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Th Thorium

Compounds with Carbon: Carbonates, Thiocyanates, Alkoxides, Carboxylates

  • Kenneth W. Bagnall
  • Karl-Christian Buschbeck
  • Cornelius Keller

Part of the Th. Thorium (System-Nr. 44) book series (GMELIN, volume T-h / A-E / C / 7)

Table of contents

  1. Front Matter
    Pages I-XIV
  2. Back Matter
    Pages 161-163

About this book

Introduction

The present volume of the Gmelin thorium series describes the solid thorium-carbon compounds with the exception of the carbides and coordination compounds of the type 4 ThAn· X B, where B is a neutral ligand. The complex equilibria of the Th + ion with C-containing complexing agents are treated in the ThD1 volume. A first look into this volume demonstrates that a very large number of ThlV complexes has 4 been prepared. This may be explained by the fact that the Th + ion is the largest tetravalent ion of the periodic table. Therefore, the preparation of complexes with, e. g. , multidentate ligands can give a well-established picture of the coordination number as a function of charge and ionic radius. However, there are very few modern and updated comprehensive treatments of such data. Many compounds described in this volume are characterized by no other means than analytical composition and IR spectra (whereby IR spectra of organic ThlV salts mostly give information only on the ligand). Besides thorium carbonate and carbonato complexes, which are relevant for the environmental behaviour of this radioactive element and some organic complexes like oxalates, which are used in the field of analytical and separation chemistry nearly all other compounds described here are practically only of scientific interest. On the other hand in order to have scientifically reliable data, a very large part of these compounds needs further investigation and characterization.

Keywords

behavior chemistry element environment information iron spectra

Authors and affiliations

  • Kenneth W. Bagnall
    • 1
  1. 1.Chemistry DepartmentUniversity of ManchesterManchesterUK

Editors and affiliations

  • Karl-Christian Buschbeck
    • 1
  • Cornelius Keller
    • 2
  1. 1.Gmelin-InstitutFrankfurt am MainGermany
  2. 2.Schule für KerntechnikKernforschungszentrum KarlsruheKarlsruheGermany

Bibliographic information

  • DOI https://doi.org/10.1007/978-3-662-06315-6
  • Copyright Information Springer-Verlag Berlin Heidelberg 1988
  • Publisher Name Springer, Berlin, Heidelberg
  • eBook Packages Springer Book Archive
  • Print ISBN 978-3-662-06317-0
  • Online ISBN 978-3-662-06315-6
  • Buy this book on publisher's site