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Metal Vapour Synthesis in Organometallic Chemistry

  • John R. Blackborow
  • Dennis Young
Book

Part of the Reactivity and Structure Concepts in Organic Chemistry book series (REACTIVITY, volume 9)

Table of contents

  1. Front Matter
    Pages I-XIII
  2. John R. Blackborow, Dennis Young
    Pages 1-11
  3. John R. Blackborow, Dennis Young
    Pages 12-45
  4. John R. Blackborow, Dennis Young
    Pages 66-178
  5. John R. Blackborow, Dennis Young
    Pages 179-189
  6. Back Matter
    Pages 191-204

About this book

Introduction

Metal Vapour Synthesis (MVS) can be defined as; "The use in synthesis of high temper­ ature gaseous species such as metal atoms by their reactions with themselves or other materials in a condensed phase. " This short book, covering the literature up to the middle of 1979, describes MVS in organic chemistry; i. e. the reactions of metal atoms with various, predominantly organic, substrates in the synthesis and reactivity studies of organic and organometallic compounds. In order to effectively describe all the underlying principles and to present a coesive picture of pertinent metal atom processes in condensed organic phases, some inorganic substrates such as rare gases, dinitrogen, dioxygen, dihalo­ gens, and inorganic halides have been included. For similar reasons, we have used, where relevent, information provided by the closely related technique of Matrix Isolation Spec­ troscopy (MIS). After an introductory chapter which gives the basis principles and includes a brief critique of the technique, the book is divided into three further chapters dealing respec­ tively with (a) experimental techniques, (b) behaviour of metal atoms in matrices, and (c) results of prep~rative experiments. While not being encyclopaedic the book describes or refers to all noteworthy areas if not in the deliberately short text in the many tables and figures.

Keywords

Alkene Metallorganische Verbindung Synthese alkyne carbon carbon dioxide isolation metals organometallic chemistry oxygen reactant spectroscopy synthesis transition metal

Authors and affiliations

  • John R. Blackborow
    • 1
  • Dennis Young
    • 2
  1. 1.Institut de ChimieUniversité Louis PasteurStrasbourg CedexFrance
  2. 2.BP Research CentreN. T. D.Sunbury-on-Thames MiddlesexGreat Britain

Bibliographic information

  • DOI https://doi.org/10.1007/978-3-642-67285-9
  • Copyright Information Springer-Verlag Berlin Heidelberg 1979
  • Publisher Name Springer, Berlin, Heidelberg
  • eBook Packages Springer Book Archive
  • Print ISBN 978-3-642-67287-3
  • Online ISBN 978-3-642-67285-9
  • Series Print ISSN 0341-2377
  • Buy this book on publisher's site