Book Volume 197 1990

Sulfur-Centered Reactive Intermediates in Chemistry and Biology

Editors:

ISBN: 978-1-4684-5876-3 (Print) 978-1-4684-5874-9 (Online)

Table of contents (39 chapters)

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  1. Front Matter

    Pages i-xi

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    Chapter

    Pages 1-6

    Force-Field and Molecular Orbital Calculations in Organosulfur Chemistry

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    Chapter

    Pages 7-12

    Electronic Transitions in Sulfur-Centered Radicals by Means of MSXα Calculations

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    Chapter

    Pages 13-18

    The Electronic Properties of Sulfur-Containing Substituents and Molecules: An ab initio Study

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    Chapter

    Pages 19-30

    Reactivity of Sulfur-Centered Nucleophiles Towards Dia- and Paramagnetic Reagents. The Frontier Orbitals Approach

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    Chapter

    Pages 31-36

    Alkanethiylperoxyl Radicals

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    Chapter

    Pages 37-52

    Thermochemistry of Sulfur-Centered Intermediates

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    Chapter

    Pages 53-67

    Experimental Procedures in Electrolysis

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    Chapter

    Pages 69-82

    Single Electron Transfer in Aliphatic Nucleophilic Substitution

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    Chapter

    Pages 83-92

    Electrochemistry as a Tool for the Study of Reactive Intermediates

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    Chapter

    Pages 93-102

    Electrochemical Reduction of Some Sulfur Compounds

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    Chapter

    Pages 103-120

    Photocatalytic Formation of Sulfur-Centered Radicals by One-Electron Redox Processes on Semiconductor Surfaces

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    Chapter

    Pages 121-134

    Applications of Pulse Radiolysis for the Study of Short-Lived Sulphur Species

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    Chapter

    Pages 135-154

    Structure and Reaction Mechanisms in Sulphur-Radical Chemistry Revealed by E.S.R. Spectroscopy

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    Chapter

    Pages 155-172

    Sulfur-Centered Three-Electron Bonded Radical Species

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    Chapter

    Pages 173-183

    Radical Cations of Conjugated Cyclic Disulfides

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    Chapter

    Pages 185-192

    Beam Experiments as a Means for the Generation of Elusive Sulfur-Containing Molecules

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    Chapter

    Pages 193-196

    Dications from Cyclic Polythioethers

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    Chapter

    Pages 197-211

    Sulfenylium Cation Carriers in Chemistry and Biochemistry

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    Chapter

    Pages 213-226

    Neighboring Group Participation: General Principles and Application to Sulfur-Centered Reactive Species

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    Chapter

    Pages 227-238

    Design, Synthesis, and Conformational Analysis of Compounds Tailored for the Study of Sulfur-Centered Reactive Intermediates

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