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S Sulfur-Nitrogen Compounds

Compounds with Sulfur of Oxidation Number IV

  • Authors
  • Hans-Jürgen Fachmann
  • Reimund Jotter
  • Alfons Kubny
  • Joachim Wagner
  • Editors
  • Norbert Baumann
  • Gerhard Czack
  • Brigitte Heibel
  • Peter Merlet
  • Joachim Wagner
  • Alfons Kubny

Part of the Gmelin Handbook of Inorganic Chemistry / Gmelin Handbuch der Anorganischen Chemie book series (GMELIN, volume S / S-N / 5)

Table of contents

  1. Front Matter
    Pages N1-XVI
  2. Hans-Jürgen Fachmann, Reimund Jotter, Alfons Kubny, Joachim Wagner, Norbert Baumann, Gerhard Czack et al.
    Pages 1-87
  3. Hans-Jürgen Fachmann, Reimund Jotter, Alfons Kubny, Joachim Wagner, Norbert Baumann, Gerhard Czack et al.
    Pages 88-274
  4. Back Matter
    Pages 275-277

About this book

Introduction

The present volume is the first of a series describing acyclic sulfur-nitrogen compounds with sulfur of oxidation number IV. The acyclic sw-N compounds are arranged according to the coordination number of the sulfur. Neutral compounds are described before ions and complex compounds. The preceding series "Sulfur-Nitrogen Compounds" Parts 2, 3, and 4 covers the cyclic sw-N compounds. In this volume, the first section deals with sulfur-nitrogen compounds with 1-coordinate sulfur and begins with the sulfur nitride {thiazyl) radical, SN. This transient molecule was observed in its electronic ground state and several electronically excited states. The descrip­ tions of the sulfur nitride (thiazyl) ions SN+ and SW follow. The SN+ ionwas studied in the gas phase as weil as in the solid state where it forms salts. Thionitrosyl complexes containing the SN Iigand as a terminal linear unit are described at the end of the first section. The second section concerns Sulfur-nitrogen compounds with 2-coordinate sulfur and starts with the description of poly(sulfur nitride), (SNlx· The preparation, crystal structure, and metallic and superconducting properties of (SN)x, which were extensively studied, fill a !arge part of the volume. Halogen-modified poly(sulfur nitride) such as the widely studied (SNBr )x 04 and Na-modified poly(sulfur nitride) are dealt with in the following chapters.

Keywords

Oxidation chemistry metals

Bibliographic information

  • DOI https://doi.org/10.1007/978-3-662-06357-6
  • Copyright Information Springer-Verlag Berlin Heidelberg 1989
  • Publisher Name Springer, Berlin, Heidelberg
  • eBook Packages Springer Book Archive
  • Print ISBN 978-3-662-06359-0
  • Online ISBN 978-3-662-06357-6
  • Buy this book on publisher's site