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S Sulfur-Nitrogen Compounds

Part 3 Compounds with Sulfur of Oxidation Number IV

  • Authors
  • Norbert Baumann
  • Hans-Jürgen Fachmann
  • Brigitte Heibel
  • Susanne Jäger
  • Alfons Kubny
  • Editors
  • Norbert Baumann
  • Hans-Jürgen Fachmann
  • Brigitte Heibel
  • Hannelore Keller-Rudek
  • Alfons Kubny
  • Peter Kuhn

Part of the Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition book series (GMELIN, volume S / S-N / 3)

Table of contents

  1. Front Matter
    Pages N2-XVII
  2. Sulfur(IV)-Nitrogen-Element Ring Systems

    1. Norbert Baumann, Hans-Jürgen Fachmann, Brigitte Heibel, Susanne Jäger, Alfons Kubny
      Pages 1-1
    2. Norbert Baumann, Hans-Jürgen Fachmann, Brigitte Heibel, Susanne Jäger, Alfons Kubny
      Pages 2-5
    3. Norbert Baumann, Hans-Jürgen Fachmann, Brigitte Heibel, Susanne Jäger, Alfons Kubny
      Pages 6-12
    4. Norbert Baumann, Hans-Jürgen Fachmann, Brigitte Heibel, Susanne Jäger, Alfons Kubny
      Pages 13-48
    5. Norbert Baumann, Hans-Jürgen Fachmann, Brigitte Heibel, Susanne Jäger, Alfons Kubny
      Pages 49-53
    6. Norbert Baumann, Hans-Jürgen Fachmann, Brigitte Heibel, Susanne Jäger, Alfons Kubny
      Pages 54-57
    7. Norbert Baumann, Hans-Jürgen Fachmann, Brigitte Heibel, Susanne Jäger, Alfons Kubny
      Pages 58-59
    8. Norbert Baumann, Hans-Jürgen Fachmann, Brigitte Heibel, Susanne Jäger, Alfons Kubny
      Pages 60-323
  3. Back Matter
    Pages 324-327

About this book

Introduction

The present volume describes cyclic sulfur-nitrogen compounds whose ring system con­ tains one or two other types of atoms in addition to sulfur and nitrogen. At least one sulfur atom can be regarded as having oxidation number IV in one resonance structure. That means the sulfur in fact has an oxidation number higher than 11 and lower than VI. The volume continues "Sulfur-Nitrogen Compounds" Part 2, in which the binary sulfur(lV)-nitrogen ring systems are described. Compounds with the same "hetero atom" in the sulfur-nitrogen ring are arranged in groups. Within a group the compounds are arranged according to ring size, and for a given number of ring atoms, in order of decreasing S: N ratio. Neutral compounds are described before ions, and saturated compounds before unsaturated, aromatic ones. A very heterogeneous material is brought together in this volume. SN Se2 rings, which 2 strongly resemble the binary S3N2 ring, are covered. S-N-Si rings with five, six, and eight atoms, and also N-S-N-bridged eight-membered rings, are described. The S-N-P rings form a puzzling and complex part of this volume; they readily interconvert by dimerization, cleavage, and by addition and loss of NSN and NPN groups. Especially interesting is the aromatic character of 8-N-P rings.

Keywords

Atom Oxidation aromatic atoms nitrogen structure system

Bibliographic information

  • DOI https://doi.org/10.1007/978-3-662-06360-6
  • Copyright Information Springer-Verlag Berlin Heidelberg 1986
  • Publisher Name Springer, Berlin, Heidelberg
  • eBook Packages Springer Book Archive
  • Print ISBN 978-3-662-06362-0
  • Online ISBN 978-3-662-06360-6
  • Buy this book on publisher's site