Advertisement

Mn Manganese D 5

Coordination Compounds 5

  • Karl Koeber
  • Helga Köttelwesch
  • Dietrich Schneider
  • Helga Demmer
  • Helga Köttelwesch
  • Edith Schleitzer-Rust

Part of the Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition book series (GMELIN, volume M-n / D / 5)

Table of contents

  1. Front Matter
    Pages N2-XIX
  2. Karl Koeber, Helga Köttelwesch, Dietrich Schneider, Helga Demmer, Edith Schleitzer-Rust
    Pages 1-2
  3. Karl Koeber, Helga Köttelwesch, Dietrich Schneider, Helga Demmer, Edith Schleitzer-Rust
    Pages 3-86
  4. Karl Koeber, Helga Köttelwesch, Dietrich Schneider, Helga Demmer, Edith Schleitzer-Rust
    Pages 87-89
  5. Karl Koeber, Helga Köttelwesch, Dietrich Schneider, Helga Demmer, Edith Schleitzer-Rust
    Pages 90-166
  6. Karl Koeber, Helga Köttelwesch, Dietrich Schneider, Helga Demmer, Edith Schleitzer-Rust
    Pages 167-210
  7. Karl Koeber, Helga Köttelwesch, Dietrich Schneider, Helga Demmer, Edith Schleitzer-Rust
    Pages 211-230
  8. Karl Koeber, Helga Köttelwesch, Dietrich Schneider, Helga Demmer, Edith Schleitzer-Rust
    Pages 231-277
  9. Karl Koeber, Helga Köttelwesch, Dietrich Schneider, Helga Demmer, Edith Schleitzer-Rust
    Pages 278-317
  10. Karl Koeber, Helga Köttelwesch, Dietrich Schneider, Helga Demmer, Edith Schleitzer-Rust
    Pages 318-320
  11. Back Matter
    Pages 321-351

About this book

Introduction

The present volume, "Manganese" D 5, continues the description of the manganese complexes. The arrangement of the complexes in these D volumes is based on the ligand type. The introduction, on p. 1, shows the classes of complexes, which have already been described in Chapters 1 to 21 in the Volumes D 1 (1979), D 2 (1980), D 3 (1982), and D 4 (1985). In Chapters 22 to 29 of this volume are treated complexes with amine-N-polycarboxylic acids, hydrazinecarboxylic acids, amides, hydrazides, derivatives of hydroxylamine (e.g., hydroxamic acids), oximes and nitroso compounds, azo compounds, and triazenes. A survey at the beginning of each of these sections gives information on the most characteristic features of the various complex types. Because of the complexometric relevance of the complexes with amine-N-polycarboxylic acids, there are many studies concerning the existence and the stability of the complexes in solution. Numerous X-ray investigations, reported for the complexes with urea or with amides and hydrazides of carboxylic acids, show the different structures of the compounds as a result of the varying bonding sites of the ligands. Complexes with hydrazides (e.g., with isonicotino­ hydrazide) are of special interest, due to their biological activity. Complexes with hydroxamic acids, oximes or azo compounds have been studied mostly in aqueous organic or pure organic solvents. The characteristic intense colors of many solutions are used for the analytical determination of manganese.

Keywords

Hydrazin Hydroxylamin chemical bond manganese

Authors and affiliations

  • Karl Koeber
    • 1
  • Helga Köttelwesch
    • 1
  • Dietrich Schneider
    • 1
  1. 1.Gmelin-InstitutFrankfurt am MainGermany

Editors and affiliations

  • Helga Demmer
    • 1
  • Helga Köttelwesch
    • 1
  • Edith Schleitzer-Rust
    • 1
  1. 1.Gmelin-InstitutFrankfurt am MainGermany

Bibliographic information

  • DOI https://doi.org/10.1007/978-3-662-08175-4
  • Copyright Information Springer-Verlag Berlin Heidelberg 1987
  • Publisher Name Springer, Berlin, Heidelberg
  • eBook Packages Springer Book Archive
  • Print ISBN 978-3-662-08177-8
  • Online ISBN 978-3-662-08175-4
  • Buy this book on publisher's site