Skip to main content
SpringerLink
Log in

Selectivities in Lewis Acid Promoted Reactions

  • Book
  • © 1989

Overview

Editors:
  1. Dieter Schinzer

    1. Institut für Organische Chemie, Universität Göttingen, Göttingen, Germany

    View editor publications

    You can also search for this editor in PubMed   Google Scholar

Part of the book series: Nato Science Series C: (ASIC, volume 289)

This is a preview of subscription content, log in via an institution to check access.

Access this book

Log in via an institution
eBook USD 169.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Other ways to access

Licence this eBook for your library

Institutional subscriptions

Table of contents (30 chapters)

  1. Front Matter

    Pages i-xv
    Download chapter PDF

  2. Cationic Cyclization Reactions Terminated by Pinacol Rearrangements

    • Larry E. Overman
    Pages 1-20

  3. Control of Electrophilicity in Aliphatic Friedel Crafts Reactions

    • Herbert Mayr
    Pages 21-36

  4. New Reactions of Ketene Silyl Acetals with Imines Promoted by Titanium(IV) and Zirconium(IV) Chlorides

    • Iwao Ojima, Stephan M. Brandstadter
    Pages 37-52

  5. Stereoselective Synthesis with Silyl Ketene Acetals and TiCl4

    • C. Gennari
    Pages 53-71

  6. Mechanistic Variability in the Lewis Acid-Promoted Reactions of Aldehydes with Organostannanes

    • G. E. Keck, S. Castellino, M. B. Andrus
    Pages 73-105

  7. Synthetic and Mechanistic Studies of Lewis Acid Mediated C-C-Bond Formation

    • M. T. Reetz
    Pages 107-125

  8. Acylation of Alkenes and Allylsilanes

    • Maurice Santelli, Ariette Tubul, Christophe Morel-Fourrier
    Pages 127-145

  9. Alkylaluminum Halide Induced Reactions of Carbonyl Compounds with Unactivated Alkenes

    • Barry B. Snider
    Pages 147-167

  10. Intramolecular Additions of Allylsilanes to Conjugated Dienones

    • George Majetich, Kenneth Hull, Derric Lowery, Clay Ringold, Jean Defauw
    Pages 169-188

  11. Lewis Acid-Catalyzed Stereoselection on Carbohydrate Templates

    • Horst Kunz
    Pages 189-202

  12. Lewis Acid Character and Selective Reactions of Penta-Coordinate Silicon Compounds

    • Hideki Sakurai
    Pages 203-226

  13. Synthesis of Clerodane Diterpenes via Lewis Acid Catalyzed Cycloadditions

    • Michael J. Taschner
    Pages 227-246

  14. Studies on the Mechanism of Allylmetal-Acetal Additions

    • Scott E. Denmark, Timothy M. Wilson
    Pages 247-263

  15. Stereocontrol in Organic Synthesis Using Silicon Compounds

    • Ian Fleming, Dick Higgins, Achintya K. Sarkar
    Pages 265-280

  16. Chiral Lewis Acid Catalysts Organoaluminum and Boron Reagent

    • Hisashi Yamamoto, Keiji Maruoka, Kyoji Furuta
    Pages 281-294

  17. Access to Trifluoromethyl Indans by Cycloalkylation of β-Aryl Trifluoromethyl-Ketones

    • Corinne Aubert, Jean-Pierre Bégué, Danièle Bonnet-Delpon, Dany Mesureur
    Pages 295-295

  18. A Route to Aliphatic Cycles Bearing a CF3 Group

    • Corinne Aubert, Jean-Pierre Bégué, Danièle Bonnet-Delpon
    Pages 297-297

  19. Lewis Acid Promoted Synthesis of β-Lactams

    • A. D. Brown, E. W. Colvin, M. J. Nugent
    Pages 299-299

  20. Lewis Acid Promoted Rearrangements of Vinyl Acetates — Basics and Applications

    • Herbert Frauenrath
    Pages 301-302
Back to top

Keywords

About this book

The ASI workshop on "Selectivities in Lewis Acid Promoted Reactions" held in the Emmantina-Hotel in Athens-Glyfada, Greece, October 2-7, 1988 was held to bring some light into the darkness of Lewis acid induced processes. As such the workshop reflects some current trends in organic synthesis, where Lewis acids are becoming a powerful tool in many different modern reactions, e.g. Diels-Alder reactions, Ene reactions, Sakurai reactions, and in general silicon and tin chemistry. The objective of this meeting was to bring together most of the world experts in the field to discuss the major reactions promoted by Lewis acids. Organic synthesis will play a major role in this book connected with some fundamental mechanistic work on allylsilane and -tin chemistry. Both natural product synthesis and unnatural molecules are presented in the chapters. The book presents all the 15 invited lectures and the contributions of 15 posters. I am confident that the material presented in this book will stimulate the chemistry, which has been discussed on our meeting, around the world. The meeting and the book were only possible through a grant of the NATO Scientific Affairs Devision and financial support by the following companies: Kali Chemie (Hannover, W-Germany), E. Merck (Darmstadt, W-Germany), Sandoz (Basel, Switzerland), Schering (Berlin, W-Germany).

Editors and Affiliations

  • Institut für Organische Chemie, Universität Göttingen, Göttingen, Germany

    Dieter Schinzer

Bibliographic Information

  • Book Title: Selectivities in Lewis Acid Promoted Reactions

  • Editors: Dieter Schinzer

  • Series Title: Nato Science Series C:

  • DOI: https://doi.org/10.1007/978-94-009-2464-2

  • Publisher: Springer Dordrecht

  • eBook Packages: Springer Book Archive

  • Copyright Information: Kluwer Academic Publishers 1989

  • Hardcover ISBN: 978-0-7923-0452-4Published: 30 September 1989

  • Softcover ISBN: 978-94-010-7611-1Published: 04 October 2011

  • eBook ISBN: 978-94-009-2464-2Published: 06 December 2012

  • Series ISSN: 1389-2185

  • Edition Number: 1

  • Number of Pages: XVI, 333

  • Topics: Organic Chemistry

Publish with us

Policies and ethics

Back to top

Search

Navigation