Abstract
Growth of hexagonal boron nitride (hBN), an isomorph of graphene/graphite, has been highlighted due to its highly insulating and transparent properties, in parallel with highly-conducting graphene counterpart, which could be useful for numerous applications. Nevertheless, difficulty arises from the absence of robust synthesis methods that provide large-area and high-quality hBN with controlled number of layers. In this article, we review the recent development for the synthesis of hBN with various approaches including liquid-metal, ultra-high-vacuum chemical vapor deposition (UHVCVD), and low-pressure CVD (LPCVD) methods. Its fundamental physical and chemical properties and its potential applications are further discussed. We expect that our comprehensive overview of the synthesis method of hBN will provide a route to find an ultimate method of synthesizing large-area and high-quality hBN with controlled number of layers.
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R. S. Pease, Nature 165, 722 (1950).
K. Watanabe, T. Taniguchi and H. Kanda, Nat. Mater. 3, 404 (2004).
A. Lipp, K. A. Schwetz and K. Hunold, J. of Eur. Ceram. Soc. 5, 3 (1989).
J. G. Kho, K. T. Moon, J. H. Kim and D. P. Kim, J. Am. Ceram. Soc. 83, 2681 (2000).
Y. Chen, J. Zou, S. J. Campbell and G. Le Caer, Appl. Phy. Lett. 84, 2430 (2004).
R. T. Paine and C. K. Narula, Chem. Rev. 90, 73 (1990).
J. S. Bunch, S. S. Verbridge, J. S. Alden, A.M. van der Zande, J. M. Parpia, H. G. Craighead and P. L. McEuen, Nano Lett. 8, 2458 (2008).
C. R. Dean et al., Nature Nanotech. 5, 722 (2010).
I. Meric, C. R. Dean, N. Petrone, L. Wang, J. Hone, P. Kim and K. L. Shepard, Proc. IEEE 101, 1609 (2013).
Y. Kubota, K. Watanabe, O. Tsuda and T. Taniguchi, Science 317, 932 (2007).
M. S. Dresselhaus and G. Dresselhaus, Adv. Phy. 51, 1 (2002).
Y.-H. Kim, K. J. Chang and S. G. Louie, Phys. Rev. B 63, 205408 (2001).
I. Jo, M. T. Pettes, J. Kim, K. Watanabe, T. Taniguchi, Z. Yao and L. Shi, Nano Lett. 13, 550 (2013).
H. O. Pierson, J. Compos. Mater. 9, 228 (1975).
A. A. Balandin, Nat. Mater. 10, 569 (2011).
A. A. Balandin, S. Ghosh, W. Bao, I. Calizo, D. Teweldebrhan, F. Miao and C. N. Lau, Nano Lett. 8, 902 (2008).
M. I. Petrescu, Diamond and Relat. Mater. 13, 1848 (2004).
C. Lee, X. Wei, J. W. Kysar and J. Hone, Science 321, 385 (2008).
W. C. Morgan, Carbon 10, 73 (1972).
W. Paszkowicz, J. B. Pelka, M. Knapp, T. Szyszko and S. Podsiadlo, Appl. Phys. Mater. Sci. Process. 75, 431 (2002).
T. Sugino and T. Tai, Jpn. J. Appl. Phys. Part 2-Lett. 39, L1101 (2000).
G.-H. Lee, Y.-J. Yu, C. Lee, C. Dean, K. L. Shepard, P. Kim and J. Hone, Appl. Phys. Lett. 99, (2011).
M. Engler, C. Lesniak, R. Damasch, B. Ruisinger and J. Eichler, Cfi-Ceramic Forum International 84, E49 (2007).
R. Haubner, M. Wilhelm, R. Weissenbacher and B. Lux, “Boron nitrides- properties, synthesis and applications”, in High Performance Non-oxide Ceramics II vol. 102, Springer-Verlag Berlin, 2002, p. 1.
G.-H. Lee, Y.-J. Yu, X. Cui, N. Petrone, C.-H. Lee, M. S. Choi, D.-Y. Lee, C. Lee, W. J. Yoo, K. Watanabe, T. Taniguchi, C. Nuckolls, P. Kim and J. Hone, ACS NANO 7, 7931 (2013).
K. K. Kim, A. Hsu, X. Jia, S. M. Kim, Y. Shi, M. Hofmann, D. Nezich, J. F. Rodriguez-Nieva, M. Dresselhaus, T. Palacios and J. Kong, Nano Lett. 12, 161 (2012).
H. Wang, T. Taychatanapat, A. Hsu, K. Watanabe, T. Taniguchi, P. Jarillo-Herrero and T. Palacios, IEEE Electron Dev. Lett. 32, 1209 (2011).
M. S. Bresnehan, M. J. Hollander, M. Wetherington, M. LaBella, K. A. Trumbull, R. Cavalero, D. W. Snyder and J. A. Robinson, ACS NANO 6, 5234 (2012).
L. Britnell, R. V. Gorbachev, R. Jalil, B. D. Belle, F. Schedin, A. Mishchenko, T. Georgiou, M. I. Katsnelson, L. Eaves, S. V. Morozov, N. M. R. Peres, J. Leist, A. K. Geim, K. S. Novoselov and L. A. Ponomarenko, Science (New York, N.Y.) 335, 947 (2012).
S. M. Kim, A. Hsu, P. T. Araujo, Y. H. Lee, T. Palacios, M. Dresselhaus, J. C. Idrobo, K. K. Kim and J. Kong, Nano Lett. 13, 933 (2013).
L. Ci, L. Song, C. H. Jin, D. Jariwala, D. X. Wu, Y. J. Li, A. Srivastava, Z. F. Wang, K. Storr, L. Balicas, F. Liu and P. M. Ajayan, Nat. Mater. 9, 430 (2010).
Z. Liu, L. Ma, G. Shi, W. Zhou, Y. Gong, S. Lei, X. Yang, J. Zhang, J. Yu, K. P. Hackenberg, A. Babakhani, J.-C. Idrobo, R. Vajtai, J. Lou and P. M. Ajayan, Nat. Nanotech. 8, 119 (2013).
M. P. Levendorf, C. J. Kim, L. Brown, P. Y. Huang, R. W. Havener, D. A. Muller and J. Park, Nature 488, 627 (2012).
Y. Lin and J. W. Connell, Nanoscale 4, 6908 (2012).
T. Taniguchi and K. Watanabe, J. Cryst. Growth 303, 525 (2007).
K. Watanabe, T. Taniguchi and H. Kanda, Phys. Status Solidi A 201, 2561 (2004).
K. Watanabe and T. Taniguchi, Int. J. Appl. Ceram. Tec. 8, 977 (2011).
B. Clubine, Thesis “Synthesis and characterization of bulk single crystal hexagonal boron nitride from metal solvents”, Kansas State University, (2012).
K. M. Burson, W. G. Cullen, S. Adam, C. R. Dean, K. Watanabe, T. Taniguchi, P. Kim and M. S. Fuhrer, Nano Lett. 13, 3576 (2013).
C. R. Dean et al., Nature 497, 598 (2013).
P. Maher, C. R. Dean, A. F. Young, T. Taniguchi, K. Watanabe, K. L. Shepard, J. Hone and P. Kim, Nat. Phys. 9, 154 (2013).
C. Dean, A. F. Young, L. Wang, I. Meric, G. H. Lee, K. Watanabe, T. Taniguchi, K. Shepard, P. Kim and J. Hone, Solid State Commun. 152, 1275 (2012).
W. Auwarter, T. J. Kreutz, T. Greber and J. Osterwalder, Surf. Sci. 429, 229 (1999).
W. Auwarter, M. Muntwiler, J. Osterwalder and T. Greber, Surf. Sci. 545, L735 (2003).
W. Auwarter, H. U. Suter, H. Sachdev and T. Greber, Chem. Mat. 16, 343 (2004).
A. B. Preobrajenski, A. S. Vinogradov and N. Martensson, Surf. Sci. 582, 21 (2005).
A. Nagashima, N. Tejima, Y. Gamou, T. Kawai and C. Oshima, Phys. Rev. B 51, 4606 (1995).
M. Morscher, M. Corso, T. Greber and J. Osterwalder, Surf. Sci. 600, 3280 (2006).
M. T. Paffett, R. J. Simonson, P. Papin and R. T. Paine, Surf. Sci. 232, 286 (1990).
A. B. Preobrajenski, A. S. Vinogradov, M. L. Ng, E. Cavar, R. Westerstrom, A. Mikkelsen, E. Lundgren and N. Martensson, Phys. Rev. B 75, 245412 (2007).
A. Goriachko, Y. B. He, M. Knapp, H. Over, M. Corso, T. Brugger, S. Berner, J. Osterwalder and T. Greber, Langmuir 23, 2928 (2007).
M. Corso, W. Auwarter, M. Muntwiler, A. Tamai, T. Greber and J. Osterwalder, Science 303, 217 (2004).
F. Mueller, S. Huefner, H. Sachdev, R. Laskowski, P. Blaha and K. Schwarz, Phys. Rev. B 82, 113406 (2010).
M. Yokoyama, Y. Matsukura and H. Tanaka, J. Cryst. Growth 203, 464 (1999).
A. Usui, H. Sunakawa, A. Sakai and A. A. Yamaguchi, Jpn. J. Appl. Phys. 236, L899 (1997).
R. Laskowski, P. Blaha and K. Schwarz, Phys. Rev. B 78, 045409 (2008).
Y. Liu, S. Bhowmick and B. I. Yakobson, Nano Lett. 11, 3113 (2011).
J. G. Diaz, Y. Ding, R. Koitz, A. P. Seitsonen, M. Iannuzzi and J. Hutter, Theor. Chem. Acc. 132, (2013).
S. Berner et al., Angew. Chem. Int. Ed. 46, 5115 (2007).
L. Song et al., Nano Lett. 10, 3209 (2010).
Y. M. Shi et al., Nano Lett. 10, 4134 (2010).
K. H. Lee, H.-J. Shin, J. Lee, I.-Y. Lee, G.-H. Kim, J.-Y. Choi and S.-W. Kim, Nano Lett. 12, 714 (2012).
K. K. Kim, A. Hsu, X. T. Jia, S. M. Kim, Y. M. Shi, M. Dresselhaus, T. Palacios and J. Kong, ACS NANO 6, 8583 (2012).
Y. H. Lee et al., RSC Adv. 2, 111 (2012).
G. Kim, A. R. Jang, H. Y. Jeong, Z. Lee, D. J. Kang and H. S. Shin, Nano Letters 13, 1834 (2013).
Y. Gao, W. Ren, T. Ma, Z. Liu, Y. Zhang, W.-B. Liu, L.-P. Ma, X. Ma and H.-M. Cheng, ACS NANO 7, 5199 (2013).
G. Wolf, J. Baumann, F. Baitalow and F. P. Hoffmann, Thermochim. Acta 343, 19 (2000).
F. Baitalow, J. Baumann, G. Wolf, K. Jaenicke-Rossler and G. Leitner, Thermochimi. Acta 391, 159 (2002).
J. Baumann, E. Baitalow and G. Wolf, Thermochim. Acta 430, 9 (2005).
P. J. Fazen, J. S. Beck, A. T. Lynch, E. E. Remsen and L. G. Sneddon, Chem. Mat. 2, 96 (1990).
P. J. Fazen, E. E. Remsen, J. S. Beck, P. J. Carroll, A. R. McGhie and L. G. Sneddon, Chem. Mat. 7, 1942 (1995).
S. Thiele, A. Reina, P. Healey, J. Kedzierski, P. Wyatt, P.-L. Hsu, C. Keast, J. Schaefer and J. Kong, Nanotechnology 21, (2010).
R. V. Gorbachev et al., Small 7, 465 (2011).
N. G. Rudawski, K. S. Jones and R. Gwilliam, Mater. Sci. Eng. R. 61, 40 (2008).
X. Li et al., Science 324, 1312 (2009).
P. Y. Huang et al., Nature 469, 389 (2011).
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Kim, K.K., Kim, S.M. & Lee, Y.H. A new horizon for hexagonal boron nitride film. Journal of the Korean Physical Society 64, 1605–1616 (2014). https://doi.org/10.3938/jkps.64.1605
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DOI: https://doi.org/10.3938/jkps.64.1605