Hydroboration and Organic Synthesis

9-Borabicyclo[3.3.1]nonane (9-BBN)

  • Ranjit S. Dhillon

Table of contents

About this book

Introduction

9-Borabicyclo [3.3.1]nonane, a commercially available reagent, is the most versatile hydroborating reagent to synthesize organoboranes (B-R-9-BBN). The reagent exhibits remarkable regio-, chemo-, and stereoselectivity during hydroboration reactions. The organoboranes can be converted to C-H, C-O, C-N, C-S, C-halogen, C-metal and above all C-C bonds. In addition, the suitable substituted / unsaturated R of B-R-9-BBN can be utilized to produce dienes, enynes, allenes etc. with defined stereochemistry. 9-BBN’s derivatives have been elegantly used for the asymmetric reduction of ketone moiety. Diels-Alder and Suzuki reactions have expanded the utility of 9-BBN for the synthesis of a variety of organic compounds required for industry. Consequently, this vast field in the form of a book will be helpful to synthetic organic chemists for easy access to literature, required for chemical transformations.

Keywords

Medicinal Chemistry Stereoselective Synthesis chemistry organic synthesis synthesis

Authors and affiliations

  • Ranjit S. Dhillon
    • 1
  1. 1.Department of Biochemistry and ChemistryPunjab Agricultural UniversityLudhianaIndia

Bibliographic information

  • DOI https://doi.org/10.1007/978-3-540-49076-0
  • Copyright Information Springer-Verlag Berlin Heidelberg 2007
  • Publisher Name Springer, Berlin, Heidelberg
  • eBook Packages Chemistry and Materials Science
  • Print ISBN 978-3-540-49075-3
  • Online ISBN 978-3-540-49076-0
  • About this book