Atmospheric Ammonia

Detecting emission changes and environmental impacts

  • Mark A. Sutton
  • Stefan Reis
  • Samantha M.H. Baker

Table of contents

  1. Front Matter
    Pages i-xxiii
  2. Ammonia Critical Thresholds

    1. Mark A. Sutton
      Pages 1-11
    2. J. Neil Cape, Ludger J. van der Eerden, Lucy J. Sheppard, Ian D. Leith, Mark A. Sutton
      Pages 15-40
    3. Lucy J. Sheppard, Ian D. Leith, Alan Crossley, Netty van Dijk, J. Neil Cape, David Fowler et al.
      Pages 49-58
    4. Carole E.R. Pitcairn, Ian D. Leith, Netty van Dijk, Lucy J. Sheppard, Mark A. Sutton, David Fowler
      Pages 59-69
    5. Mark A. Sutton, Pat A. Wolseley, Ian D. Leith, Netty van Dijk, Y. Sim Tang, P.W. James et al.
      Pages 71-86
    6. Mark A. Sutton, Addo van Pul, Ferd Sauter, Y. Sim Tang, Laszlo Horvath
      Pages 93-99
    7. Patricia A. Wolseley, Ian D. Leith, Netty van Dijk, Mark A. Sutton
      Pages 101-108
    8. Pedro Pinho, Cristina Branquinho, Cristina Cruz, Y. Sim Tang, Teresa Dias, Ana Paula Rosa et al.
      Pages 109-119
  3. Temporal Trends in Atmospheric Ammonia

    1. Albert Bleeker, Mark A. Sutton, Beat Acherman, Ana Alebic-Juretic, Viney P. Aneja, Thomas Ellermann et al.
      Pages 123-180
    2. Y. Sim Tang, Ulrike Dragosits, Netty van Dijk, Linda Love, Ivan Simmons, Mark A. Sutton
      Pages 187-194
    3. J. Webb, Brigitte Eurich-Menden, Ulrich Dämmgen, Francesco Agostini
      Pages 195-202
  4. Analysis of Ammonia Hotspots

    1. Benjamin Loubet, Willem A. H. Asman, Mark R. Theobald, Ole Hertel, Y. Sim Tang, Paul Robin et al.
      Pages 205-267
    2. Ian D. Leith, Netty van Dijk, Carole E. R. Pitcairn, Lucy J. Sheppard, Mark A. Sutton
      Pages 269-279
    3. Netty van Dijk, Ian D. Leith, Carole E. R. Pitcairn, Mark A. Sutton
      Pages 281-289
    4. Ulrike Dragosits, Mark R. Theobald, Chris J. Place, Helen M. ApSimon, Mark A. Sutton
      Pages 291-298
  5. Regional Modelling of Atmospheric Ammonia

    1. Addo van Pul, Ole Hertel, Camilla Geels, Anthony J. Dore, Massimo Vieno, Hans A. van Jaarsveld et al.
      Pages 301-358
    2. Maciej Kryza, Anthony J. Dore, Marek Błás, Mieczysław Sobik
      Pages 359-366
    3. Massimo Vieno, Anthony J. Dore, Peter Wind, Chiara Di Marco, Eiko Nemitz, Gavin Phillips et al.
      Pages 367-372
  6. Conclusions and Outlook

    1. John Neil Cape, Ludger van der Eerden, Andreas Fangmeier, John Ayres, Simon Bareham, Roland Bobbink et al.
      Pages 375-382
    2. Jan Willem Erisman, Albert Bleeker, Albrecht Neftel, Viney Aneja, Nick Hutchings, Liam Kinsella et al.
      Pages 383-390
    3. Pierre Cellier, Mark R. Theobald, Willem Asman, William Bealey, Shabtai Bittman, Ulrike Dragosits et al.
      Pages 391-407
    4. Addo van Pul, Stefan Reis, Tony Dore, Liu Xuejun, Fagerli Hilde, Camilla Geels et al.
      Pages 409-421
    5. J. Webb, J. Nicholas Hutchings, Shabtai Bittman, Samantha M.H. Baker, Reidy Beat, Caroline Raes et al.
      Pages 423-431
    6. Till Spranger, Zbigniew Klimont, Michel Sponar, Caroline Raes, Samantha M.H. Baker, Mark A. Sutton et al.
      Pages 433-443
    7. Mark A. Sutton, Stefan Reis, Samantha M.H. Baker
      Pages 445-454
  7. Back Matter
    Pages 455-464

About this book


Atmospheric ammonia is increasingly being recognized as a pollutant of key environmental concern. Ammonia contributes to several environmental problems, including direct toxic effects on vegetation, atmospheric nitrogen deposition, leading to the eutrophication and acidification of sensitive ecosystem, and to the formation of secondary particulate matter in the atmosphere, with effects on human health, atmospheric visibility and global radiative balance. Ammonia emissions are increasing rapidly in many parts of the world, so that these environmental concerns are expected to grow in future. In Europe, efforts are currently being made to reduce ammonia emissions, alongside reductions in other air pollutants, notably sulphur dioxide and nitrogen oxides. However, reducing ammonia emissions has proved uncertain and challenging, with only modest regional reductions achieved to date. As the emissions of sulphur dioxide and nitrogen oxides are reduced, ammonia is therefore increasingly dominating the air pollution climate of Europe and the consequent environmental impacts.

It was in this context that the leading international experts met in Edinburgh in December 2006 under the auspices of the UN-ECE Convention on Long Range Transboundary Air Pollution to review the current state of the science of ammonia in the atmosphere. Specifically, the international workshop was a joint effort between several bodies of the Convention: the Ammonia Expert Group, the Working Group on Effects and the Task Force on Measurement and Modelling, together with the COST 729 and the NitroEurope Integrated Project. This book reports the underpinning information in the form of several major reviews, combined with supporting chapters on recent research results, to provide an up-to-date scientific synthesis in relation to four key themes:

  1. Re-evaluation of the critical thresholds for ammonia effects on sensitive plants and habitats
  2. Review of approaches for downscaling transboundary assessments to deal with ammonia hotspots in relation to operational modelling and monitoring
  3. Review of regional scale atmospheric transport and chemistry models in relation to their formulation and results for ammonia.

Each of these themes is of fundamental to the quantification of ammonia impacts in the environment and the assessment of possible abatement measures. The reviews highlight how the critical threshold for ammonia concentrations – the "critical level" – has been overestimated in the past, and the book explains the new estimates. Monitoring of atmospheric concentrations and deposition is the only independent way to verify the success of emission abatement policies. The analysis shows how it has been a major challenge to verify the reported reductions in emissions, but that several new datasets now support expected trends in emission reduction, even though total emissions may still be underestimated. Atmospheric models are central to the assessment at both regional and landscape scales. The dynamics within ‘ammonia hotspots’ are particularly important to understand both the fate of ammonia export from source regions and to assess the local environmental impacts. Similarly, modeling at regional scales forms the basis for transboundary assessment of ammonia emissions and deposition. At both scales, the present assessment shows that quantification of ammonia dry deposition remains a key uncertainty. Cross-cutting analyses in the review addressed the reliability of ammonia emissions data and abatement efficiencies, as well as the agricultural and environmental policy context, considering how scientific understanding can help address the challenges to reduce the adverse effects of ammonia in the environment.

This book will be valuable to all those interested in the behaviour of ammonia in the environment, as it explains the current state of knowledge, reports new critical level values, and describes the main scientific uncertainties.


Air pollution Biodiversity Hotspot emissions environment pollution vegetation

Editors and affiliations

  • Mark A. Sutton
    • 1
  • Stefan Reis
    • 1
  • Samantha M.H. Baker
    • 2
  1. 1.Centre for Ecology & Hydrology, (CEH)UK
  2. 2.Department for Environment Food and Rural Affairs (Defra)UK

Bibliographic information