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New Discoveries on the β-Hydride Elimination

  • Thomas M. Gøgsig

Part of the Springer Theses book series (Springer Theses)

Table of contents

  1. Front Matter
    Pages i-xvii
  2. Thomas Meyer Gøgsig
    Pages 1-31
  3. Thomas Meyer Gøgsig
    Pages 33-43
  4. Thomas Meyer Gøgsig
    Pages 97-108
  5. Thomas Meyer Gøgsig
    Pages 109-109
  6. Back Matter
    Pages 111-122

About this book

Introduction

The work presented in Thomas M. Gøgsig's thesis deals with the discovery of new metal-catalyzed transformations ranging from Kumada-, Heck- and Suzuki-type reactions. The thesis starts with a formidable introduction to Pd-catalyzed cross-coupling reactions. New results have been obtained on:
(i) Pd-catalyzed 1,2-migration reactions,
(ii) Pd-catalyzed Heck reactions employing heteroaromatic tosylates,
(iii) Ni-catalyzed Heck reactions, and
(iv) Pd-catalyzed carbonylative Heck reactions.
Metal-catalyzed cross-coupling reactions are today a highly competititve field (the 2010 Nobel Prize in Chemistry was awarded "for palladium-catalyzed cross couplings in organic synthesis", the 2001 and 2005 Nobel Prizes in closely related fields). Thomas M. Gøgsig obtained new results in his thesis that will help to improve the outcome of catalytic processes and improve their scope. The results will thus become key references for tomorrow's new applications. All chapters include insightful discussions and in-depth descriptions of the key principles of these new discoveries.

Keywords

Carbonylative Heck Reaction Cross-coupling Reactions Heck Reaction Kumada Coupling Negishi Coupling Ni-catalyzed Heck Reaction Pd 1,2-migration Pd-catalysis Suzuki Coupling β-Hydride Elimination

Authors and affiliations

  • Thomas M. Gøgsig
    • 1
  1. 1.Aarhus CDenmark

Bibliographic information

  • DOI https://doi.org/10.1007/978-3-642-32099-6
  • Copyright Information Springer-Verlag Berlin Heidelberg 2012
  • Publisher Name Springer, Berlin, Heidelberg
  • eBook Packages Chemistry and Materials Science
  • Print ISBN 978-3-642-32098-9
  • Online ISBN 978-3-642-32099-6
  • Series Print ISSN 2190-5053
  • Series Online ISSN 2190-5061
  • Buy this book on publisher's site