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Effect of donor weight in a P3HT:PCBM blended layer on the characteristics of a polymer photovoltaic cell

Journal of the Korean Physical Society volume 66, pages 1720–1725 (2015)Cite this article

Abstract

The dependence of the weight of the electron-donating material, poly(3-hexylthiophene-2,5-diyl) (P3HT), and electron-accepting material, [6,6]-phenyl C61 butyric acid methyl ester (PCBM), on the photovoltaic characteristics of a polymer photovoltaic (PV) cell was investigated. A P3HT weight varied, the dependence of the power-conversion efficiency (PCE) on the weight of P3HT was similar to that of the short-circuit current (J SC ), but not that of to the open-circuit voltage (V OC ) and the fill factor (FF). That trend is associated with the fact that the absorbance of light and the carrier transport resistance strongly depend on the weight P3HT. In particular, the PCE and J SC of a cell with a specific weight ratio of P3HT to PCBM, i.e., P3HT (0.0266 g):PCBM (0.0133 g), were maximized, 3.48% and 8.43 mA/cm2, which were improvements of 676 and 532%, respectively. The weight P3HT in the P3HT:PCBM blended layer strongly influenced the J SC of the polymer PV cell.

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References

  1. C. J. Brabec, N. S. Sariciftci and J. C. Hummelen, Adv. Funct. Mater. 11, 15 (2001).

  2. S. R. Forrest, Nature 428, 911 (2004).

    Article  ADS  Google Scholar 

  3. C. Winder and N. S. Sariciftci, J. Mater. Chem. 14, 1077 (2004).

    Article  Google Scholar 

  4. W. Y. Wong, X. Z. Wang, Z. He, A. B. Djurisic, C. T. Yip, K. Y. Cheung, H. Wang, C. S. K. Mak and W. K. Chan, Nat. Mater. 6, 521 (2007).

    Article  ADS  Google Scholar 

  5. W. Y. Wong et al., J. Am. Chem. Soc. 129, 14372 (2007).

    Article  Google Scholar 

  6. F. C. Krebs, H. Spanggard, M. Biancardo and J. Alstrup, Mater. Sci. Eng. B 138, 106 (2007).

    Article  Google Scholar 

  7. C. Lungenschmied, G. Dennler, H. Neugebauer, S. N. Sariciftci, M. Glatthaar, T. Meyer and A. Meyer, Sol. Energy Mater. Sol. Cells 91, 379 (2007).

    Article  Google Scholar 

  8. S. E. Shaheen, R. Radspinner, N. Peyghambarian and G. E. Jabbour, Appl. Phys. Lett. 79, 2996 (2001).

    Article  ADS  Google Scholar 

  9. F. C. Krebs, J. Alstrup, H. Spanggaard, K. Larsen and E. Kold, Sol. Energy Mater. Sol. Cells 83, 293 (2004).

    Article  Google Scholar 

  10. G. Dennler, C. Lungenschmied, H. Neugebauer, N. S. Sariciftci and A. Labouret, J. Mater. Res. 20, 3224 (2005).

    Article  ADS  Google Scholar 

  11. S. A. Gevorgyan and F. C. Krebs, Chem. Mater. 20, 4386 (2008).

    Article  Google Scholar 

  12. G. Li, Y. Yang, R. A. B. Devine and C. Mayberry, Nanotechnology 19, 424014 (2008).

    Article  ADS  Google Scholar 

  13. J. A. Hauch, P. Schilinsky, S. A. Choulis, R. Childers, M. Biele and C. J. Brabec, Sol. Energy Mater. Sol. Cells 92, 727 (2008).

    Article  Google Scholar 

  14. X. Yang, J. Loos, S. C. Veenstra, W. J. H. Verhees, M. M. Wienk, J. M. Kroon, M. A. J. Michels and R. A. J. Janssen, NanoLett. 5, 579 (2005).

    Article  ADS  Google Scholar 

  15. E. A. Katz, S. Gevorgyan, M. S. Orynbayev and F. C. Krebs, Eur. Phys. J. Appl. Phys. 36, 307 (2006).

    Article  ADS  Google Scholar 

  16. M. Jorgensen, K. Norrman and F. C. Krebs, Sol. Energy Mater. Sol. Cells 92, 686 (2008).

    Article  Google Scholar 

  17. P. Vivo, J. Jukola, M. Ojala, V. Chukharev and H. Lemmetyinen, Sol. Energy Mater. Sol. Cells 92, 1416 (2008).

    Article  Google Scholar 

  18. F. C. Krebs, Y. Thomann, R. Thomann and J. W. Andreasen, Nanotrechnology 19, 424023 (2008).

    Google Scholar 

  19. C. Zhang, S. W. Tong, C. Jiang, E. T. Kang, D. S. H. Chan and C. Zhu, Appl. Phys. Lett. 92, 083310 (2008).

    Article  ADS  Google Scholar 

  20. C. Zhang, S. W. Tong, C. Jiang, E. T. Kang, D. S. H. Chan and C. Zhu, Appl. Phys. Lett. 93, 043307 (2008).

    Article  ADS  Google Scholar 

  21. J. C. Lee, W. Lee, S. H. Han, T. G. Kim and Y. M. Sung, Electrochemistry Commun. 11, 231 (2009).

    Article  Google Scholar 

  22. J. Y. Kim, K. Lee, N. E. Coates, D. Moses, T. Nguyen, M. Dante and A. J. Heeger, Science 13, 222 (2007).

    Article  ADS  Google Scholar 

  23. Y. Divayana, B. J. Chen, X. W. Sun and K. S. Sarma, Appl. Phys. Lett. 88, 083508 (2006).

    Article  ADS  Google Scholar 

  24. M. Vogel, S. Doka, C. Breyer, M. C. L. Steiner and K. Fostiropoulos, Appl. Phys. Lett. 89, 163501 (2006).

    Article  ADS  Google Scholar 

  25. A. K. Pandey, P. E. Shaw, D. W. Samuel and J. M. Nunzi, Appl. Phys. Lett. 94, 103303 (2009).

    Article  ADS  Google Scholar 

  26. S. H. Lee, D. H. Kim, J. H. Kim, T. H. Shim and J. G. Park, Synth. Met. 159, 1705 (2009).

    Article  Google Scholar 

  27. M. Strange, D. Plackett, M. Kaasgaard and F. C. Krebs, Sol. Energy Mater. Sol. Cells 92, 805 (2008).

    Article  Google Scholar 

  28. R. Valaski, C. D. Canestraro, L. Micaroni, R. M. Q. Mello and L. S. Roman, Sol. Energy Mater. Sol. Cells 91, 684 (2007).

    Article  Google Scholar 

  29. T. Aernouts, P. Vanlaeke, W. Geens, J. Poortmans, P. Heremans, S. Borghsa, R. Mertensa, R. Andriessen and L. Leenders, Thin Solid Films 451-452, 22 (2004).

    Article  ADS  Google Scholar 

  30. J. Y. Lee, S. T. Connor, Y. Cui and P. Peumans, NanoLett. 8, 689 (2008).

    Article  ADS  Google Scholar 

  31. E. von Hauff, V. Dyakonov and J. Parisi, Sol. Energy Mater. Sol. Cells 87, 149 (2005).

    Article  Google Scholar 

  32. J. Dai, X. X. Jiang, H. B. Wang and D. H. Yan, Appl. Phys. Lett. 91, 253503 (2007).

    Article  ADS  Google Scholar 

  33. G. Li, V. Shrotriya, Y. Yao and Y. Yang, J. Appl. Phys. 98, 043704 (2005).

    Article  ADS  Google Scholar 

  34. M. R. Reyes, K. Kim and D. L. Carroll, Appl. Phys. Lett. 87, 083506 (2005).

    Article  ADS  Google Scholar 

  35. W. Ma, C. Yang, X. Gong, K. Lee and A. J. Heeger, Adv. Funct. Mater. 15, 1617 (2005).

    Article  Google Scholar 

  36. Y. Shao and Y. Yang, Adv. Mater. 17, 2841 (2005).

    Article  Google Scholar 

  37. W. Ma, J. Y. Kim, K. Lee and A. J. Heeger, Macromol. Rapid. Commun. 28, 1776 (2007).

    Article  Google Scholar 

  38. P. Schilinsky, U. Asawapirom, U. Scherf, M. Biele and C. J. Brabec, Chem. Mater. 17, 2175 (2005).

    Article  Google Scholar 

  39. T. Yamanari, T. Taima, K. Hara and K. Saito, J. Photochem. Photobiol. Chem. 182, 269 (2006).

    Article  Google Scholar 

  40. D. Chirvase, J. Parisi, J. C. Hummelen and V. Dyakonov, Nanotechnology 15, 1317 (2004).

    Article  ADS  Google Scholar 

  41. W. H. Baek, H. Yang, T. S. Yoon, C. J. Kang, H. H. Lee and Y. S. Kim, Sol. Energy Mater. Sol. Cells 93, 1263 (2009).

    Article  Google Scholar 

  42. Q. Wei, T. Nishizawa, K. Tajima and K. Hashimoto, Adv. Mater. 20, 2211 (2008).

    Article  Google Scholar 

  43. Y. G. Kim et al., Nature Mater. 5, 197 (2006).

    Article  ADS  Google Scholar 

  44. R. Cugola, U. Giovanella, P. D. Gianvincenzo, F. Bertini, M. Catellani and S. Luzzati, Thin Solid Films 511-512, 489 (2006).

    Article  ADS  Google Scholar 

  45. S. H. Lee, D. H. Kim, T. H. Shim and J. G. Park, Nanotechnology 20, 335201 (2009).

    Article  ADS  Google Scholar 

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Authors and Affiliations

  1. Department of Electronics and Computer Engineering, Hanyang University, Seoul, 133-791, Korea

    Ji-Heon Kim

  2. Department of Electronics Engineering, Hanyang University, Seoul, 133-791, Korea

    Jea-Gun Park

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  1. Ji-Heon Kim
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  2. Jea-Gun Park
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Correspondence to Jea-Gun Park.

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Kim, JH., Park, JG. Effect of donor weight in a P3HT:PCBM blended layer on the characteristics of a polymer photovoltaic cell. Journal of the Korean Physical Society 66, 1720–1725 (2015). https://doi.org/10.3938/jkps.66.1720

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  • DOI: https://doi.org/10.3938/jkps.66.1720

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