Catalytic Synthesis of Alkene-Carbon Monoxide Copolymers and Cooligomers

  • Ayusman Sen

Part of the Catalysis by Metal Complexes book series (CMCO, volume 27)

Table of contents

  1. Front Matter
    Pages i-x
  2. Ayusman Sen
    Pages 1-7
  3. David J. Cole-Hamilton, Ruth A. M. Robertson
    Pages 37-86
  4. W. P. Mul, A. W. van der Made, A. A. Smaardijk, E. Drent
    Pages 87-140
  5. Piet W. N. M. van Leeuwen
    Pages 141-188
  6. Giambattista Consiglio, Barbara Milani
    Pages 189-215
  7. Ayusman Sen
    Pages 237-263
  8. Peter Margl, Artur Michalak, Tom Ziegler
    Pages 265-307
  9. Back Matter
    Pages 309-325

About this book

Introduction

217 2. COPOLYMERIZATION OF PROPENE OR HIGHER I-ALKENES WITH 218 CARBON MONOXIDE 2. 1. Ligands and polymerization conditions 218 2. 2. Spiroketal formation 221 2. 3. Enantioselectivity 222 2. 4. Higher I-Alkenes 226 3. COPOLYMERIZATION OF STYRENE OR ITS DERIVATIVES WITH 226 CARBON MONOXIDE 4. COPOLYMERIZATION OF OTHER OLEANS WITH CARBON MONOXIDE 230 5. ASYMMETRIC TERPOLYMERIZATION OF MORE THAN Two KINDS OF 232 OLEFINS WITH CARBON MONOXIDE 6. POLYKETONE CONFORMATION 233 7. CONCLUSION 234 Chapter 8. Chain Propagation Mechanisms 237 Ayusman Sen 1. INTRODUCTION 237 2. PALLADIUM (II) BASED SYSTEMS 238 3. NICKEL (II) BASED SYSTEMS 256 4. RHODIUM (I) BASED SYSTEMS 257 5. CONCLUSION 261 Chapter 9. Theoretical Studies on Copolymerization of Polar Monomers 265 Peter Margl, Artur Michalak, and Tom Ziegler 1. INTRODUCTION 265 2. COPOLYMERIZATION OF CARBON MONOXIDE WITH ETHYLENE 267 2. 1. Experimental and calculated rates for the insertion processes for 267 copolymerization catalysed by Pd(II) systems. 2. 2. A more detailed look at the productive and unproductive cycles 270 in copolymerization catalysed by Pd(II) complexes. 2. 2. 1. The productive cycle 270 2. 2. 2. C2H4 misinsertion into an ethylene terminated polyketone 275 chain 2. 3. Experimental and calculated rates for the insertion processes for 277 alternating copolymerization catalyzed by Ni(II) systems 3. COPOLYMERIZATION OF OLEFINS WITH POLAR MONOMERS OTHER 280 THAN CO 3. 1. Preferred binding mode of oxygen containing monomers 282 3. 2. Preferred binding mode of nitrogen containing monomers 285 3. 3.

Keywords

Alkene Ethen Olefin Organometallic chemistry Propen catalysis chemistry polymer

Editors and affiliations

  • Ayusman Sen
    • 1
  1. 1.Department of ChemistryThe Pennsylvania State UniversityUSA

Bibliographic information

  • DOI https://doi.org/10.1007/978-1-4419-9266-6
  • Copyright Information Kluwer Academic Publishers 2003
  • Publisher Name Springer, Boston, MA
  • eBook Packages Springer Book Archive
  • Print ISBN 978-1-4613-4866-5
  • Online ISBN 978-1-4419-9266-6
  • Series Print ISSN 0920-4652
  • About this book