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Working with Ion-Selective Electrodes

Chemical Laboratory Practice

  • Karl Cammann

Part of the Chemical Laboratory Practice book series (CHEMICAL LABORA)

Table of contents

  1. Front Matter
    Pages I-XII
  2. Karl Cammann
    Pages 1-5
  3. Karl Cammann
    Pages 6-30
  4. Karl Cammann
    Pages 31-48
  5. Karl Cammann
    Pages 49-104
  6. Karl Cammann
    Pages 162-193
  7. Back Matter
    Pages 194-226

About this book

Introduction

The first section introduces the electrochemical nomenclature necessary for under­ standing the literature on ion-selective electrodes and discusses the general principles behind all electrodes. The second section is concerned with the problems which arise in any accurate elec­ trode potential measurement in practice. Here the most important reference electrodes are discussed with special reference to their use in conjunction with ion-selective elec­ trodes. From experience, almost 75% of all problems which arise when working with ion-selective electrodes are on account of the reference electrode. After the reader is aquainted with the basic problems involved, the third section deals with individual ion-selective electrodes; their properties, handling and methods of pre­ paration. Here the discussion of these electrodes is not arranged according to the spe­ cies detected, but rather according to the kind of construction, since from this view­ point characteristic properties are much the same and handling procedures need only be described once for an entire series of similar electrodes. The fourth section discusses amplifiers. Here the problems of high-ohmic EMF meas­ urements such as noise level, insulation, static charging and ground loops are discussed. The fifth section is devoted to the various evaluation methods. Here a few schemes and examples are provided to indicate optimum practical procedures and the accura­ cies attainable with the various methods are discussed. The last section describes special set-ups such as clinical flow-thru cells, microelec­ trodes for measuring intracellular ionic activities, industrial on-line techniques and continuous environmental protection monitors.

Keywords

Chlorid Cyanid Electrodes Elektrode Membranelektrode Thallium Titration cells environment iron measurement nomenclature sensor sensors temperature

Authors and affiliations

  • Karl Cammann
    • 1
  1. 1.Abteilung für Analytische ChemieUniversität UlmUlmGermany

Bibliographic information

  • DOI https://doi.org/10.1007/978-3-642-67276-7
  • Copyright Information Springer-Verlag Berlin Heidelberg 1979
  • Publisher Name Springer, Berlin, Heidelberg
  • eBook Packages Springer Book Archive
  • Print ISBN 978-3-642-67278-1
  • Online ISBN 978-3-642-67276-7
  • Series Print ISSN 0172-4967
  • Buy this book on publisher's site