© 1992

Energetics of Organometallic Species

  • J. A. Martinho Simões

Part of the NATO ASI Series book series (ASIC, volume 367)

Table of contents

  1. Front Matter
    Pages i-xii
  2. Michael A. Giardello, Wayne A. King, Steven P. Nolan, Marina Porchia, Chand Sishta, Tobin J. Marks
    Pages 35-51
  3. William D. Jones, R. Martin Chin, Lingzhen Dong, Simon B. Duckett, Edward T. Hessell
    Pages 53-67
  4. James S. Chickos, Donald G. Hesse, Joel F. Liebman
    Pages 159-169
  5. Amy E. Stevens Miller, Thomas M. Miller
    Pages 253-267
  6. Lee S. Sunderlin, Robert R. Squires
    Pages 269-286
  7. P. B. Armentrout, D. E. Clemmer
    Pages 321-356

About this book


An overview of modern organometallic thermochemistry, made by some of the most active scientists in the area, is offered in this book. The contents correspond to the seventeen lectures delivered at the NATO ASI Energetics of Organometallic Species (Curia, Portugal, September 1991), plus three other invited contributions from participants of that summer school. These papers reflect a variety of research interests, and discuss results obtained with several techniques. It is therefore considered appropriate to add a few preliminary words, attempting to bring some unity out of that diversity. In the first three chapters, results obtained by classical calorimetric methods are described. Modern organometallic thermochemistry started in Manchester, with Henry Skinner, and his pioneering work is briefly surveyed in the first chapter. The historical perspective is followed by a discussion of a very actual issue: the trends of stepwise bond dissociation enthalpies. Geoff Pilcher, another Manchester thermochemist, makes, in chapter 2, a comprehensive and authoritative survey of problems found in the most classical of thermochemical techniques - combustion calorimetr- applied to organometallic compounds. Finally, results from another classical technique, reaction-solution calorimetry, are reviewed in the third chapter, by Tobin Marks and coworkers. More than anybody else, Tobin Marks has used thermochemical values to define synthetic strategies for organometallic compounds, thus indicating an application of thermochemical data of which too little use has been made so far.


Silane chemistry combustion electrochemistry metals rhodium transition metal

Editors and affiliations

  • J. A. Martinho Simões
    • 1
  1. 1.Departmento de Engenharia QuímicaInstituto Superior TécnicoLisbonPortugal

Bibliographic information