Reactive and Flexible Molecules in Liquids

  • Th. Dorfmüller

Part of the NATO ASI Series book series (ASIC, volume 291)

Table of contents

  1. Front Matter
    Pages i-x
  2. Bertrand Guillot, George Birnbaum
    Pages 1-36
  3. Giorgio J. Moro, Alberta Ferrarini, Antonino Polimeno, Pier Luigi Nordio
    Pages 107-139
  4. Dietmar Porschke
    Pages 257-268
  5. L. J. Korstanje, E. E. Van Faassen, Y. K. Levine
    Pages 285-307
  6. M. Drifford, P. J. Derian, L. Belloni
    Pages 309-325
  7. A. Bick, Th. Dorfmüller
    Pages 389-398
  8. Kathy Carpenter, Geraldine Kenney-Wallace
    Pages 407-438
  9. Back Matter
    Pages 455-460

About this book


The observable phenomena in liquids ",hich distinguishes this state of matter from other types of condensed matter can be mainly assigned to a) the configurational disorder and b) the random motion of molecules. Both, the static and the dynamic aspect of randomness are typical for the liquid state and serve as a useful guideline in the attempts to theoretically understand this state. These two basic features, however, introduce in liquid state theory a number of apparently unsurmountable technical and conceptual problems so that progress in the last decades has only been made by small steps. In order not to complicate the situation even more, the tacit assumption was made that we could neglect internal motions of the molecules and that the molecular interactions which had to be taken into account are as simple as possible. We thus became accustomed to visualize molecules in the liquid as a dense assembly of classical rigid particles interacting with a potential which basically is represented by a Lennard-Jones type relation. In the last decade, it has become obvious that with these restrictions we dis­ regard many interesting effects in those liquids which are the most important ones. We thus see a serious gap developing between the refinements of liquid state theory and the exciting experiments being carried out in many laboratories.


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Editors and affiliations

  • Th. Dorfmüller
    • 1
  1. 1.Fakultät für ChemieUniversität BielefeldBielefeldGermany

Bibliographic information

  • DOI
  • Copyright Information Springer Science+Business Media B.V. 1989
  • Publisher Name Springer, Dordrecht
  • eBook Packages Springer Book Archive
  • Print ISBN 978-94-010-6961-8
  • Online ISBN 978-94-009-1043-0
  • Series Print ISSN 1389-2185
  • Buy this book on publisher's site