPA, Ryan AJ (1998) Macromolecules 31:5702

    Article  CAS  Google Scholar 

  54. Chen Z-R, Kornfield JA, Smith SD, Grothaus JT, Stakowski MM (1997) Science 277:1248

    Article  CAS  Google Scholar 

  55. Laurer JH, Pinheiro BS, Polis DL, Winey KI (1999) Macromolecules 32:4999

    Article  CAS  Google Scholar 

  56. Keller A, Pedemonte E, Willmouth FM (1970) Nature 225:538

    Article  CAS  Google Scholar 

  57. Lee HH, Register RH, Hajduk DA, Bruner SM (1997) Polym Eng Sci 36:1414

    Google Scholar 

  58. Quiram DJ, Register RA, Marchand GR, Adamson DH (1998) Macromolecules 31:4891

    CAS  Google Scholar 

  59. Albalak RJ, Thomas EL (1993) J Polym Sci, Part B Polym Phys 31:37

    CAS  Google Scholar 

  60. Bodycomb J, Funaki Y, Kimishima K, Hashimoto T (1999) Macromolecules 32:2075

    Article  CAS  Google Scholar 

  61. Amundson K, Helfand E, Davis DD, Quan X, Patel SS, Smith SD (1991) Macromolecules 24:6546

    CAS  Google Scholar 

  62. Amundson K, Helfand E, Quan X, Smith SD (1993) Macromolecules 26:2698

    CAS  Google Scholar 

  63. Amundson K, Helfand E, Quan X, Hudson SD, Smith SD (1994) Macromolecules 27:6559

    Article  CAS  Google Scholar 

  64. Böker A, Knoll A, Elbs H, Abetz V, Müller AHE, Krausch G (2002) Macromolecules 35:1319

    Google Scholar 

  65. Chao C-Y, Li X, Ober CK, Osuji C, Thomas EL (2004) Adv Fun Mater 14:364

    CAS  Google Scholar 

  66. Fasolka MJ, Harrison DJ, Mayes AM, Yoon M, Mochrie SGJ (1997) Phys Rev Lett 79:3018

    Article  CAS  Google Scholar 

  67. Kellogg GJ, Walton DG, Mayes AM, Lambooy P, Russell TP, Gallagher PD, Satija SK (1996) Phys Rev Lett 76:2503

    CAS  Google Scholar 

  68. Huang E, Russell TP, Harrison C, Chaikin PM, Register RA, Hawker CJ, Mays J (1998) Macromolecules 31:7641

    CAS  Google Scholar 

  69. Huang E, Rockford L, Russell TP, Hawker CJ (1998) Nature 395:757

    CAS  Google Scholar 

  70. Harrison C, Chaikin PM, Huse DA, Register RA, Adamson DH, Daniel A, Huang E, Mansky P, Russell TP, Hawker CJ, Egolf DA, Melnikov IV, Bodenschatz, E (2000) Macromolecules 33:857

    Article  CAS  Google Scholar 

  71. Mansky P, Liu Y, Huang E, Russell TP, Hawker C (1997) Science 275:1458

    Article  CAS  Google Scholar 

  72. Peters RD, Yang XM, Kim TK, Sohn BH, Nealey PF (2000) Langmuir 16:4625

    CAS  Google Scholar 

  73. Rockford L, Liu Y, Mansky P, Russell TP, Yoon M, Mochrie SGJ (1999) Phys Rev Lett 82:2602

    Article  CAS  Google Scholar 

  74. Rockford L, Mochrie SGJ, Russell TP (2001) Macromolecules 34:1487

    Article  CAS  Google Scholar 

  75. Yang XM, Peters RD, Nealey PF, Solak HH, Cerrina F (2000) Macromolecules 33:9575

    CAS  Google Scholar 

  76. Kim SO, Solak HH, Stoykovich MP, Ferrier NJ, de Pablo JJ, Nealey PF (2003) Nature 424:411

    CAS  Google Scholar 

  77. Morkved TL, Lu M, Urbas AM, Ehrichs EE, Jaeger HM, Mansky P, Russell TP (1996) Science 273:931

    CAS  Google Scholar 

  78. Thurn-Albrecht T, Steiner R, DeRouchey J, Stafford CM, Huang E, Bal M, Tuominen M, Hawker CJ, Russell TP (2000) Adv Mater 12:787

    Article  CAS  Google Scholar 

  79. Thurn-Albrecht T, DeRouchey J, Russell TP, Jaeger HM (2000) Macromolecules 33:3250

    Article  CAS  Google Scholar 

  80. Mansky P, DeRouchey J, Russell TP, Mays J, Pitsikalis M, Morkved T, Jaeger H (1998) Macromolecules 31:4399

    Article  CAS  Google Scholar 

  81. Xu T, Hawker CJ, Russell TP (2003) Macromolecules 36:6178

    CAS  Google Scholar 

  82. Xu T, Goldbach JT, Russell TP (2003) Macromolecules 36:7296

    CAS  Google Scholar 

  83. Asakawa K, Hiraoka T, Hieda H, Sakurai M, Kamata Y, Naito D (2002) J Photopolym Sci Technol 15:465

    CAS  Google Scholar 

  84. Park C, De Rosa C, Thomas EL (2001) Macromolecules 34:2602

    CAS  Google Scholar 

  85. Segalman RA, Yokoyama H, Kramer EJ (2001) Adv Mater 13:1152

    Article  CAS  Google Scholar 

  86. Segalman RA, Hexemer A, Kramer EJ (2003) Macromolecules 36:6831

    CAS  Google Scholar 

  87. Hahn J, Webber SE (2004) Langmuir 20:1489

    CAS  Google Scholar 

  88. Heier J, Kramer EJ, Walheim S, Krausch G (1997) Macromolecules 30:6610

    Article  CAS  Google Scholar 

  89. Heier J, Genzer J, Kramer EJ, Bates FS, Walheim S, Krausch G (1999) J Chem Phys 111:11101

    Article  CAS  Google Scholar 

  90. Cheng JY, Ross CA, Thomas EL, Smith HI, Vancso GJ (2002) Appl Phys Lett 81:3657

    CAS  Google Scholar 

  91. Cheng JY, Ross CA, Thomas EL, Smith HI, Vancso GJ (2003) Adv Mater 15:1599

    Article  CAS  Google Scholar 

  92. Massey JA, Winnik MA, Manner I, Chan VZ-H, Ostermann JM, Enchelmaier R, Spatz JP, Möller M (2001) J Am Chem Soc 123:3147

    Article  CAS  Google Scholar 

  93. Temple K, Kulbaba K, Power-Billard KN, Manners I, Leach KA, Xu T, Russell TP, Hawker CJ (2003) Adv Mater 15:297

    Article  CAS  Google Scholar 

  94. Elhadj S, Woody JW, Niu VS, Saraf RF (2003) Appl Phys Lett 82:871

    Article  CAS  Google Scholar 

  95. De Rosa C, Park C, Thomas EL, Lotz B (2000) Nature 405:433

    Google Scholar 

  96. Reiter G, Castelein G, Hoerner P, Riess G, Blumen A, Sommer J-U (1999) Phys Rev Lett 83:3844

    Article  CAS  Google Scholar 

  97. Hong S, MacKnight WJ, Russell TP, Gido SP (2001) Macromolecules 34:2398

    CAS  Google Scholar 

  98. Hong S, MacKnight WJ, Russell TP, Gido SP (2001) Macromolecules 34:2876

    CAS  Google Scholar 

  99. Mansky P, Chaikin P, Thomas EL (1995) J Mater Sci 30:1987

    Article  CAS  Google Scholar 

  100. Turturro A, Gattiglia E, Vacca P, Viola GT (1995) Polymer 36:3987

    Article  CAS  Google Scholar 

  101. Kimura M, Misner MJ, Xu T, Kim SH, Russell TP (2003) Langmuir 19:9910

    CAS  Google Scholar 

  102. Park C, Cheng JY, Fasolka MJ, Mayers AM, Ross CA, Thomas EL, De Rosa C (2001) Appl Phys Lett 79:848

    CAS  Google Scholar 

  103. Lin ZQ, Kim DH, Wu XD, Boosahda L, Stone D, LaRose L, Russell TP (2002) Adv Mater 14:1373

    Article  CAS  Google Scholar 

  104. Fukunaga K, Elbs H, Magerle R, Krausch G (2000) Macromolecules 33:947

    Article  CAS  Google Scholar 

  105. Kim G, Libera M (1998) Macromolecules 31:2569

    CAS  Google Scholar 

  106. Ober CK, Li M, Douki K, Goto K, Li X (2003) J Photopolym Sci Technol 16:347

    CAS  Google Scholar 

  107. Du P, Li M, Douki K, Li X, Garcia CBW, Jain A, Smilgies DM, Fetters LJ, Gruner SM, Wiesner U, Ober CK (2004) Adv Mater 16:953

    Article  CAS  Google Scholar 

  108. Li M, Douki K, Goto K, Li X, Coenjarts C, Smilgies DM, Ober CK (2004) Chem Mater 16:3800

    CAS  Google Scholar 

  109. Walton DG, Kellogg GJ, Mayes AM, Lambooy P, Russell TP (1994) Macromolecules 27:6225

    Article  CAS  Google Scholar 

  110. Matsen MW (1997) J Chem Phys 106:7781

    CAS  Google Scholar 

  111. Geisinger T, Muller M, Binder K (1999) J Chem Phys 111:5251

    CAS  Google Scholar 

  112. Koneripalli N, Levicky R, Bates FS, Ankner J, Kaiser H, Satija SK (1996) Langmuir 12:6681

    Article  CAS  Google Scholar 

  113. Pickett GT, Balazs AC (1997) Macromolecules 30:3097

    Article  CAS  Google Scholar 

  114. Russell TP, Menelle A, Anastasiadis SH, Satija SK, Majkrzak CF (1991) Macromolecules 24:6263

    CAS  Google Scholar 

  115. Russell TP, Coulon G, Deline VR, Miller DC (1989) Macromolecules 22:4600

    Article  CAS  Google Scholar 

  116. Fredrickson GH (1987) Macromolecules 20:2535

    CAS  Google Scholar 

  117. Koneripalli N, Singh N, Levicky R, Bates FS, Gallagher PD, Satija SK (1995) Macromolecules 28:2897

    Article  CAS  Google Scholar 

  118. Anastasiadis SH, Russell TP, Satija SK, Majkrzak CF (1989) Phys Rev Lett 62:1852

    Article  CAS  Google Scholar 

  119. Henkee CS, Thomas EL, Fetters LJ (1988) J Mater Sci 23:1685

    Article  CAS  Google Scholar 

  120. Morkved TL, Jaeger HM (1997) Europhys Lett 40:643

    Article  CAS  Google Scholar 

  121. Pickett GT, Witten TA, Nagel SR (1993) Macromolecules 26:3194

    Article  CAS  Google Scholar 

  122. Genzer J, Kramer EJ (1997) Phys Rev Lett 78:4946

    Article  CAS  Google Scholar 

  123. Thurn-Albrecht T, DeRouchey J, Russell TP, Kolb R (2002) Macromolecules 35:8106

    Article  CAS  Google Scholar 

  124. Ober CK, Gabor AH (1996) J Photopoly Sci Tech 9:1

    CAS  Google Scholar 

  125. Reichmanis E, Ober CK, MacDonald SA, Iwayanagi T, Nishikudo T (eds) (1995) Microelectronics technology: Polymers in advanced imaging and packaging. ACS Symposium Series 614. American Chemical Society, Washington DC

    Google Scholar 

  126. Sundararajan N, Yang S, Ogino K, Valiyaveettil S, Wang J, Zhou X, Ober CK, Obendorf SK, Allen RD (2000) Chem Mater 12:41

    Article  CAS  Google Scholar 

  127. Hartney MA, Novembre AE, Bates FS (1985) J Vac Sci Technol B 3:1346

    CAS  Google Scholar 

  128. DeSimone JM, York GA, McGrath JE, Gozdz AS, Bowden MJ (1991) Macromolecules 24:5330

    Article  CAS  Google Scholar 

  129. Gabor AH, Lehner EA, Mao G, Schneggenburger LA, Ober CK (1994) Chem Mater 6:927

    Article  CAS  Google Scholar 

  130. Vasilev C, Heinzelmann H, Reiter G (2004) J Polym Sci B: Polym Phys 42:1312

    CAS  Google Scholar 

  131. Trimbach D, Feldman K, Spencer ND, Broer DJ, Bastiaansen CWM (2003) Langmuir 19:10957

    Article  CAS  Google Scholar 

  132. Podariu I, Chakrabarti A (2000) J Chem Phys 113:6423

    Article  CAS  Google Scholar 

  133. Wang Q, Nath SK, Graham MD, Nealey PF, de Pablo JJ (2000) J Chem Phys 112:9996

    CAS  Google Scholar 

  134. Deng T, Ha Y-H, Cheng JY, Ross CA, Thomas EL (2002) Langmuir 18:6719

    Article  CAS  Google Scholar 

  135. Yang P, Rizvi AH, Messer B, Chmelka BF, Whitesides GM, Stucky GD (2001) Adv Mater 13:427

    Google Scholar 

  136. Yang P, Wirnsberger G, Huang HC, Cordero SR, MaGehee MD, Scott B, Deng T, Whitesides GM, Chmelka BF, Buratto SK, Stucky GD (2000) Science 287:465

    CAS  Google Scholar 

  137. Fang H, Lu Y, Stump A, Reed ST, Baer T, Schunk R, Perez-Luna V, López GP, Brinker CJ (2000) Nature 405:56

    Google Scholar 

  138. Pereira GG, Williams DRM (1998) Macromolecules 31:5904

    Article  CAS  Google Scholar 

  139. Pereira GG, Williams DRM (1999) Macromolecules 32:758

    CAS  Google Scholar 

  140. Wang Q, Nealey PF, de Pablo JJ (2003) Macromolecules 36:1731

    CAS  Google Scholar 

  141. Pereira GG, Williams DRM (1998) Phys Rev Lett 80:2849

    Article  CAS  Google Scholar 

  142. Petera D, Muthukumar M (1998) J Chem Phys 109:5101

    Article  CAS  Google Scholar 

  143. Huang KL, Balazs AC (1991) Phys Rev Lett 66:620

    CAS  Google Scholar 

  144. Balazs AC, Huang K, McElwain P, Brady JE (1991) Macromolecules 24:714

    CAS  Google Scholar 

  145. Chakrabarti A, Chen H (1998) J Polym Sci Part B: Polym Phys 36:3127

    Article  CAS  Google Scholar 

  146. Peters RD, Yang XM, Wang Q, de Pablo JJ, Nealey PF (2000) J Vac Sci Technol B 18:3530

    Article  CAS  Google Scholar 

  147. Bal M, Ursache A, Tuominen MT, Goldbach JT, Russell TP (2002) Appl Phys Lett 81:3479

    Article  CAS  Google Scholar 

  148. Spatz JP, Chan VZ-H, Mößmer S, Kamm F-M, Plettl A, Ziemann P, Möller M (2002) Adv Mater 14:1827

    Article  CAS  Google Scholar 

  149. Glass R, Arnold M, Blümmel J, Küller A, Möller M, Spatz JP (2003) Adv Funct Mater 13:569

    Article  CAS  Google Scholar 

  150. Murray CB, Kagan CR, Bawendi MG (1995) Science 270:1335

    Article  CAS  Google Scholar 

  151. Turner SW, Perez AM, Lopez A, Craighead HG (1998) J Vac Sci Technol B 16:3835

    Article  CAS  Google Scholar 

  152. Harrison C, Park M, Chaikin PM, Register RA, Adamson DH (1998) J Vac Sci Technol B 16:544

    Article  CAS  Google Scholar 

  153. Cheng JY, Ross CA, Chan VZ-H, Thomas EL, Lammertink RGH, Vancso GJ (2001) Adv Mater 13:1174

    Article  CAS  Google Scholar 

  154. Park M, Chaikin PM, Register RA, Adamson DA (2001) Appl Phys Lett 79:257

    CAS  Google Scholar 

  155. Li RR, Dapkus PD, Thompson ME, Jeong WG, Harrison C, Chaikin PM, Register RA, Adamson DH (2000) Appl Phys Lett 76:1689

    CAS  Google Scholar 

  156. Black CT, Guarini KW, Milkove KR, Baker SM, Russell TP, Tuominen MT (2001) Appl Phys Lett 79:409

    Article  CAS  Google Scholar 

  157. Guarini KW, Black CT, Milkove KR, Sandstrom RL (2001) J Vac Sci Technol B 19:2784

    Article  CAS  Google Scholar 

  158. Spatz JP, Herzog T, Mößmer S, Ziemann P, Möller M (1999) Adv Mater 11:149

    Article  CAS  Google Scholar 

  159. Haupt M, Miller S, Glass R, Arnold M, Sauer R, Thonke K, Möller M, Spatz JP (2003) Adv Mater 15:829

    Article  CAS  Google Scholar 

  160. Lammertink RGH, Hempenius MA, van den Enk JE, Chan VZ-H, Thomas EL, Vancso GJ (2000) Adv Mater 12:98

    Article  CAS  Google Scholar 

  161. Russell TP, Thurn-Albrecht T, Tuominen M, Huang E, Hawker CJ (2000) Macromol Symp 159:77

    Article  CAS  Google Scholar 

  162. Lammertink RGH, Hempenius MA, Thomas EL, Vancso GJ (1999) J Polym Sci, Polym Phys Ed 37:1009

    CAS  Google Scholar 

  163. Lammertink RGH, Hempenius MA, Chan VZ-H, Thomas EL, Vancso GJ (2001) Chem Mater 13:429

    Article  CAS  Google Scholar 

  164. Spatz JP, Eibeck P, Mößmer S, Möller M, Herzog T, Ziemann P (1998) Adv Mater 10:849

    CAS  Google Scholar 

  165. Koslowski B, Stobel S, Herzog T, Heinz B, Boyen HG, Notz R, Ziemann P, Spatz JP, Möller M (2000) J Appl Phys 87:7533

    Article  CAS  Google Scholar 

  166. Urbas A, Fink Y, Thomas EL (1999) Macromolecules 32:4748

    Article  CAS  Google Scholar 

  167. Ruokolainen J, Mäkinen R, Torkkeli M, Mäkelä T, ten Brinke G, Ikkala O (1998) Science 280:557

    Article  CAS  Google Scholar 

  168. Morkved TL, Wiltzius P, Jaeger HM, Grier DG, Witten TA (1994) Appl Phys Lett 64:422

    Article  CAS  Google Scholar 

  169. Lopes WA, Jaeger HM (2001) Nature 414:735

    Article  CAS  Google Scholar 

  170. Tadd EH, Bradley J, Tannenbaum R (2002) Langmuir 18:2378

    Article  CAS  Google Scholar 

  171. Tadd EH, Bradley J, Goldberg EP, Tannenbaum R (2002) Mat Res Soc Symp Proc 707:205

    CAS  Google Scholar 

  172. Brown GD, Watkins JJ (2000) Mater Res Soc Symp Proc 584:169

    CAS  Google Scholar 

  173. Abes JI, Cohen RE, Ross CA (2003) Chem Mater 15:1125

    Article  CAS  Google Scholar 

  174. Abes JI, Cohen RE, Ross CA (2003) Mater Sci Eng C23:641

    CAS  Google Scholar 

  175. Möller M, Spatz JP, Roescher A (1996) Adv Mater 8:337

    Google Scholar 

  176. Goren M, Lennox RB (2001) Nano Lett 1:735

    Article  CAS  Google Scholar 

  177. Lee T, Yao N, Aksay IA (1997) Langmuir 13:3866

    CAS  Google Scholar 

  178. Kane RS, Cohen RE, Silbey R (1996) Chem Mater 8:1919

    CAS  Google Scholar 

  179. Fogg DE, Radzilowski LH, Blanski R, Schrock RR, Thomas EL (1997) Macromolecules 30:417

    CAS  Google Scholar 

  180. Ansari IA, Hamley IW (2003) J Mater Chem 13:2412

    Article  CAS  Google Scholar 

  181. Wong MS, Cha JN, Choi K-S, Deming TJ, Stucky GD (2002) Nano Lett 2:583

    Article  CAS  Google Scholar 

  182. Sone ED, Zubarev ER, Stupp SI (2002) Angew Chem Int Ed 41:1705

    Article  CAS  Google Scholar 

  183. Park C, McAlvin JE, Fraser CL, Thomas EL (2002) Chem Mater 14:1225

    CAS  Google Scholar 

  184. Manners I (2001) Science 294:1664

    Article  CAS  Google Scholar 

  185. Wang X-S, Arsenault A, Ozin GA, Winnik MA, Manners I (2003) J Am Chem Soc 125:12686

    CAS  Google Scholar 

  186. Kowalewski T, Tsarevsky NV, Matyjaszewski K (2002) J Am Chem Soc 124:10632

    Article  CAS  Google Scholar 

  187. Wu CG, Bein T (1994) Science 264:1757

    CAS  Google Scholar 

  188. Martin CR (1996) Chem Mater 8:1739

    CAS  Google Scholar 

  189. Foss CA, Hornyak GL, Stockert JA, Martin CR (1992) J Phy Chem 96:7497

    CAS  Google Scholar 

  190. Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS (1992) Nature 359:710

    Article  CAS  Google Scholar 

  191. Lee H-K, Lee H, Ko YH, Chang YJ, Oh N-K, Zin W-C, Kim K (2001) Angew Chem Int Ed 40:2669

    Google Scholar 

  192. Krause B, Sijbesma HJP, Münüklü P, van der Vege NFA, Wessling M (2001) Macromolecules 34:8792

    CAS  Google Scholar 

  193. Chan VZ-H, Hoffman J, Lee VY, Iatrou H, Avgeropoulos A, Hadjichristidis N, Miller RD, Thomas EL (1999) Science 286:1716

    Article  CAS  Google Scholar 

  194. Corma A (1997) Chem Rev 97:2373

    Article  CAS  Google Scholar 

  195. Gin DL, Gu W (2001) Adv Mater 13:1407

    Article  CAS  Google Scholar 

  196. Feng X, Fryxell GE, Wang L-Q, Kim AY, Liu J, Kemner KM (1997) Science 276:923

    Article  CAS  Google Scholar 

  197. Mercier L, Pinnavaia TJ (1997) Adv Mater 9:500

    Article  CAS  Google Scholar 

  198. Lee SB, Mitchell DT, Trofin L, Nevanen TK, Södelund H, Martin CR (2002) Science 296:2198

    CAS  Google Scholar 

  199. Yang S, Mirau PA, Pai C-S, Nalamasu O, Reichmanis E, Pai JC, Obeng YS, Seputro J, Lin EK, Lee H-J, Sun J, Gidley DW (2002) Chem Mater 14:369

    CAS  Google Scholar 

  200. Hedrick JL, Miller RD, Hawker CJ, Carter KR, Volksen W, Yoon DY, Trollsås M (1998) Adv Mater 10:1049

    Article  CAS  Google Scholar 

  201. Huo Q, Magolese DI, Ciesla U, Feng P, Gier TE, Sieger P, Leon R, Petroff PM, Schüth F, Stucky GD (1994) Nature 368:317

    Article  CAS  Google Scholar 

  202. Harrison DJ, Fluri K, Seiler K, Fan Z, Effenhauser CS, Manz A (1993) Science 261:895

    CAS  Google Scholar 

  203. Zhao D, Feng J, Huo Q, Melosh N, Fredrickson GH, Chmelka BF, Stucky GD (1998) Science 279:548

    CAS  Google Scholar 

  204. Kruk M, Jaroniec M, Ko CH, Ryoo R (2000) Chem Mater 12:1961

    CAS  Google Scholar 

  205. Van Grieken R, Calleja G, Stucky GD, Melero JA, Garcia RA, Iglesias J (2003) Langmuir 19:3966

    Google Scholar 

  206. Yang C-M, Zibrowius B, Schmidt W, Schüth F (2003) Chem Mater 15:3739

    CAS  Google Scholar 

  207. Kriesel JW, Sander MS, Tilley TD (2001) Chem Mater 13:3554

    Article  CAS  Google Scholar 

  208. Yang P, Zhao D, Margolese DI, Chemlka BF, Stucky GD (1998) Nature 396:152

    CAS  Google Scholar 

  209. Templin M, Franck A, Chesne AD, Leist H, Zhang Y, Ulrich R, Schädler V, Wiesner U (1997) Science 278:1795

    Article  CAS  Google Scholar 

  210. Krämer E, Förster S, Göltner C, Antonietti M (1998) Langmuir 14:2027

    Google Scholar 

  211. Lee J-S, Hirao A, Nakahama S (1988) Macromolecules 21:274

    CAS  Google Scholar 

  212. Xu T, Stevens J, Villa JA, Goldbach JT, Guarini KW, Black CT, Hawker CJ, Russell TP (2003) Adv Fun Mater 13:698

    CAS  Google Scholar 

  213. Jeong U, Ryu DY, Kim JK, Kim DH, Russell TP, Hawker CJ (2003) Adv Mater 15:1247

    CAS  Google Scholar 

  214. Jeong U, Kim H-C, Rodriguez RL, Tsai IY, Stafford CM, Kim JK, Hawker CJ, Thomas TP (2002) Adv Mater 14:274

    Article  CAS  Google Scholar 

  215. Liu G, Ding J, Hashimoto T, Kimishima K, Winnik FM, Nigam S (1999) Chem Mater 11:2233

    CAS  Google Scholar 

  216. Zalusky AS, Olayo-Valles R, Wolf JH, Hillmyer MA (2002) J Am Chem Soc 124:12761

    Article  CAS  Google Scholar 

  217. Zalusky AS, Olayo-Valles R, Taylor CJ, Hillmyer MA (2001) J Am Chem Soc 123:1519

    Article  CAS  Google Scholar 

  218. Wolf JH, Hillmyer MA (2003) Langmuir 19:6553

    Article  CAS  Google Scholar 

  219. Mäki-Ontto R, de Moel K, de Odorico W, Ruokolainen J, Stamm M, ten Brinke G, Ikkala O (2001) Adv Mater 13:117

    Google Scholar 

  220. Antonietti M, Göltner C (1997) Angew Chem Int Ed 36:910

    Google Scholar 

  221. Ying JY, Mehnert CP, Wong MS (1999) Angew Chem Int Ed 38:56

    Article  CAS  Google Scholar 

  222. Förster S, Antonietti M (1998) Adv Mater 10:195

    Google Scholar 

  223. Golner CG, Antonietti M (1997) Adv Mater 9:431

    Google Scholar 

  224. Thomas A, Schlaad H, Smarsly B, Antonietti M (2003) Langmuir 19:4455

    CAS  Google Scholar 

  225. Zhao D, Yang P, Melosh N, Feng J, Chmelka BF, Stucky GD (1998) Adv Mater 10:1380

    Article  CAS  Google Scholar 

  226. Pal RA, Humayun R, Schulberg MT, Sengupta A, Sun J-N, Watkins JJ (2004) Science 303:507

    Google Scholar 

  227. Liu G, Ding J, Stewart S (1999) Angew Chem Int Ed 38:835

    CAS  Google Scholar 

  228. Buchmeiser MR (2001) Angew Chem Int Ed 40:3795

    CAS  Google Scholar 

  229. Drzal PL, Halasa AF, Kofinas P (2000) Polymer 41:4671

    Article  CAS  Google Scholar 

  230. Pitois O, Francois B (1999) Colloid Polym Sci 277:574

    Article  CAS  Google Scholar 

  231. Karthaus O, Maruyama N, Cieren X, Shimomura M, Hasegawa H, Hashimoto T (2000) Langmuir 16:6071

    Article  CAS  Google Scholar 

  232. Kesting RE (1985) Synthetic polymer membranes. Wiley, New York

    Google Scholar 

  233. Shin K, Leach KA, Goldbach JT, Kim DH, Jho JY, Tuominen M, Hawker CJ, Russell TP (2002) Nano Lett 2:933

    Article  CAS  Google Scholar 

  234. Parthasarathy RV, Phani KLN, Martin CR (1995) Adv Mater 7:896

    Article  CAS  Google Scholar 

  235. Kim H-C, Jia X, Stafford CM, Kim DH, McCarthy TJ, Tuominen M, Hawker CJ, Russell TP (2001) Adv Mater 13:795

    CAS  Google Scholar 

  236. Misner MJ, Skaff H, Emrick T, Russell TP (2003) Adv Mater 15:221

    Article  CAS  Google Scholar 

  237. Nguyen T-Q, Wu J, Doan V, Schwartz BJ, Tolbert SH (2000) Science 288:652

    Article  CAS  Google Scholar 

  238. Parthasarathy RV, Martin CR (1994) Nature 369:298

    Article  CAS  Google Scholar 

  239. Kim DH, Lin Z, Kim H-C, Jeong U, Russell TP (2003) Adv Mater 15:811

    CAS  Google Scholar 

  240. Martin CR (1994) Science 266:1961

    CAS  Google Scholar 

  241. Jeoung E, Galow TH, Schotter J, Bal M, Ursache A, Tuominen MT, Stafford CM, Russell TP, Rotello VM (2001) Langmuir 17:6396

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The research reported here was supported by the Nanobiotechnogy Center (NBTC), an STC Program of the National Science Foundation under Agreement No. ECS-9876771. We also thanks the Cornell Center for Materials Research (CCMR) and Cornell Nanofabrication Center (CNF) for use of their facilities.

Author information

Authors and Affiliations

  1. Department of Materials Science and Engineering, Cornell University, Bard Hall 310, 14853, Ithaca, NY, USA

    Mingqi Li, Christopher A. Coenjarts & Christopher K. Ober

Authors
  1. Mingqi Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Christopher A. Coenjarts
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Christopher K. Ober
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Christopher K. Ober .

Editor information

Volker Abetz

Rights and permissions

Reprints and permissions

About this chapter

Cite this chapter

Li, M., Coenjarts, C.A., Ober, C.K. Patternable Block Copolymers. In: Abetz, V. (eds) Block Copolymers II. Advances in Polymer Science, vol 190. Springer, Berlin, Heidelberg. https://doi.org/10.1007/12_003

Download citation

Publish with us

Policies and ethics

Search

Navigation