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Effects of doping concentration on the structural and the optical properties of Sol-gel-derived In-doped ZnO thin films grown on muscovite mica substrates

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Abstract

In-doped ZnO (IZO) thin films were grown on muscovite mica substrates by using the sol-gel process. The structural and the optical properties of IZO thin films with different In concentrations (0, 1.5, 3, 4.5, 6, and 7.5 at.%) were investigated. All films had a granular structures with spherical nanosized crystallites, and the film’s thickness decreased gradually with increasing In concentration. However, noticeable cracks were observed in the films for In concentrations above 4.5 at.%. The deep-level (DL) emissions in the photoluminescence spectra were found to depend on the In concentration, with a marked decrease in the full width at half maximum of the near-band-edge emissions at relatively high In concentrations. The average transmittance of all films in the visible region was higher than 80%. Increasing the In concentration also led to a slight decrease in the optical band gap and to a significant increase in the Urbach energy.

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References

  1. L. Xu, G. Zheng, J. Miao and F. Xian, Appl. Surf. Sci. 258, 7760 (2012).

    Article  ADS  Google Scholar 

  2. T. R. B. Foong, S. P. Singh, P. Sonar, Z-E. Ooi, K. L. Chan and A. Dodabalapur, J. Mater. Chem. 22, 20896 (2012).

    Article  Google Scholar 

  3. D. Singh, S. Singh, U. Kumar, R. S. Srinivasa and S. S. Major, Thin Solid Films 555, 126 (2014).

    Article  ADS  Google Scholar 

  4. A. EI Manouni, F. J. Manjon, M. Perales, M. Mollar, B. Mari, M. C. Lopez and J. R. Ramos Barrado, Superlattices Microst. 42, 134 (2007).

    Article  ADS  Google Scholar 

  5. P. Nunes, E. Fortunato, P. Tonello, F. Braz Fernandes, P. Vilarihno and R. Maritins, Vacuum 64, 281 (2002).

    Article  Google Scholar 

  6. U. Ozgur, Y. I. Alivov, C. L. A. Teke, M. A. Reshchikov, S. Dogan, V. Avrutin, S. J. Cho and H. Morkoc, J. Appl. Phys. 98, 041301 (2005).

    Article  ADS  Google Scholar 

  7. Y. R. Park, E. K. Kim, D. Jung, T. S. Park and Y. S. Kim, Appl. Surf. Sci. 254, 2250 (2008).

    Article  ADS  Google Scholar 

  8. K. J. Chen, F. Y. Hung, S. J. Chang and Z. S. Hu, Appl. Surf. Sci. 255, 6308 (2009).

    Article  ADS  Google Scholar 

  9. Y-S. Kim and W-P. Tai, Appl. Surf. Sci. 253, 4911 (2007).

    Article  ADS  Google Scholar 

  10. M. Caglar, S. Ilican and Y. Caglar, Thin Solid Films 517, 5023 (2009).

    Article  ADS  Google Scholar 

  11. L. P. Peng, L. Fang, X. F. Yang, Y. J. Li, Q. L. Huang, F. Wu and C. Y. Kong, J. Alloys Comp. 484, 575 (2009).

    Article  Google Scholar 

  12. A. Hafdallah, F. Yanineb, M. S. Aida and N. Attaf, J. Alloys Comp. 509, 7267 (2011).

    Article  Google Scholar 

  13. M. Girtan, M. Socol, B. Pattier, M. Sylla and A. Stanculescu, Thin Solid Films 519, 573 (2010).

    Article  ADS  Google Scholar 

  14. P. M. R. Kumar, C. S. Kartha, K. P. Vijayakumar, T. Abe, Y. Kashiwaba, F. Singh and D. K. Avasthi, Semicond. Sci. Technol. 20, 120 (2005).

    Article  ADS  Google Scholar 

  15. D. Y. Kim, S. Lee, Z-H. Lin, K. H. Choi, S. G. Doo, H. Chang, J-Y. Leem, Z. H. Wang and S-O Kim, Nano Energy 9, 101 (2014).

    Article  ADS  Google Scholar 

  16. M. S. Kim et al., J. Korean Phys. Soc. 60, 1593 (2012).

    Article  ADS  Google Scholar 

  17. Z. Liu, Z. Jin, W. Li and J. Qiu, Mater. Lett. 59, 3620 (2005).

    Article  Google Scholar 

  18. S. H. Jeong, B. S. Kim and B. T. Lee, Appl. Phys. Lett. 82, 2625 (2003).

    Article  ADS  Google Scholar 

  19. P. M. R. Kumar, K. P. Vijayakumar and C. S. Kartha, J. Mater. Sci. 42, 2598 (2007).

    Article  ADS  Google Scholar 

  20. J. Zhao, X. Yan, Y. Yang, Y. Huang and Y. Zhang, Mater. Lett. 64, 567 (2010).

    Google Scholar 

  21. A. Bouraiou, M. S. Aida, O. Meglali and N. Attaf, Curr. Appl. Phys. 11, 1173 (2011).

    Article  ADS  Google Scholar 

  22. M. Caglar and F. Yakuphanoglu, Appl. Surf. Sci. 258, 3039 (2012).

    Article  ADS  Google Scholar 

  23. B. Benramache, B. Benhaoua, F. Chabane and A. Gueffaf, Optik 124, 3321 (2013).

    Article  Google Scholar 

  24. Y. Caglar, M. Caglar and S. Illican, Curr. Appl. Phys. 12, 963 (2012).

    Article  ADS  Google Scholar 

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Correspondence to Jae-Young Leem.

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Kim, Y., Leem, JY. Effects of doping concentration on the structural and the optical properties of Sol-gel-derived In-doped ZnO thin films grown on muscovite mica substrates. Journal of the Korean Physical Society 66, 1516–1520 (2015). https://doi.org/10.3938/jkps.66.1516

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  • DOI: https://doi.org/10.3938/jkps.66.1516

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