About this book

Introduction

The unique properties and applications of transition metal compounds have long fascinated both physicists and chemists. This volume presents theoretical and experimental studies for a deeper understanding of the electronic and vibronic properties of these compounds. In particular, an introduction into properties of spin sublevels of dd*, dÂ*, and ÂÂ* states is given, and a modern ligand field theory based on the Angular Overlap Model is presented. In experimental case studies it is shown how to characterize different types of electronic transitions using modern methods of laser spectroscopy. Consequences of spin-orbit coupling, zero-field splittings, spin-lattice relaxations, chromophore-matrix interactions, Herzberg-Teller/Franck-Condon activities, and localization/delocalization properties are treated.

Keywords

Absorption Elektronenstruktur Laser Ligandenfeld-Theorie Spektroskopie electronic structure ligand field theory spectroscopy transition metal compounds Übergangsmetallverbindung

Bibliographic information

  • DOI https://doi.org/10.1007/BFb0119208
  • Copyright Information Springer-Verlag 1997
  • Publisher Name Springer, Berlin, Heidelberg
  • eBook Packages Springer Book Archive
  • Print ISBN 978-3-540-62922-1
  • Online ISBN 978-3-540-69047-4
  • Series Print ISSN 0340-1022
  • Series Online ISSN 1436-5049
  • About this book