Abstract
We have synthesized functionalized graphene by using direct dispersion of graphite flakes with single-stranded DNA in distilled water. The synthesized graphene-DNA complexes were investigated by using Raman spectroscopy, atomic force microscopy (AFM), transmission electron microscopy (TEM), and time-of-flight secondary-ion mass spectroscopy (TOF-SIMS). Raman spectra exhibited typical G-band and 2D-band signatures of graphene at ~1590 cm−1 and ~2700 cm−1, respectively. TOF-SIMS result showed that the graphene layers were successfully functionalized with singlestranded DNA. Mono-layer and few-layer graphene were identified by measuring the layer thickness by using AFM and by analyzing the electron diffraction patterns from TEM measurements.
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K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Duobonos, I. V. Grigorieva and A. A. Firsov, Science 306, 666 (2004).
A. K. Geim and K. S. Novoselov, Nat. Mater. 6, 183 (2007).
A. K. Geim, Science 324, 1530 (2009).
K. S. Novoselov, Rev. Mod. Phys. 83, 837 (2011).
J. Wu, M. Agrawal, H. A. Becerril, Z. Bao, Z. Liu, Y. Chen and P. Peumans, ACS Nano 4, 43 (2010).
T. Han, Y. Lee, M. Choi, S. Woo, S. Bae, B. H. Hong, J. Ahn and T. Lee, Nat. Photonics 6, 105 (2012).
Y. Wang, Z. Shi, Y. Huang, Y. Ma, C. Wang, M. Chen and Y. Chen, J. Phys. Chem. C 113, 13103 (2009).
Y. Zhu et al., Science 332, 1537 (2011).
A. J. Prtil, J. L. Vickery, T. B. Scott and S. Mann, Adv. Mater. 21, 3159 (2009).
Y. Wang, Z. Li, J. Wang, J. Li and Y. Lin, Trends Biotechnol. 29, 205 (2011).
M. Zhang, B. Yin, W. Tan and B. Ye, Biosens. Bioelectron. 26, 3260 (2011).
T. Premkumar and K. E. Geckeler, Prog. Polym. Sci. 37, 515 (2012).
K. Kostarelos and K. S. Novoselov, Science 344, 261 (2014).
S. He et al., Adv. Funct. Mater. 20, 453 (2010).
W. Lv, M. Guo, M. Liang, F. Jin, L. Cui, L Zhi and Q. Yang, J. Mater. Chem. 20, 6668 (2010).
L. Tang, Y. Wang, Y. Liu and J. Li, ACS Nano 5, 3817 (2011).
W. D. Pu, L. Zhang and C. Z. Huang, Anal. Methods 4, 1662 (2012).
Y. Hernandez et al., Nat. Nanotechnol. 3, 563 (2008).
C. Lee, G. M. Harbers, D. W. Grainger, L. J. Gamble and D. G. Castner, J. Am. Chem. Soc. 129, 9429 (2007).
A. C. Ferrari et al., Phys. Rev. Lett. 97, 187401 (2006).
Y. Sim, J. Park, Y. J. Kim, M. Seong and S. Hong, J. Korean Phys. Soc. 58, 938 (2011).
D. Bischoff, J. Guttinger, S. Droscher, T. Ihn, K. Ensslin and C. Stampfer, J. Appl. Phys. 109, 073710 (2011).
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Sim, Y., Seong, MJ. Functionalization of graphene with single-stranded DNA. Journal of the Korean Physical Society 67, 1952–1956 (2015). https://doi.org/10.3938/jkps.67.1952
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DOI: https://doi.org/10.3938/jkps.67.1952