Inorganic and Metal-Containing Polymeric Materials

1. Prearranged Poly-4-Vinylpyridine Nickel Complexes as Catalysts for the Hydrogenation of Allyl Alcohol

   • Aiaz A. Efendiev, Jumshud J. Orujev, Elmar B. Amanov, Yusif M. Sultanov

   Pages 255-264

2. Polymers with Ligated Peroxotungstic Units: Organophosphoryl Macroligands for the Catalytic Epoxidation of Alkenes

   • Georges Gelbard, David C. Sherrington, François Breton, Mohamed Benelmoudeni, Marie-Thérèse Charreyre, Doan Dong

   Pages 265-275

3. Cobalt Dicarbollide Containing Polymer Resins for Cesium and Strontium Uptake

   • W. P. Steckle Jr., J. R. Duke Jr., B. S. Jorgensen

   Pages 277-285

4. Magnetic Investigations on Cu(II)- And Fe(III)-Containing Liquid Crystalline Metallopolymers

   • W. Haase, K. Griesar, E. A. Soto-Bustamante, Yu. G. Galyametdinov

   Pages 287-299

5. Novel Photonic Materials Containing Porphyrin Rings

   • Zhenan Bao, Luping Yu

   Pages 301-312

6. Metal-Containing Polymers as Precursors for the Production of Ferromagnetic and Superconducting Materials

   • A. D. Pomogailo, A. S. Rozenberg, G. I. Dzhardimalieva

   Pages 313-329

7. Bridged Macrocyclic Transition Metal-Oligomers, Synthesis and Electrical Properties

   • Michael Hanack

   Pages 331-336

8. Enhancement of Dimensional Stability in Soluble Polyimides via Lanthanide (III) Additives

   • Robin E. Southward, D. Scott Thompson, David W. Thompson, Anne K. St. Clair

   Pages 337-347

9. Preparation of Silvered Polyimide Mirrors via Self-Metallizing Poly(Amic Acid) Resins

   • Robin E. Southward, D. Scott Thompson, David W. Thompson, Maggie L. Caplan, Anne K. St. Clair

   Pages 349-356

10. Polyimides Doped with Silver-II: Surface Conductive Films

    • Adley F. Rubira, James D. Rancourt, Larry T. Taylor

    Pages 357-368

11. Investigation of the Ion-Binding Properties of Tactic Poly(Methacrylic Acids) Using Terbium (III) Ion as a Fluorescent Probe

    • Hannia Luján-Upton, Yoshiyuki Okamoto

    Pages 369-382

12. Rational Design of Novel Polyelectrolytes: Aluminosilicate/Poly(Ethylene Glycol) Copolymers

    • Glenn C. Rawsky, Duward F. Shriver

    Pages 383-393

13. Determination of Acidity in the Interior of the Cross-Linked Polyelectrolyte Grain by the Use of pH-Sensitive Probes

    • Leonid S. Molochnikov, Elena G. Kovalyova, Igor’ A. Grigor’ev, Vladimir A. Reznikov

    Pages 395-401

14. Molecular Complexes of Cellulose with Metals New Development

    • Nina E. Kotelnikova, Deitrich Fengel, Valery P. Kotelnikov

    Pages 403-408

15. Electron Impact Mass Spectroscopy of Condensation Metal-Containing Polymers

    • Charles E. Carraher Jr., J. William Louda, Dorothy Sterling, Earl Baker, Alberto Rivalta, Qingmao Zhang

    Pages 409-420

16. Model Systems and Structure, Function and Reactivity Relationships in Transition Metal-Containing Biopolymers

    • Geoffrey B. Jameson

    Pages 421-480

17. Incorporation of Square-Planar Metal Binding Sites into Protein Polymeric Structures

    • Eric C. Long, Paula D. Eason, Daniel F. Shullenberger

    Pages 481-489

18. Dynamic Aspects of Electron-Transfer Reactions in Metalloprotein Complexes

    • Nenad M. Kostić

    Pages 491-500

19. Back Matter

    Pages 501-518

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Research on metal-containing polymers began in the early 1960's when several workers found that vinyl ferrocene and other vinylic transition metal TI -complexes would undergo polymerization under the same conditions as conventional organic monomers to form high polymers which incorporated a potentially reactive metal as an integral part of the polymer structures. Some of these materials could act as semi­ conductors and possessed one or two dimensional conductivity. Thus applications in electronics could be visualized immediately. Other workers found that reactions used to make simple metal chelates could be used to prepare polymers if the ligands were designed properly. As interest in homogeneous catalysts developed in the late 60's and early 70's, several investigators began binding homogeneous catalysts onto polymers, where the advantage of homogeneous catalysis - known reaction mechanisms and the advantage of heterogeneous catalysis - simplicity and ease of recovery of catalysts could both be obtained. Indeed the polymer matrix itself often enhanced the selectivity of the catalyst. The first symposium on Organometallic Polymers, held at the National Meeting of the American Chemical Society in September 1977, attracted a large number of scientists interested in this field, both established investigators and newcomers. Subsequent symposia in 1977, 1979, 1983, and 1987 have seen the field mature. Hundreds of papers and patents have been published.

• Additiv
• Compound
• Copolymer
• Pentad
• Polyethylen
• Polyimide
• Polymer
• Raman spectroscopy
• ceramics
• spectroscopy

• Mississippi State University, USA

  Charles U. Pittman

• Florida Atlantic University, Boca Raton, USA

  Charles E. Carraher

• City University of New York, New York, USA

  Martel Zeldin

• Rider College, Lawrenceville, USA

  John E. Sheats

• Ohio State University, Columbus, USA

  Bill M. Culbertson

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