Advertisement

The Jahn-Teller Effect and Vibronic Interactions in Modern Chemistry

  • Isaak Borisovich Bersuker

Part of the Modern Inorganic Chemistry book series (MGAM)

Table of contents

  1. Front Matter
    Pages i-xiv
  2. Isaak Borisovich Bersuker
    Pages 1-6
  3. Isaak Borisovich Bersuker
    Pages 7-39
  4. Isaak Borisovich Bersuker
    Pages 41-72
  5. Isaak Borisovich Bersuker
    Pages 73-102
  6. Isaak Borisovich Bersuker
    Pages 103-175
  7. Isaak Borisovich Bersuker
    Pages 177-249
  8. Isaak Borisovich Bersuker
    Pages 251-290
  9. Back Matter
    Pages 291-319

About this book

Introduction

The first half of the title of this book may delude the uninitiated reader. The term '"Jahn-Teller effect," taken literally, refers to a special effect inherent in particular molecular systems. Actually, this term implies a new approach to the general problem of correlations between the structure and properties of any molecular polyatomic system, including solids. Just such a new approach, or concept (in some sense, a new outlook or even a new way of thinking), which leads not to one special effect but to a series of different effects and laws, is embodied in the many ( ~ 4000) studies devoted to the investigation and application of the Jahn-Teller effect. The term "vibronic interactions" seems to be most appropriate to the new concept, and this explains the origin of the second half of the title. The primary objective of this book is to present a systematic develop­ ment of the concept of vibronic interactions and its applications, and to illustrate its possibilities and significance in modern chemistry. In the first three chapters (covering about one-third of the book) the theoretical background of the vibronic concept and Jahn-Teller effect is given. The basic ideas are illustrated fully, although a comprehensive presentation of the theory with all related mathematical deductions is beyond the scope of this book. In the last three chapters the applications of theory to spectro­ scopy, stereochemistry and crystal chemistry, reactivity, and catalysis, are illustrated by a series of effects and laws.

Keywords

Atom catalysis chemical reaction chemistry crystal spectroscopy stereochemistry structure system the origin

Authors and affiliations

  • Isaak Borisovich Bersuker
    • 1
  1. 1.Institute of ChemistryMoldavian Academy of SciencesKishinevUSSR

Bibliographic information

  • DOI https://doi.org/10.1007/978-1-4613-2653-3
  • Copyright Information Springer-Verlag US 1984
  • Publisher Name Springer, Boston, MA
  • eBook Packages Springer Book Archive
  • Print ISBN 978-1-4612-9654-6
  • Online ISBN 978-1-4613-2653-3
  • Series Print ISSN 0924-2155
  • Buy this book on publisher's site