Guidelines for Mastering the Properties of Molecular Sieves

Relationship between the Physicochemical Properties of Zeolitic Systems and Their Low Dimensionality

  • Denise Barthomeuf
  • Eric G. Derouane
  • Wolfgang Hölderich

Part of the NATO ASI Series book series (NSSB, volume 221)

Table of contents

  1. Front Matter
    Pages i-xi
  2. Orientation of Chemical Properties by Direct Synthesis of Molecular Sieves

    1. Machteld Mertens, Johan A. Martens, Piet J. Grobet, Peter A. Jacobs
      Pages 1-52
    2. François Fajula
      Pages 53-67
    3. J. L. Guth, P. Caullet, A. Seive, J. Patarin, F. Delprato
      Pages 69-85
    4. Q. Chen, J. B. Nagy, J. Fraissard, J. El Hage-Al Asswad, Z. Gabelica, E. G. Derouane et al.
      Pages 87-93
  3. Characterisation of Structural and Physicochemical Properties of Zeolitic Systems

    1. D. E. W. Vaughan, M. M. J. Treacy, J. M. Newsam
      Pages 99-120
    2. Alberto Alberti, Glauco Gottardi, Tiziana Lai
      Pages 145-155
    3. H. G. Karge, V. Mavrodinova, Z. Zheng, H. K. Beyer
      Pages 157-168
  4. Static and Dynamic Parameters in Adsorption and Catalysis in Zeolites

    1. Hans T. Lechert, Wolf D. Basler, Mendong Jia
      Pages 183-192
    2. J. B. Moffat, G. B. McGarvey, J. B. McMonagle, V. Nayak, H. Nishi
      Pages 193-200
  5. Localized and Overall Properties Related to the Nature and Structural Organization of the Framework Atoms

  6. Orientation of the Path of Reactions (Catalysis, Adsorption) By Chemical or other Geometric or Non Geometric Effects

About this book

Introduction

Low dimensionality is a multifarious concept which applies to very diversified materials. Thus, examples of low-dimensional systems are structures with one or several layers, single lines or patterns of lines, and small clusters isolated or dispersed in solid systems. Such low­ dimensional features can be produced in a wide variety of materials systems with a broad spectrum of scientific and practical interests. These features, in turn, induce specific properties and, particularly, specific transport properties. In the case of zeolites, low dimensionality appears in the network of small-diameter pores of molecular size, extending in one, two or three di­ mensions, that these solids exhibit as a characteristic feature and which explains the term of "molecular sieves" currently used to name these ma­ terials. Indeed, a large number of industrial processes for separation of gases and liquids, and for catalysis are based upon the use of this low­ dimensional feature in zeolites. For instance, zeolites constitute the first class of catalysts employed allover the world. Because of the peculiarity and flexibility of their structure (and composition), zeolites can be adapted to suit many specific and diversified applications. For this reason, zeolites are presently the object of a large and fast-growing interest among chemists and chemical engineers.

Keywords

Atom NMR Sorption Substitution adsorption catalysis catalyst cluster molecule platinum structure

Editors and affiliations

  • Denise Barthomeuf
    • 1
  • Eric G. Derouane
    • 2
  • Wolfgang Hölderich
    • 3
  1. 1.Université Paris VIParisFrance
  2. 2.Université Notre Dame de la PaixNamurBelgium
  3. 3.BASFLudwigshafenFederal Republic of Germany

Bibliographic information

  • DOI https://doi.org/10.1007/978-1-4684-5787-2
  • Copyright Information Springer-Verlag US 1990
  • Publisher Name Springer, Boston, MA
  • eBook Packages Springer Book Archive
  • Print ISBN 978-1-4684-5789-6
  • Online ISBN 978-1-4684-5787-2
  • Series Print ISSN 0258-1221
  • About this book