Electrochemistry of N4 Macrocyclic Metal Complexes

Volume 1: Energy

  • Jose H. Zagal
  • Fethi Bedioui

Table of contents

  1. Front Matter
    Pages i-xv
  2. Kexi Liu, Yinkai Lei, Rongrong Chen, Guofeng Wang
    Pages 1-39
  3. Hoon Chung, Gang Wu, Drew Higgins, Pouyan Zamani, Zhongwei Chen, Piotr Zelenay
    Pages 41-68
  4. Alessandro H. A. Monteverde Videla, Luigi Osmieri, Stefania Specchia
    Pages 69-101
  5. Sebastián Miranda-Rojas, Alvaro Muñoz-Castro, Ramiro Arratia-Pérez, Fernando Mendizábal
    Pages 143-170
  6. Ievgen Obraztsov, Wlodzimierz Kutner, Francis D’Souza
    Pages 171-262
  7. Back Matter
    Pages 315-316

About this book


This new edition describes the state of the art regarding molecular catalysts such as MN4 metal complexes, like porphyrins and phthalocyanines. This volume focuses on the particular case of the electrocatalysis of the reduction of O2 for practical applications in fuel cells and air batteries. Indeed, active and stable materials have been developed in the last 5 years where MN4 catalytic systems can be obtained by the pyrolysis of starting materials that do not necessarily involve MN4 complexes. These latter systems constitute a new class of stable and highly active non-precious metal catalysts for ORR that can replace expensive Platinum containing electrodes. The book also offers future projections and points out new fields of research and development of these non-precious metal catalysts.


Electrocatalysis MNx Catalysts Macrocyclic Metal Complexes Metallophthalocyanines Metalloporphyrins Oxygen Reduction Reaction Photoelectrochemistry Solar Cells

Editors and affiliations

  • Jose H. Zagal
    • 1
  • Fethi Bedioui
    • 2
  1. 1.Universidad de Santiago de ChileSantiagoChile
  2. 2.CNRS-Chimie ParisTechParis CX 05France

Bibliographic information