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HETEROGENEOUS ENANTIOSELECTIVE HYDROGENATION

Theory and Practice

  • EVGENII KLABUNOVSKII
  • GERARD V. SMITH
  • ÁGNES ZSIGMOND

Part of the Catalysis by Metal Complexes book series (CMCO, volume 31)

Table of contents

  1. Front Matter
    Pages I-XIV
  2. EVGENII KLABUNOVSKII, GERARD V. SMITH, ÁGNES ZSIGMOND
    Pages 1-29
  3. EVGENII KLABUNOVSKII, GERARD V. SMITH, ÁGNES ZSIGMOND
    Pages 31-61
  4. EVGENII KLABUNOVSKII, GERARD V. SMITH, ÁGNES ZSIGMOND
    Pages 63-75
  5. EVGENII KLABUNOVSKII, GERARD V. SMITH, ÁGNES ZSIGMOND
    Pages 77-160
  6. EVGENII KLABUNOVSKII, GERARD V. SMITH, ÁGNES ZSIGMOND
    Pages 267-274
  7. EVGENII KLABUNOVSKII, GERARD V. SMITH, ÁGNES ZSIGMOND
    Pages 275-293
  8. Back Matter
    Pages 295-303

About this book

Introduction

Heterogeneous Enantioselective Hydrogenation: Theory and Practice reviews the development of enantioselective hydrogenation reaction catalysts. The book looks at the first relatively ineffective catalysts right through to modern highly effective enantioselective catalytic systems, comparable in their efficiency to chiral metal complexes and enzymatic systems. The book begins with a summary of the first work on heterogeneous metal catalysts, which showed only the principal possibilities of enantioselective reactions. The book then elaborates on metal catalysts which have enantioselectivities close to 100%. Finally, the book describes the practical utilization of chiral catalytic systems in processes of hydrogenation. The a - and b -hydroxy carboxylic acid esters produced are precursors for manufacturing many synthones used for medicines as well as for monomers used for biodegradable polyesters, both of which have important practical applications. The book summarizes more than 800 scientific papers in the field of enantioselective catalytic hydrogenation reactions, mainly those using heterogeneous metal catalysts. It provides detailed explanations of special techniques for the preparation of effective dissymmetric catalysts which provide highly efficient catalytic systems.

This book differs from previous publications by virtue of the recommendations for the practical utilization of recently described preparations of metal catalysts.

Heterogeneous Enantioselective Hydrogenation: Theory and Practice will be an invaluable resource to catalysis researchers as well as to those utilizing the technology.

Keywords

Additiv Adsorption Asymmetric catalysis Chiral compounds Heterogeneous catalysis Hydrogenation Hydroxycarboxylic acid esters STEM

Editors and affiliations

  • EVGENII KLABUNOVSKII
    • 1
  • GERARD V. SMITH
    • 2
  • ÁGNES ZSIGMOND
    • 3
  1. 1.Laboratory of Asymmetric Catalysis. N.D. Zelinskii Institute of Organic ChemistryRussian Academy of SciencesMoscowRussian Federation
  2. 2.Southern Illinois UniversityCarbondaleU.S.A.
  3. 3.University of SzegedSzegedHungary

Bibliographic information