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Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene

  • Ruijun Hou

Part of the Springer Theses book series (Springer Theses)

About this book

Introduction

This thesis offers novel methods for catalyst and process design for the selective hydrogenation of acetylene and 1,3-butadiene. The author predicts the properties of supported Pd–Ni bimetallic catalysts using density functional theory (DFT) calculations and temperature-programmed desorption (TPD). The excellent correlation between model surfaces and supported catalysts demonstrates the feasibility of designing effective bimetallic catalysts for selective hydrogenation reactions. The author also proposes a method for designing non-precious metal catalysts to replace precious metals. She modifies the process of selective hydrogenation of acetylene by coupling the selective adsorption to the selective hydrogenation in the liquid phase, as a result of which the ethylene selectivity is greatly improved and heat transfer is greatly enhanced. Lastly, by analyzing the mechanism of liquid-phase hydrogenation, the author proposes a multi-stage slurry bed reactor for industrial applications.<

Keywords

Acetylene 1,3-butadiene Selective hydrogenation Pd-Ni bimetallic catalyst Liquid-phase hydrogenation

Authors and affiliations

  • Ruijun Hou
    • 1
  1. 1.Beijing Institute of Technology BeijingChina

Bibliographic information

  • DOI https://doi.org/10.1007/978-981-10-0773-6
  • Copyright Information Springer Science+Business Media Singapore 2017
  • Publisher Name Springer, Singapore
  • eBook Packages Chemistry and Materials Science
  • Print ISBN 978-981-10-0772-9
  • Online ISBN 978-981-10-0773-6
  • Series Print ISSN 2190-5053
  • Series Online ISSN 2190-5061
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