Sustaining Life on Planet Earth: Metalloenzymes Mastering Dioxygen and Other Chewy Gases

  • Peter M. H Kroneck
  • Martha E. Sosa Torres

Part of the Metal Ions in Life Sciences book series (MILS, volume 15)

Table of contents

  1. Front Matter
    Pages i-xxxv
  2. Martha E. Sosa Torres, Juan P. Saucedo-Vázquez, Peter M. H. Kroneck
    Pages 1-12
  3. Junko Yano, Jan Kern, Vittal K. Yachandra, Håkan Nilsson, Sergey Koroidov, Johannes Messinger
    Pages 13-43
  4. Jennifer L. DuBois, Sunil Ojha
    Pages 45-87
  5. Shinya Yoshikawa, Atsuhiro Shimada, Kyoko Shinzawa-Itoh
    Pages 89-130
  6. Gereon M. Yee, William B. Tolman
    Pages 131-204
  7. Matthew H. Sazinsky, Stephen J. Lippard
    Pages 205-256
  8. Back Matter
    Pages 315-329

About this book


MILS-15 provides an up-to-date review of the metalloenzymes involved in the activation, production, and conversion of molecular oxygen as well as the functionalization of the chemically inert gases methane and ammonia. Found either in aerobes (humans, animals, plants, microorganisms) or in anaerobes (so-called “impossible bacteria”) these enzymes employ preferentially iron and copper at their active sites, in order to conserve energy by redox-driven proton pumps, to convert methane to methanol, or ammonia to hydroxylamine or other compounds. When it comes to the light-driven production of molecular oxygen, the tetranuclear manganese cluster of photosystem II must be regarded as the key player. However, dioxygen can also be produced in the dark, by heme iron-dependent dismutation of oxyanions. Metalloenzymes Mastering Dioxygen and Other Chewy Gases is a vibrant research area based mainly on structural and microbial biology, inorganic biological chemistry, and environmental biochemistry. All this is covered in an authoritative manner in 7 stimulating chapters, written by 21 internationally recognized experts, and supported by nearly 1100 references, informative tables, and over 140 illustrations (many in color). MILS-15 provides excellent information for teaching; it is also closely related to MILS-14, The Metal-Driven Biogeochemistry of Gaseous Compounds in the Environment

Peter M. H. Kroneck is a bioinorganic chemist who is exploring the role of transition metals in biology, with a focus on functional and structural aspects of microbial iron, copper, and molybdenum enzymes and their impact on the biogeochemical cycles of nitrogen and sulfur.

Martha E. Sosa Torres is an inorganic chemist, with special interests in magnetic properties of newly synthesized transition metal complexes and their reactivity towards molecular oxygen, applying kinetic, electrochemical, and spectroscopic techniques.


Chewy Gases Dioxygen Metal Metalloenzymes Sustaining Life

Editors and affiliations

  • Peter M. H Kroneck
    • 1
  • Martha E. Sosa Torres
    • 2
  1. 1.Fachbereich BiologieUniversita¨t KonstanzKonstanzGermany
  2. 2.Facultad de Química Departamento de Química Inorganica y NucUniversidad Nacional Autónoma de MéxicoCiudad de MéxicoMexico

Bibliographic information

  • DOI
  • Copyright Information Springer International Publishing Switzerland 2015
  • Publisher Name Springer, Cham
  • eBook Packages Biomedical and Life Sciences
  • Print ISBN 978-3-319-12414-8
  • Online ISBN 978-3-319-12415-5
  • Series Print ISSN 1559-0836
  • Series Online ISSN 1868-0402
  • Buy this book on publisher's site