Abstract
The Photovoltaic properties of dye co-sensitized solar cells fabricated by using a one-bath mixed dye solution were compared with those of mono-sensitized devices. Co-sensitized TiO2 photo-electrodes were prepared from a mixed dye solution of M-Red [2-cyano-3(10-hexthyl-phenothiazin)acrylic acid] or D-Red [3,3′-hexyl-bis(phenothiazine-2-cyanoacrylic acid)] and S-Blue [(5-carboxy-3,3-dimethyl-1-nonyl-indolium)methylene-2-(E)-(5-carboxy-3,3-dimethyl-1-octylindolin-2-ylidene)-3-oxocyclobut-1-enolate)] to improve the short-circuit current (J sc ) of dyesensitized solar cells (DSSCs). When the photo-electrode was co-sensitized from the mixed solution of M-Red (75%) and S-Blue (25%), the power conversion efficiency (PCE) of the resulting DSSCs exhibited an 11.2% increase, compared to that of M-Red dye (100%). Use of the mixed dye solution of M-red and S-Blue is thought to have ability to reduce the aggregation of S-Blue dye adsorbed on TiO2 surface, leading to an enhancement in J sc of the co-sensitized solar cells. In the case of D-Red dye, the co-sensitized device prepared from the mixed solution of D-Red (50%) and S-Blue (50%) dye showed a 31.7% enhancement in the PCE, compared to that of the solar cell with a mono (D-Red)-sensitized photo-electrode. Unlike the co-sensitization system using the mixed solution of M-Red and S-Blue, the optimum photovoltaic performance was found from the mixed solution with a 1:1 ratio (D-Red:S-Blue). This could be attributed to the adsorption rate of D-Red (dimeric red) being faster than that of M-Red (monomeric red) dye, there inducing similar adsorption rates for the D-Red and the S-blue dye in the one-bath adsorption process for co-sensitization.
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References
B. O’Regan and M. Grätzel, Nature 353, 737 (1991).
J. Bisquert, D. Cahen, G. Hodes, S. Rühle and A. Zaban, J. Phys. Chem. B 108, 8106 (2004).
A. Hagfeldt and M. Grätzel, Acc. chem. Res. 33, 269 (2000).
P. J. Cameron and L. M. Peter, J. Phys. Chem. B 107, 14394 (2003).
H. Alarcón, G. Boschloo, P. Mendoza, J. L. Solis and A. Hagfeldt, J. Phys. Chem. B 109, 18483 (2005).
S. Karuppuchamy, K. Nonomura, T. Yoshida, T. Sugiura, H. Minoura, J. L. Solis and A. Hagfeldt, Solid State Ionics 151, 19 (2002).
A. Yella, H. W. Lee, H. N. Tsao, C. Yi, A. K. Chandiran, Md. K. Nazeeruddin, E. W. G. Diau, C. Y. Yeh, S. M. Zakeeruddin and M. Grätzel, Science 334, 629 (2011).
A. Hagfeldtt, G. Boschloo, L. Sun, L. Kloo and H. Petterson, Chem. Rev. 110, 6595 (2010).
M. Grätzel, Nature 414, 338 (2001).
M. K. Nazeeruddin, R. Humphry-Baker, P. Liska and M. Grätzel, J. Phys. Chem. B 107, 8981 (2003).
Y. Chiba, A. Islam, Y. Watanabe, R. Komiya, N. Koide and L. Y. Han, Jpn. J. Appl. Phys. 45, L638 (2006).
F. Gao, Y. Wang, D. Shi, J. Zhang, M. K. Wang, X. Y. Jing, R. Humphry-Baker, P. Wang, S. M. Zakeeruddin and M. Grätzel, J. Am. Chem. Soc. 130, 10720 (2008).
N. Robertson, Angew. Chem. Int. Ed. 47, 1012 (2008).
J. J. Cid, J. H. Yum, S. R. Jang, M. K. Nazeeruddin, E. Martnez-Ferrero, E. Palomares, J. Ko, M. Grätzel and T. Torres, Angew. Chem. 119, 8510 (2007).
S. W. Park, J. Y. Kim and Y. S. Kim, J. Korean Phys. Soc. 61, 1615 (2012).
N. R. Neale, N. Kopidakis, J. V. d. Lagemaat, M. Gratzel and A. J. Frank, J. Phys. Chem. B 109, 23183 (2005).
C. R. Lee, H. S. Kim, I. H. Jang, J. H. Im and N. G. Park, ACS Appl. Mater. Interfaces 3, 1953 (2011).
J. H. Cheon, S. A. Kim, K. S. Ahn, M. S. Kang and J. H. Kim, Electrochimica Acta 68, 240 (2012).
S. S. Park, Y. S. Won, Y. C. Choi and J. H. Kim, Energy & Fuels 23, 3732 (2009)
M. S. Kim, M. J. Cho, Y. C. Choi, K. S. Ahn, D. H. Choi, K. Kim and J. H. Kim, Dyes & Pigments, in press (2013).
J. H. Yum, S. R. Jang, R. Humphry-Baker, M. Grätzel, J. J. Cid, T. Torres and M. K. Nazeeruddin, Langmuir 24, 5636 (2008).
K. Hara, Y. Dan-oh, C. Kasada, Y. Ohga, A. Shinpo, S. Suga, K. Sayama and H. Arakawa, Langmuir 20, 4205 (2004).
N. R. Neale, N. Kopidakis, J. V. d. Lagematt, M. Grätzel and A. J. Frank, J Phys Chem. B 109, 23183 (2005).
K. M. Lee, C. Y. Chen, S. J. Wu, S. C. Chen and C. G. Wu, Sol. Energy Mater. Sol. Cells 108, 70 (2013).
J. H. Yum, S. J. Moon, R. Humphry-Baker, P. Walter, T. Geiger, F. Nuesch, M. Gätzel and M. D. K. Nazeeruddin, Nanotechnology 19, 424005 (2008).
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Kim, Y.R., Yang, H.S., Ahn, KS. et al. Enhanced performance of dye co-sensitized solar cells by panchromatic light harvesting. Journal of the Korean Physical Society 64, 904–909 (2014). https://doi.org/10.3938/jkps.64.904
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DOI: https://doi.org/10.3938/jkps.64.904